Experimental calibration of vanadium partitioning and stable isotope fractionation between hydrous granitic melt and magnetite at 800 °C and 0.5 GPa     

Paolo?A.?SossiEmail author  Julie?Prytulak  Hugh?St.?C.?O’Neill 《Contributions to Mineralogy and Petrology》2018,173(4):27

Vanadium has multiple oxidation states in silicate melts and minerals, a property that also promotes fractionation of its isotopes. As a result, vanadium isotopes vary during magmatic differentiation, and can be powerful indicators of redox processes at high temperatures if their partitioning behaviour can be determined. To quantify the partitioning and isotope fractionation factor of V between magnetite and melt, piston cylinder experiments were performed in which magnetite and a hydrous, haplogranitic melt were equilibrated at 800 °C and 0.5 GPa over a range of oxygen fugacities (\({f_{{{\text{O}}_{\text{2}}}}}\)), bracketing those of terrestrial magmas. Magnetite is isotopically light with respect to the coexisting melt, a tendency ascribed to the VI-fold V³⁺ and V⁴⁺ in magnetite, and a mixture of IV- and VI-fold V⁵⁺ and V⁴⁺ in the melt. The magnitude of the fractionation factor systematically increases with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\) relative to the Fayalite–Magnetite–Quartz buffer (FMQ), from ?⁵¹V_mag-gl = ? 0.63?±?0.09‰ at FMQ ? 1 to ? 0.92?±?0.11‰ (SD) at ≈?FMQ?+?5, reflecting constant V³⁺/V⁴⁺ in magnetite but increasing V⁵⁺/V⁴⁺ in the melt with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\). These first mineral-melt measurements of V isotope fractionation factors underline the importance of both oxidation state and co-ordination environment in controlling isotopic fractionation. The fractionation factors determined experimentally are in excellent agreement with those needed to explain natural isotope variations in magmatic suites. Furthermore, these experiments provide a useful framework in which to interpret vanadium isotope variations in natural rocks and magnetites, and may be used as a potential fingerprint the redox state of the magma from which they crystallise.  相似文献   

Neo-rural populations and their relations with local decision makers in rural Québec: collaboration or conflict?   总被引：1，自引：0，他引：1  

Myriam Simard  Laurie Guimond  Julie Vézina 《GeoJournal》2018,83(3):613-629

The socio-demographic recomposition of the countryside is affecting local interactions and power relations. Understanding these relationships remains a challenge, as the studies to date are often limited to conflicts between neo-rural populations (newcomers) and long-time country residents over partial issues, without including decision makers. To go beyond this conflictual and fragmentary perspective, the objective of this article is to present an overall picture of both cooperative and oppositional relations between four groups, namely, newcomers, long-time rural residents, leaders of local organizations and municipal officials, in regard to all the issues that concern them. The data are based on interviews with these various actors in two contrasting rural areas of Québec (Canada). After looking at the newcomers’ mixed assessment of their participation in community life, we concentrate on areas of collaboration and/or conflict between all the actors regarding demographic, economic, sociocultural, political, environmental and agricultural issues. Three main trends emerge, revealing unexpected ways of interacting, complex power relations and antagonistic conceptions of rural spaces and their future development.  相似文献   

On the modelling of sand bedforms using the semivariogram     

Andr Robert  Keith S. Richards 《地球表面变化过程与地形》1988,13(5):459-473

This study shows the usefulness of the semivariogram for modelling sand ripples created by water flows of varied flow intensity. A combination of two mathematical functions is fitted to each sample semivariogram, that is an exponential (or stochastic) component and a periodic component. The parameters of each of these components have direct physical meaning. A non-dimensional ratio combining the two parameters of the exponential model is interpreted as a regularity index (which increases with the degree of regularity of bedform arrangement). This regularity index is inversely related to the Froude number of the flow. The non-dimensional wavelength, estimated from the dominant periodic function, is also inversely and closely related to the Froude number. The wave height, accurately estimated from properties of the two fitted components, is a direct function of flow velocity and is also proportional to the standard deviation of bed elevations. The bedform shape introduces a considerable discrepancy between the generally assumed normal frequency distribution and the empirical distributions of bed height. The series of bed elevations are generally characterized by a mixture of normal distributions having the same variance but different means. The calculation of a covariance assuming a constant and single mean (as in spectral analysis) can therefore be misleading and the problem may be avoided by using the semivariogram.  相似文献   

Nonlinear Topics In Ocean Physics, A. R. Osborne (Ed), Elsevier, Amsterdam & New York, 1991, 945 Pp, Isbn 0-444-89017-3, Dfl. 420, Use 240.     

