Experimental calibration of vanadium partitioning and stable isotope fractionation between hydrous granitic melt and magnetite at 800 °C and 0.5 GPa     

Paolo?A.?SossiEmail author  Julie?Prytulak  Hugh?St.?C.?O’Neill 《Contributions to Mineralogy and Petrology》2018,173(4):27

Vanadium has multiple oxidation states in silicate melts and minerals, a property that also promotes fractionation of its isotopes. As a result, vanadium isotopes vary during magmatic differentiation, and can be powerful indicators of redox processes at high temperatures if their partitioning behaviour can be determined. To quantify the partitioning and isotope fractionation factor of V between magnetite and melt, piston cylinder experiments were performed in which magnetite and a hydrous, haplogranitic melt were equilibrated at 800 °C and 0.5 GPa over a range of oxygen fugacities (\({f_{{{\text{O}}_{\text{2}}}}}\)), bracketing those of terrestrial magmas. Magnetite is isotopically light with respect to the coexisting melt, a tendency ascribed to the VI-fold V³⁺ and V⁴⁺ in magnetite, and a mixture of IV- and VI-fold V⁵⁺ and V⁴⁺ in the melt. The magnitude of the fractionation factor systematically increases with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\) relative to the Fayalite–Magnetite–Quartz buffer (FMQ), from ?⁵¹V_mag-gl = ? 0.63?±?0.09‰ at FMQ ? 1 to ? 0.92?±?0.11‰ (SD) at ≈?FMQ?+?5, reflecting constant V³⁺/V⁴⁺ in magnetite but increasing V⁵⁺/V⁴⁺ in the melt with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\). These first mineral-melt measurements of V isotope fractionation factors underline the importance of both oxidation state and co-ordination environment in controlling isotopic fractionation. The fractionation factors determined experimentally are in excellent agreement with those needed to explain natural isotope variations in magmatic suites. Furthermore, these experiments provide a useful framework in which to interpret vanadium isotope variations in natural rocks and magnetites, and may be used as a potential fingerprint the redox state of the magma from which they crystallise.  相似文献   

Neo-rural populations and their relations with local decision makers in rural Québec: collaboration or conflict?   总被引：1，自引：0，他引：1  

Myriam Simard  Laurie Guimond  Julie Vézina 《GeoJournal》2018,83(3):613-629

The socio-demographic recomposition of the countryside is affecting local interactions and power relations. Understanding these relationships remains a challenge, as the studies to date are often limited to conflicts between neo-rural populations (newcomers) and long-time country residents over partial issues, without including decision makers. To go beyond this conflictual and fragmentary perspective, the objective of this article is to present an overall picture of both cooperative and oppositional relations between four groups, namely, newcomers, long-time rural residents, leaders of local organizations and municipal officials, in regard to all the issues that concern them. The data are based on interviews with these various actors in two contrasting rural areas of Québec (Canada). After looking at the newcomers’ mixed assessment of their participation in community life, we concentrate on areas of collaboration and/or conflict between all the actors regarding demographic, economic, sociocultural, political, environmental and agricultural issues. Three main trends emerge, revealing unexpected ways of interacting, complex power relations and antagonistic conceptions of rural spaces and their future development.  相似文献   

Benthic infaunal communities around two artificial reefs in Mamala Bay, Oahu, Hawaii     

Fukunaga A  Bailey-Brock JH 《Marine environmental research》2008,65(3):250-263

Non-fishery use of artificial reefs has been given attention in recent years. The primary concern associated with non-fishery artificial reefs is their effects to the surrounding ecosystems. This study examined the infaunal communities around two non-fishery artificial reefs (the sunken vessels YO257 and Sea Tiger) in Mamala Bay, Hawaii. Infaunal community structures at these artificial reefs were relatively similar to one at a nearly natural patch reef. A large amount of basalt gravel around YO257 associated with its deployment operation possibly had an effect on the surrounding community by increasing pore space. Polychaete assemblages were compared with existing data throughout the bay, and this revealed that the variation in sediment grain sizes and depths seemed to play some role in structuring the polychaete communities. Nevertheless, the infaunal communities around the artificial reefs were typical and within the range of natural variation in Mamala Bay, supporting their beneficial uses in ecotourism.  相似文献   

