Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A     

Lui-Heung Chan  Jeffrey C Alt 《Earth and Planetary Science Letters》2002,201(1):187-201

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.  相似文献   

中国农村剩余劳动力转移的趋向和措施     

范宇  姚士谋  Kam Wing Chan 《热带地理》2002,22(1):3-8

在对中国农村剩余劳动力现状描述的基础上 ,对剩余劳动力形成的原因进行了分析与阐述 ;结合目前形势 ,指出未来农村剩余劳动力的转移前景不容乐观 ;并在此基础上阐述了中国剩余劳动力转移途径和主要措施  相似文献   

Fluxes of Sr into the headwaters of the Ganges   总被引：1，自引：0，他引：1  

Mike J Bickle  Judith Bunbury  Nigel B.W Harris  Talat Ahmad 《Geochimica et cosmochimica acta》2003,67(14):2567-2584

Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, ⁸⁷Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated ⁸⁷Sr/⁸⁶Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the ⁸⁷Sr flux in excess of the seawater ⁸⁷Sr/⁸⁶Sr ratio of 0.709.  相似文献   

孟加拉湾季风爆发对南海季风爆发的影响Ⅰ:个例分析   总被引：11，自引：4，他引：11       下载免费PDF全文

刘屹岷  陈仲良  毛江玉  吴国雄 《气象学报》2003,61(1):1-9

利用南海季风试验分析场和NCAR向外长波辐射通量(OLR)资料研究了1998年孟加拉湾季风和南海季风爆发期间副热带环流的大尺度和天气尺度特征,探讨了孟加拉湾季风爆发与南海季风爆发之间的物理联系及孟加拉湾季风气旋的对流凝结潜热释放对副热带高压“撤出”南海的影响。结果表明,1998年5月爆发的东亚季风展现出典型的从孟加拉湾地区东传发展到南海地区的过程。随着孟加拉湾季风爆发和对流活动增强、北移,南海北部出现了低层西风和对流活动,领先于副热带高压在南海地区减弱和撤退。结果还显示南海北部地区的对流凝结加热有助于该地区经向温度梯度的反转,在热成风关系的制约下南海上空副热带高压脊面的垂直倾斜由冬季型转向夏季型,季风爆发。  相似文献   

Some characteristics of ozone profiles above Hong Kong     

Y. K. Leung  W. L. Chang  Y. W. Chan 《Meteorology and Atmospheric Physics》2004,87(4):279-291

Summary Analysis of ozonesonde data shows that in the lower troposphere above Hong Kong, there is a relative maximum with respect to height in all seasons except winter. In the upper troposphere, there is with respect to height a relative minimum in the seasonally averaged ozone mixing ratio in winter. Ozone mixing ratios in the upper troposphere in winter and spring can be significantly enhanced by stratospheric intrusions associated with the passage of cold fronts and upper cut-off lows.For Hong Kong, the seasonally averaged total ozone has the highest value in spring, and the lowest in winter. The seasonally averaged total tropospheric ozone also has the highest value in spring, but the lowest in summer. In a relative sense, total tropospheric ozone contributes most to the total ozone in spring and the least in summer.The phase of the total ozone anomaly above Hong Kong is influenced by the Quasi-Biennial Oscillation (QBO), with the positive anomaly associated with the easterly phase of QBO, and the negative anomaly the westerly phase.  相似文献   

A hybrid method for size characterization of coarse subsurface fluvial sediments     

Stephen P. Rice  Judith K. Haschenburger 《地球表面变化过程与地形》2004,29(3):373-389

This paper introduces and evaluates a novel method for ascertaining the grain‐size distribution of subsurface sediments that involves profoundly less sampling effort than standard methods. It is based on hybrid sampling principles previously applied to the construction of synthetic surface grain‐size distributions. The method is developed from an empirical demonstration of the approximate similarity of surface and subsurface grain‐size distributions when compared over a common range of sizes. Subsurface hybrid models are found to provide good facsimiles of grain‐size distributions de?ned using standard criteria and to yield distribution percentiles with millimetre accuracy. The technique is presented as an expedient alternative to standard methods for large, perennial gravel‐bed rivers. As this is a new technique, prudent application is advised in lieu of further investigation. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献   

