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During the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study ΙΙ (SEEDS-II), we monitored variations in the concentrations of non-methane hydrocarbons (NMHCs), CH3Cl, N2O, and CH4 within a phytoplankton bloom. Stable isotopic compositions were also determined to evaluate the sources of the variations. Although there was little variation in either the concentrations or the stable isotopic compositions of alkenes, CH3Cl, N2O, and CH4 during the 23-day observation period, alkane concentrations increased substantially as the phytoplankton bloomed. The column-integrated quantities of alkanes increased to 3 times pre-bloom levels for C2H6, 5 times for C3H8, and 20 times for n-C4H10. The δ13C values of both C2H6 and C3H8 remained almost constant while concentrations increased, whereas that of n-C4H10 increased by about 12‰. To evaluate the sources of the alkanes produced during the bloom, we compared their δ13C values with those of alkanes produced in axenic phytoplankton cultures in our laboratory. We concluded that during the SEEDS-ΙΙ experiment the major portions of C2H6 and C3H8 were produced during the autolysis of diatoms cells, whereas n-C4H10 was produced during autolysis of other phytoplankton cells such as cryptophytes and dinoflagellates.  相似文献   
23.
Field surveys on atmospheric deposition and stream water chemistry were conducted in an evergreen forest in northeastern Thailand characterized by a tropical savanna climate with distinct dry and wet seasons. Atmospheric deposition of ion constituents by throughfall and stemflow was shown to increase in the beginning and end of the wet season, reflecting the precipitation pattern. The pH and electrical conductivity of stream water increased with alkalinity and base cation concentrations due to mineralization of organic matter by the first rain and retention of anions in soil during the start of the wet season. After initial alkalinization, the pH and alkalinity declined rapidly with the highest SO42? concentration displayed in the middle towards the end of the wet season. The magnitude of peaks in SO42? concentration (13.5–60.6 μmolc/L) reflects deposition during the first 2 months of the wet season (March and April) in respective years (60.8–170 molc/ha). Release of SO42? with H+, which is retained in soil during the early wet season, may cause acidification later in the season. The deposition and concentration of SO42? declined over 6 years. However, the pH of stream water declined with increasing concentrations of SO42? and other major ions. The release of materials accumulated in the ecosystem was facilitated by the decrease in SO42? concentration/deposition and increased precipitation in the middle–late wet season. The retention‐release cycle of SO42? largely contributed to both seasonal and interannual variations in stream water chemistry in the tropical savanna climate studied.  相似文献   
24.
After years of discussions and trials, Japan's domestic emissions trading scheme remains purely voluntary. The newly elected Democratic Party of Japan (DPJ) has taken a firmer stance on climate change, initially intending to establish a nationwide mandatory cap-and-trade as early as 2011. This has promoted several questions regarding the possible designs and feasibility of such a scheme. This article describes the key features of the two trial schemes implemented, thus far, assesses the effectiveness of their implementation and discusses what will be the likely areas of contention should the Japanese government introduce a mandatory cap-and-trade in the future. The analyses indicate that the initial years of ‘Japan's Voluntary Emissions Trading Scheme’ (JVETS) implementation have shown positive performance, although its scale has remained limited. The ‘Trial Implementation of an Integrated Domestic Market for Emissions Trading’ emerged as a hybrid scheme, one that incorporated varying interests. Significant institutional developments have taken place in recent years, however the effectiveness of the present trial scheme also seems restricted.  相似文献   
25.
Concentrations of total arsenic and individual arsenic compounds were determined in liver, muscle, kidney and blubber of mother and fetus of Dall’s porpoises collected from off Sanriku, Japan, in the year 2000 to characterize the placental transfer of arsenic to fetus in cetaceans. Arsenic was detected in all the tissues of Dall’s porpoises. Total arsenic concentrations in liver, kidney, muscle and blubber were 0.76, 0.69, 0.35 and 0.55 μg/g wet wt, respectively, for mother and 0.28, 0.23, 0.26 and 0.07 μg/g wet wt, respectively, for fetus. In all the tissues, concentrations of total arsenic in mother Dall’s porpoise were higher than in fetus. Arsenic speciation revealed that arsenobetaine was the major arsenic compound in liver, kidney and muscle of both mother and fetus. The percentage of arsenobetaine to total arsenic ranged from 76.0 to 91.0% in the tissues. Dimethylarsinic acid, arsenocholine, methylarsonic acid and an unidentified arsenic compound were also detected in tissues of both mother and fetus as minor constituents, whereas tetramethylarsonium ion was not detected in tissues of the fetus. These results suggest that arsenobetaine, dimethylarsinic acid, arsenocholine and methylarsonic acid are transferable from mother to fetus in Dall’s porpoises. To our knowledge, this is the first report on placental transfer of arsenic compounds to fetus in marine mammals.  相似文献   
26.
Seasonal variations in coastal debris on Awaji Island, Japan   总被引:1,自引:1,他引:0  
The subject of our study was Awaji Island, an island located in the west of Japan that is surrounded by sea and that has serious problems relating to coastal debris. We conducted a long-term investigation focusing on three beaches and evaluated the results. The study was designed to develop an understanding of the actual situation, to inform local citizens, and raise their concerns about the problem of debris with a view to taking action against it. We obtained the following results: the amount, type, and ratio of debris changed according to weather and ocean conditions; debris also differs according to geographical conditions; social and economic activities of the surrounding area influence the type of debris encountered. Following this study, we have continued our investigation, and are continuing to gather data. At the same time, it is important to spread our ideas and enlighten people so as to encourage them not to dump debris. We hope that these actions manage to raise the level of consciousness among local citizens and to expand their anti-debris activities.  相似文献   
27.