Size distributions of artifact classes: Combining macro-and micro-fractions     

Julie K. Stein  Patrice A. Teltser 《Geoarchaeology》1989,4(1):1-30

The size and composition of microartifacts (objects less than 2 mm) and macroartifacts (objects greater than 2 mm) are utilized to interpret the formational processes of an archaeological site. Because grain-size distributions are known to reflect mode of transport and source, the attribute of size is examined by plotting each artifact class (unmodified rock, modified rock, ceramic, concretion, bone/shell, and metal) in size frequency diagrams. the plots allow the agent and mode of transport to be reconstructed, which in turn allows the formational processes of the site to be interpreted. the example used is the Pelts Site (23-DU-29) of southeastern Missouri. the site was chosen for this pilot study because the formation processes can be reconstructed from other data. the size distributions of each artifact class support those reconstructions and allow the proposed method to be evaluated as an interpretive method for other archaeological sites.  相似文献   

Carbonaceous chondrites as analogs for the composition and alteration of Ceres          下载免费PDF全文

Harry Y. McSween Jr.  Joshua P. Emery  Andrew S. Rivkin  Michael J. Toplis  Julie C. Castillo‐Rogez  Thomas H. Prettyman  M. Cristina De Sanctis  Carle M. Pieters  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1793-1804

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

Tectonic evolution of the Cape and Karoo basins of South Africa   总被引：1，自引：0，他引：1  

Anthony Tankard  Herman Welsink  Peter Aukes  Robert Newton  Edgar Stettler 《Marine and Petroleum Geology》2009,26(8):1379-1412

The Cape and Karoo basins formed within the continental interior of Gondwana. Subsidence resulted from the vertical motion of rigid basement blocks and intervening crustal faults. Each basin episode records a three-stage evolution consisting of crustal uplift, fault-controlled subsidence, and long periods of regional subsidence largely unaccompanied by faulting or erosional truncation. The large-scale episodes of subsidence were probably the result of lithospheric deflection due to subduction-driven mantle flow. The early Paleozoic Cape basin records the combined effects of a north-dipping intra-crustal décollement (a late Neoproterozoic suture) and a right-stepping offset between thick Rio de la Plata craton and Namaqua basement. Following the Saldanian orogeny, a suite of small rift basins and their post-rift drape formed at this releasing stepover. Great thicknesses of quartz sandstone (Ordovician–Silurian) and mudstone (Devonian) accumulation are attributed to subsidence by rheological weakening and mantle flow. In contrast, the Karoo basin is a cratonic cover that mimics the underlying basement blocks. The Permian Ecca and lower Beaufort groups were deposited in a southward-deepening ramp syncline by extensional decoupling on the intra-crustal décollement. Reflection seismic and deep-burial diagenetic studies indicate that the Cape orogeny started in the Early Triassic. Deformation was partitioned into basement-involved strike-slip faults and thin-skinned thrusting. Uplift of the Namaqua basement resulted in erosion of the Beaufort cover. East of the Cape fold belt, contemporaneous subsidence and tilting of the Natal basement created a late Karoo transtensional foreland basin, the Stormberg depocentre. Early Jurassic tectonic resetting and continental flood basalts terminated the Karoo basin.  相似文献   

Grossular activity-composition relationships in ternary garnets determined by reversed displaced-equilibrium experiments   总被引：1，自引：1，他引：1  

Andrea M. Koziol  Robert C. Newton 《Contributions to Mineralogy and Petrology》1989,103(4):423-433