K. J. Richards 《Geophysical Journal International》1993,112(2):301-301

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Mechanics and performance of a tied-back wall under seismic loads     

G. Neelakantan  Muniram Budhu  R. Richards 《地震工程与结构动力学》1990,19(3):315-331

In this paper the stability of a tied-back wall subjected to seismic loads is analysed for a predetermined mode of failure (rotation about the top of the wall) and the analysis is compared with data from tests on this type of wall using the seismic simulator at the State University of New York at Buffalo. We carried out a pseudo-static analysis of the problem using the Mononobe-Okabe earth pressure coefficients, wherein the dynamic effects due to the seismic loading are converted into equivalent static loads. The acceleration ratio at which the wall fails by rotation about the top was obtained by considering the moments due to the various lateral earth pressure resultants and the inertial forces induced in the soil due to the seismic loading. We found that the presence of wall friction on the passive side significantly enhances the stability of the flexible retaining wall under seismic loads. Thus, flexible retaining walls supporting dry cohesionless soil can be very efficient during earthquakes. Under moderate earthquakes, an increase in the depth of embedment increases the dynamic factor of safety significantly. However, beyond a certain acceleration ratio for a soil with a particular value of ø, any increase in the depth of emdedment has no effect in impeding failure, irrespective of any change in the geometry of the system. Seismic design charts are presented to evaluate the stability of, and to design, flexible retaining walls embedded in dry cohesionless soils under seismic loading.  相似文献   

Oceanography: The past | Mary Sears and Daniel Merriman (Editors), 1980. Springer-Verlag,New York,N.Y., 812 pp., DM 70     

K.J. Richards 《Earth》1982,18(1):81-82

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Lead analysis of sediment cores from seven Connecticut lakes   总被引：2，自引：0，他引：2  

Peter A. Siver  Julie A. Wizniak 《Journal of Paleolimnology》2001,26(1):1-10

Lead analyses were performed on sediment cores from seven Connecticut lakes by dilute acid leaching. The absolute concentrations of lead varied from core to core, but the lead profiles were similar in all of the cores, and each depicted a point where the concentration of lead sharply increased above background levels. The background lead concentrations observed in the bottom portions of the cores ranged from 12-54 g Pb/g sediment with a mean of 30 g Pb/g, and increased to a mean maximum of 310 g Pb/g. In six of the lakes significant increases above background levels were not noted until between 1924 and 1952, suggesting that, at least for Connecticut lakes, the point in a lake sediment core where the concentration of lead began to increase was after ca. 1924, and on average about 1930. Lead concentrations declined in the surface sediments of only three of the lakes, mostly since the 1980's, and presumably in response to the phasing out of leaded gasoline. However, significant declines in lead concentrations were not observed in the remaining cores, possibly due to increased motor vehicle use within the airshed of the lakes and/or changes in the export of lead to the lakes from their watersheds.  相似文献   

The Llullaillaco volcano, northwest Argentina: construction by Pleistocene volcanism and destruction by sector collapse     

