Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry     

Martha Gledhill  Constant M. G. van den Berg 《Marine Chemistry》1995,50(1-4)

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.  相似文献   

Risk of dike failure due to flow slides     

M. B. de Groot  H. den Adel  T. P. Stoutjesdijk  C. J. van Westenbrugge 《Coastal Engineering》1995,26(3-4)

Flow slides may affect the stability of dikes. A flow slide is an instability of a submerged slope caused by liquefaction of loose, (medium) fine sand. Whether a flow slide will occur depends on the properties of the sand, which are a function of its density, and the geometry of the slope, as determined by wave and current induced scour and sedimentation. The influence of sand properties and the geometry parameters on the risk of flow slides are discussed. The application of a flow slide prediction method to an example and a risk analysis is briefly discussed.  相似文献   

A comparative study of some directional sea models     

J.M. Niedzwecki  C.P. Whatley 《Ocean Engineering》1991,18(1-2)

Current specification of the ocean wave environment for the design of offshore platforms does not adequately describe the directional nature of a real seaway. The strong wave frequency dependent nature of the directional behavior of observed seas is often over-simplified for design. A general formulation encompassing a wide range of directional sea models is presented. Parameter values used in some of the more popular directional sea models are examined. Approximate expressions for the two frequency dependent parameters in a modified Longuet-Higgins cosine wave spreading model are presented. A general procedure which allows an engineer to estimate parameters for alternate wave spreading models is discussed. To illustrate this procedure an empirically based modified cosine spreading model is used as the basis to estimate frequency dependent parameters for circular normal and wrapped Gaussian wave spreading models. A comparison of the contours of the various directional sea models and the prediction of the root-mean-square velocity distribution is presented.  相似文献   

Wave drift enhancement effects in multi column structures     

R. Eatock Taylor  S.M. Hung 《Applied Ocean Research》1985,7(3):128-137

A theoretical assessment is made of mean wave drift forces on groups of vertical circular cylinders, such as the columns of a floating offshore platform. A complete analytical solution is obtained for two cylinders extending from seabed to free surface, and a long wave approximation is found to provide reliable predictions of the drift force in line with the waves at low frequencies. For moderate separation between the two cylinders, this force is found to tend at low frequencies to a value four times the force on an isolated cylinder.A numerical method is employed to study two surface piercing cylinders truncated below the free surface, and an arrangement of four vertical cylinders characteristic of a floating offshore platform. The mean vertical drift force is found to be reasonably well approximated, over the frequency range of practical interest, by the force on an individual cylinder considered in isolation multiplied by the number of cylinders in the group. Interaction effects, however, have a profound influence on the total horizontal drift force. At low frequencies this force is found to tend to the force on an isolated cylinder multiplied by the squate of the number of cylinders in the group.  相似文献   

An experimental investigation of plunging breaker boundary layers in the transformation zone     

M.S. Kirkgz 《Coastal Engineering》1989,13(4)

Experimental investigation is made on the boundary layers of the transformation zone (i.e. the region between the last symmetrical wave profile depth and the breaking point) of plunging breakers propagating on a smooth beach with 1/12 uniform slope. Using a laser anemometer, the particle velocities are measured at four verticals along the transformation zone for three different steepnesses of waves within the plunging breaker range. The boundary layer flow in the transformation zone is found mostly of turbulent character and vertical distribution of particle velocities does not seem to conform to the classical law of the wall distribution given for steady-flow boundary layers. The results show that free-stream particle velocities, in the boundary layer of the breaker under the crest phase, increase considerably as the wave progresses towards the breaking point. The boundary layer thickness, defined as the velocity-affected region, remains constant throughout the transformation zone but it decreases with increasing deep-water wave steepness for the particular beach slope tested.  相似文献   

Distribution, texture and composition of modern phosphate pellets in Peru shelf muds     