Activity-composition relationships of Ca₃Al₂Si₃O₁₂ (grs) in ternary Ca-Mg-Fe garnets of various compositions have been determined by reversed displaced equilibrium experiments at 1000° C and 900° C and pressures of 8 to 17 kbar. The mixing of grs in garnet is nearly ideal at 30 mol% grs, with positive deviations from ideality at lower grs contents. Models of garnet mixing currently in the literature do not predict this trend. Analysis of the present reversals, in conjunction with a garnet mixing model based solely on calorimetry measurements on the binary joins, indicates that a ternary interaction constant for a ternary asymmetric Margules model (Wohl 1953) cannot be constrained. Apparently, some aspects of the garnet binary joins are still not well-known. An alternative asymmetric empirical model, based on analysis of pseudobinary joins of constant Mg/Mg + Fe(Mg #), reproduces the data well and is able to predict grs activity coefficients for garnets with grs contents between 3 and 40 mol% and Mg numbers between 0 and 0.60. The grossular activity coefficient, _grs, is given by:

相似文献    28. Responsible fisheries: An overview of FAO policy developments (1945–1994)      S.M. Garcia  C.H. Newton 《Marine pollution bulletin》1994,29(6-12):528-536 The paper outlines the evolution of fisheries development policies (aquaculture excluded), from an international perspective as seen within the various UN and FAO fishery committees. It begins with the first FAO Technical Committee on Fisheries in 1945 and extends through the various periods corresponding to post-war reconstruction (1945–1958), geographical expansion (1959–1972), establishment of a new economic order of the oceans (1973–1982), and transition towards global concerns (1983–1992). It underlines the gaps between government resolutions at the international level and effective implementation at national policy level. This identifies the elements to be considered in responsible fishing policies. Finally, the FAO International Code of Conduct for Responsible fisheries is presented as the conceptual framework for achieving sustainable fisheries development and UNCED's objectives within the framework of the 1992 Convention.  相似文献    29. The water status of Terminalia brownii Fresen. seedlings during establishment in semi-arid sites in Kenya      A. C. Newton  R. C. Munro  T. W. Wambugu 《Journal of Arid Environments》1993,25(4) The water status of Terminalia brownii seedlings was assessed in relation to incident microclimate and initial irrigation treatments, during establishment at Olorgesailie in the Rift Valley of Kenya. Experimental treatments involved incorporation of a water-absorbing polymer with the root systems of the plants during establishment, and repeated irrigation, in a factorial design. The maximum photosynthetically active radiation of over 2500 μmol/m2/s recorded during the first 9 days after outplanting was associated with air temperatures of up to 47·4°C, and leaf-to-air vapour pressure deficits (VPDs) of up to 8·04 kPa. Water potentials declined to a minimum of -3·7 MPa, 9 days after outplanting, indicating severe water deficits. Stomatal conductances were generally below 0·2 cm/s, reflecting a high degree of stomatal closure. However, conductances of over 1·3 cm/s were observed on the 6th day after outplanting, associated with VPDs below 1·5 kPa. These relatively high conductances were restricted to plants which had received irrigation; overall, irrigation was found to significantly increase stomatal conductance on three of the four measurement days. Although the application of synthetic polymers increased stomatal conductances on two of the measurement days, the effects were very slight (treated means 0·02-0·03 cm/s higher than controls). These results indicate the severity of the transplant shock in semi-arid sites for seedling water status, and imply that initial irrigation treatments are more likely to increase establishment rates of tree seedlings than application of synthetic polymers.  相似文献    30. THE NEW DECADE: DIGITS AND DIVERSITY      I. Newton  J. D. Leatherdale    J.-P. Muller  M. Sowton  A. S. Walker 《The Photogrammetric Record》1991,13(78):877-888 The President of the Photogrammetric Society, Mr. I Newton, chaired a panel discussion concerned with those developments in photogrammetry which may take place during the 1990s.  相似文献    [首页] « 上一页 [1] [2] 3 [4] [5] [6] [7] [8] [9] [10] [11] 下一页 » 末  页»