J. P. Richards  M. Villeneuve 《Journal of Volcanology and Geothermal Research》2001,105(1-2)

Llullaillaco is one of a chain of Quaternary stratovolcanoes that defines the present Andean Central Volcanic Zone (CVZ), and marks the border between Chile and Argentina/Bolivia. The current edifice is constructed from a series of thick dacitic lava flows, forming the second tallest active volcano in the world (6739 m). K–Ar and new biotite laser ⁴⁰Ar/³⁹Ar step-heating dates indicate that the volcano was constructed during the Pleistocene (≤1.5 Ma), with a youngest date of 0.048±0.012 Ma being recorded for a fresh dacite flow that descends the southern flank. Additional ⁴⁰Ar/³⁹Ar measurements for andesitic and dacitic lava flows from the surrounding volcanic terrain yield dates of between 11.94±0.13 Ma and 5.48±0.07 Ma, corresponding to an extended period of Miocene volcanism which defines much of the landscape in this region. Major- and trace-element compositions of lavas from Llullaillaco are typical of Miocene–Pleistocene volcanic rocks from the western margin of the CVZ, and are related to relatively shallow-dipping subduction of the Nazca plate beneath northern Chile and Argentina.Oversteepening of the edifice by stacking of thick, viscous, dacitic lava flows resulted in collapse of its southeastern flank to form a large volcanic debris avalanche. Biotite ⁴⁰Ar/³⁹Ar dating of lava blocks from the avalanche deposit indicate that collapse occurred at or after 0.15 Ma, and may have been triggered by extrusion of a dacitic flow similar to the one dated at 0.048±0.012 Ma. The avalanche deposits are exceptionally well preserved due to the arid climate, and prominent levées, longitudinal ridges, and megablocks up to 20-m diameter are observed.The avalanche descended 2.8 km vertically, and bifurcated around an older volcano, Cerro Rosado, before debouching onto the salt flats of Salina de Llullaillaco. The north and south limbs of the avalanche traveled 25 and 23 km, respectively, and together cover an area of approximately 165 km². Estimates of deposit volume are hampered by a lack of thickness information except at the edges, but it is likely to be between 1 and 2 km³. Equivalent coefficients of friction of 0.11 and 0.12, and excess travel distances of 20.5 and 18.5 km, are calculated for the north and south limbs, respectively. The avalanche ascended 400 m where it broke against the western flank of Cerro Rosado, and a minimum flow velocity of 90 m s⁻¹ can be calculated at this point; lower velocities of 45 m s⁻¹ are calculated where distal toes ascend 200 m slopes.It is suggested that the remaining precipitous edifice has a high probability for further avalanche collapse in the event of renewed volcanism.  相似文献   

Petroleum Hydrocarbon Bioventing Kinetics Determined in Soil Core, Microcosm, and Tubing Cluster Studies   总被引：2，自引：0，他引：2  

Ellen E. Moyer  David W. Ostendorf  Robin J. Richards  Steve Goodwin 《Ground Water Monitoring & Remediation》1996,16(1):141-153

Aerobic biodegradation of vapor-phase petroleum hydrocarbons was evaluated in an intact soil core from the site of an aviation gasoline release. An unsaturated zone soil core was subjected to a flow of nitrogen gas, oxygen, water vapor, and vapor-phase hydrocarbons in a configuration analogous to a biofilter or an in situ bioventing or sparging situation. The vertical profiles of vapor-phase hydrocarbon concentration in the soil core were determined by gas chromatography of vapor samples. Biodegradation reduced low influent hydrocarbon concentrations by 45 to 92 percent over a 0.6-m interval of an intact soil core. The estimated total hydrocarbon concentration was reduced by 75 percent from 26 to 7 parts per million. Steady-state concentrations were input to a simple analytical model balancing advection and first-order biodegradation of hydrocarbons. First-order rate constants for the major hydrocarbon compounds were used to calibrate the model to the concentration profiles. Rate constants for the seven individual hydrocarbon compounds varied by a factor of 4. Compounds with lower molecular weights, fewer methyl groups, and no quaternary carbons tended to have higher rate constants. The first-order rate constants were consistent with kinetic parameters determined from both microcosm and tubing cluster studies at the field site.  相似文献   

Nant-y-moch grassland improvement study,A. M. Roberts,J. A. Hudson and G. Roberts,Institute of Hydrology,Report No. 104, 1990. No. of pages: 85. Price: £7.00. ISBN 0-948540-16-8     

Keith Richards 《地球表面变化过程与地形》1992,17(6):635-635

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