Li/Ca in multiple species of benthic and planktonic foraminifera: thermocline, latitudinal, and glacial-interglacial variation     

Jenney M. Hall  L.-H. Chan 《Geochimica et cosmochimica acta》2004,68(3):529-545

Li/Ca ratios were measured in planktonic and benthic foraminifera from a variety of hydrographic settings to investigate the factors influencing lithium incorporation into foraminiferal tests including temperature, dissolution, pressure, and interspecies differences. Down-core measurements of planktonic (Orbulina universa, Globigerinoides ruber, and Globigerinoides sacculifer) and benthic foraminifera (calcitic Cibicides wuellerstorfi and aragonitic Hoeglandina elegans) show a systematic variation in Li/Ca with δ¹⁸O through the last glacial-interglacial transition. All species examined exhibit an increase in Li/Ca between 14 to 50% from the Holocene to the last glacial maximum. Li/Ca generally increases with decreasing temperature as seen in a latitudinal transect of planktonic O. universa and down-slope benthic species along the Bahama Bank margins. Postdepositional dissolution possibly causes a decrease in planktonic foraminiferal Li/Ca along the Sierra Leone Rise, and increased water depth causes a decrease in benthic foraminiferal Li/Ca in the deep Caribbean. However, none of these effects are sufficient to account for the observed glacial-interglacial changes. Physiological factors such as calcification rate may affect the Li/Ca content of foraminiferal calcite. The calcification rate in turn may be a function of carbonate ion concentration of ambient ocean water. This work shows that incorporation of lithium by foraminifera appears to be influenced by factors other than seawater composition and does not appear to be dominated by changes in temperature, dissolution, or pressure. We hypothesize that the consistent increase in foraminiferal Li/Ca during the last glacial maximum may be linked to changes in seawater carbonate ion concentration. Important parameters to be tested include calcification rate and foraminiferal test size and weight. If foraminiferal Li/Ca is dominantly controlled by calcification rate as a function of seawater carbonate ion concentration, then Li/Ca may act as a proxy of past atmospheric CO₂.  相似文献   

Assessing natural and cultural influence on soil in remnant tropical woodlands     

C Y Jim  Michael W H Chan 《Area》2004,36(1):6-18

Rural Hong Kong contains culturally protected enclaves of remnant woodlands that provide sanctuary for vegetation, wildlife and soil. This study focuses on the influence of natural and cultural factors on soil properties in woodlands with different human activities. At each of the nine selected sites, two pits were dug to collect soil samples for analysis of 24 physical and chemical properties. Analyses of variance between soil attributes and site factors suggest the prominence of woodland size, and important contribution of topography, aspect and parent material. Soil indicators of human impacts and the tenacity of woodland soil towards anthropogenic disturbance were demonstrated.  相似文献   

Stable axisymmetric SPH formulation with no axis singularity          下载免费PDF全文

Jian Wang  Dave Chan  Jiahe Zhang 《国际地质力学数值与分析法杂志》2016,40(7):987-1006

The axisymmetric formulation of the governing equations for geomechanics in the framework of smoothed particle hydrodynamics (SPH) is presented in this study. Two forms of SPH discretization for the motion equations, which are labeled as form I and form II, are proposed, and the methods to compute the hoop stress and strain terms including hoop strain rate and the acceleration introduced by the hoop stress are compared. To avoid possible singularity problem near the axis of symmetry, a perfectly smooth contact along with ghost particles are applied to prevent the real particles from overly approaching the axis of symmetry to remove this potential singularity. In addition, the Mohr–Coulomb constitutive model is implemented into the SPH formulation in describing soil behavior. Four numerical tests are carried out to validate and compare the accuracy and stability of the proposed algorithms, and their results are compared with analytical solutions and results from FEM analysis. The performance in these comparisons suggests that SPH II with hoop terms computed through direct hoop method is more stable than the others, and the adoption of contact for the symmetric axis is efficient in eliminating the singularity problem. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献