K. Bryan Baker  William C. Burnett 《Marine Geology》1988,80(3-4):195-213

Textural analysis, including estimates of concentrations of authigenic phosphate pellets, were made for eight sediment cores from the Peru continental margin. Phosphatic pellets separated from these modern organic-rich sediments are black, spherical-ovoidal in shape, and in thin section often display a concentric structure around a nucleus consisting of inorganic mineral grains. Some pellets have a gray-white exterior coating which appears to be secondary diagenetic calcite. Phosphatic pellets account for upwards of 80% of the sediment mass in some cores. Pellets concentrate in specific size classes, generally between 125 and 500 μm in diameter, and occur within a poorly sorted sediment.  相似文献   

Stock-recruitment curves as used in the stock-reduction analysis model     

Kimura  Daniel K. 《ICES Journal of Marine Science》1988,44(3):253-258

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Design of a caisson plate under wave impact     

M. Salih Kirkgz  Yalin Mengi 《Ocean Engineering》1987,14(4)

From the laboratory experiments and field studies it has been shown that when a wave breaks directly on a vertical wall, impact pressures of high magnitude and short duration, are produced. Despite the recent advances made in collecting data on impact pressure histories and their spatial distributions, analyses on the structural behaviour of the walls loaded by the impact forces do not seem adequate. In the present study the theoretical analysis of the response characteristics of a caisson plate, having different aspect ratios, under the wave impact loading is investigated. Numerical results for the dynamic values of moments and transverse displacements are obtained by the method of finite elements. Some prerequisite experimental data for wave breaking and resulting impact pressures are provided. The static results for moments and deflections are also computed for comparing them with the dynamic values. The dynamic results are found significantly greater than the static values. The ratio between the dynamic and static values is called “Dynamic magnification factor” that varies with plate aspect ratio. Based on this factor a procedure is proposed which may have practical consequences in the design of caisson plates.  相似文献   

The effect of currents on the generation of internal waves by a barotropic tide near an underwater ridge     

E. M. Kolomoitseva  L. V. Cherkesov 《Physical Oceanography》1997,8(3):155-167

In the frame of the linear theory for long waves, the paper studies long waves generated by a barotropic tide running at an arbitrary angle over a bottom ridge. The ocean is assumed to be two-layered. In the area of a ridge with a rectangular cross section, geostrophic flows are considered, coupled with the inclinations of the free surface and interface. Wave amplitudes are shown to depend on the angle of an onrunning tide and this allows us to reach a conclusion about the influence of a geostrophic current on the generation of internal waves. Translated by Vladimir A. Puchkin.  相似文献   

The Amphipod Community as a Bioindicator in Algeciras Bay (Southern Iberian Peninsula) Based on a Spatio-Temporal Distribution   总被引：2，自引：0，他引：2  

M. Conradi    P. J. López-González  C. García-Gómez   《Marine Ecology》1997,18(2):97-111

Abstract. The amphipod population associated with Bugula neritina (L.), a verycommon bryozoan species in Algeciras Bay (Strait of Gibraltar), was studied on a spatio-temporal scale, in order to define its role as a bioindicator. Samples were collected in December, March, June and September along a transect running from the external to the internal sampling stations.
Fifty-three species belonging to 22 families were identified; the most abundant species were Jassa marmorata H olmes , Ischyrocerus inexpectatus (R uffo ) and Phtisica marina S labber .
The spatial evolution of the amphipod community reflected the physico-chemical conditions of Algeciras Bay, yielding a clear gradient from the outer to the inner stations. The stations located at the mouth of the bay, characterised by high hydrodynamism and low sedimentation, had a higher diversity and species richness than the inner stations with low water movement and higher sedimentation. Eight species preferred for the outer stations, while another nine species were typical of the inner harbours.
The most notable aspect of the seasonal evolution was the increased dominance of the tube-builder and deposit-suspension feeder Jassa marmorota .
Structural and ordination analyses corroborate the outer-inner gradient in the bay and illustrate the importance of hydrodynamic forces and sedimentation in the amphipod community.  相似文献