The chemical desorption of an adsorbed CO molecule in the vicinity of H2-forming sites on cosmic dust grains in cold dense clouds is investigated theoretically, mainly using a model based on a classical molecular dynamics computational simulation. As a model surface for icy mantles of dust grains, an amorphous water ice slab is generated at 10 K, and the first and the second H atoms are thrown on to the model surface to reproduce the recombination process of the two H atoms, H+H→H2. Then, the time and space dependence of the local temperature increase of icy mantles caused by the release of H2 formation energy in the vicinity of H2-forming sites is examined. It is found that icy mantles are heated locally up to about 30 K in the surface region at R 4 Å and about 20 K at 4 R 6 Å, where R is the distance from the H2-forming site. The critical temperature of CO desorption is estimated to be about 20–30 K under conditions in typical dense clouds, which might be seen to be comparable to the above result. However, the lifetime of local heating of icy mantles is found to be too short, compared with the time-scale of CO desorption (1013 s) and that for H2 forming in the vicinity of an adsorbed CO molecule (more than 2×1013 s). Thus, it is found that the efficiency of chemical desorption of CO on a large dust grain is negligible. On the other hand, chemical desorption can occur on a small dust grain with size less than 20 Å.  相似文献   
28.
A significant carbon-14 enhancement has recently been found in tree rings for the year 994, suggesting an extremely strong and brief cosmic ray flux event. The origin of this particular cosmic ray event has not been confirmed, but one possibility is that it might be of solar origin. Contemporary historical records of low-latitude auroras can be used as supporting evidence of intense solar activity around that time. We investigate previously reported as well as new records that have been found in contemporary observations from the 990s to determine potential auroras. Records of potential red auroras in late 992 and early 993 were found around the world, i.e. in the Korean Peninsula, Saxonian cities in modern Germany, and the Island of Ireland, suggesting the occurrence of an intense geomagnetic storm driven by solar activity.  相似文献   
29.
Although the mining activity of the Idrija mine in Slovenia ceased in 1995, a large amount of mining dregs containing high concentrations of mercury remains in the area. The mining dregs were transported with river flow and deposition along the Idrija River. To estimate the dispersion and change in the chemical form of mercury, a total of 28 soil core samples were taken around the river. The individual core samples were separated into layers for the analysis of their chemical composition, carbon contents, total mercury (T-Hg) and methylmercury (MeHg) concentrations. The chemical composition measured by X-ray fluorescence spectrometry was useful to estimate the dispersion of tailings: the fluvial terrace soil had a chemical composition similar to that of the tailings and could be distinguished clearly from the forest soil. The highest T-Hg concentration, 1,100 mg kg−1, was observed in the fluvial terrace soil near the mine. Although the concentration decreased gradually along with distance from the mine, concentrations higher than 200 mg kg−1 of T-Hg were still observed in the fluvial terrace soil approximately 20 km downstream from the mine. In the vertical distribution of T-Hg in the hillslope soil, a higher value was observed in the upper layers, which suggests the recent atmospheric deposition of mercury. The concentration of MeHg was the lowest at the riverside and higher in the hillslope soil, which was the opposite of the T-Hg distribution. The total organic carbon content tracked similarly with the distribution of MeHg and a linear relation with a significantly high correlation coefficient was obtained. The distinction may be related to the different dispersion process of mercury, and the organic carbon contents may be an important factor for MeHg formation.  相似文献   
30.
The 2005 northern Pakistan earthquake (magnitude 7.6) of 8 October 2005 occurred in the northwestern part of the Himalayas. We interpreted landslides triggered by the earthquake using black-and-white 2.5-m-resolution System Pour l’Observation de la Terre 5 (SPOT 5) stereo images. As a result, the counts of 2,424 landslides were identified in the study area of 55 by 51 km. About 79% or 1,925 of the landslides were small (less than 0.5 ha in area), whereas 207 of the landslides (about 9%) were large (1 ha and more in area). Judging from our field survey, most of the small landslides are shallow rock falls and slides. However, the resolution and whitish image in the photos prevented interpreting the movement type and geomorphologic features of the landslide sites in detail. It is known that this earthquake took place along preexisting active reverse faults. The landslide distribution was mapped and superimposed on the crustal deformation detected by the environmental satellite/synthetic aperture radar (SAR) data, active faults map, geological map, and shuttle radar topography mission data. The landslide distribution showed the following characteristics: (1) Most of the landslides occurred on the hanging-wall side of the Balakot–Garhi fault; (2) greater than one third of the landslides occurred within 1 km from the active fault; (3) the greatest number of landslides (1,147 counts), landslide density (3.2 counts/km2), and landslide area ratio (2.3 ha/km2) was found within Miocene sandstone and siltstone, Precambrian schist and quartzite, and Eocene and Paleocene limestone and shale, respectively; (4) there was a slight trend that large landslides occurred on vertically convex slopes rather than on concave slopes; furthermore, large landslides occurred on steeper (30° and more) slopes than on gentler slopes; (5) many large landslides occurred on slopes facing S and SW directions, which is consistent with SAR-detected horizontal dominant direction of crustal deformation on the hanging wall.  相似文献   
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