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11.
Geochemical as well as multivariate statistical analyses (PCA) were carried out on 20 crude oil samples from ‘Middle’ Pliocene Production Series (MPPS) of Guneshli-Chirag-Azeri (GCA), Bahar, and Gum Adasi fields in the western South Caspian Basin (SCB). PCA analysis employed to source-specific biomarkers distinguishes the oils into two types one being divided into two sub-types; Type 1 (GCA oils), Type 2A (Bahar field oils) and Type 2B (Gum Adasi field oils). Indirect oil-to-source rock correlations to available source rock data from previous studies suggest that Type 1 oils, located in the Apsheron-Balkhans uplift area, are derived from basinal shales of the Oligocene-Lower Miocene Middle Maikop Formation. Type 2A and 2B oils, located in the Gum-deniz-Bahar-Shakh-deniz trend area, are more likely derived from shelf-edge shales of the Upper Maikop Formation and the Middle-Upper Miocene Diatom Suite, respectively.Biomarker maturity study reveals that Type 1 oils (mean %Rc=0.78) are more mature than Type 2 oils (mean %Rc=0.71). Source rocks, which generated these oils, were at generation depth interval between 5200 m (112 °C) and 7500 m (153 °C) at the time of expulsion. This indicates that the western SCB oils experienced significant long-range vertical migration along the deep-seated faults to accumulate in the MPPS reservoirs. Post-accumulation biodegradation process was only observed in the Guneshli field where bacterial alteration (level 4) began between 4.2 and 2.6 mybp and stopped with the deposition of the overlying impermeable Upper Pliocene Akchagyl Formation. Subsequent light hydrocarbon (C1–C16) charge into the Guneshli fields caused precipitation of asphaltenes, which is evidenced by high resin to asphaltene ratios for the present-day Guneshli oils. Evaporative-fractionation examined using the scheme of [Thompson, 1987] showed high correlations of the ‘aromaticity’ B parameter (=toluene/n-C7) and ‘parafinicity’ F parameter (=n-C7/MCH with the %Rc (maturity) and C27/C29 sterane ratio (organic matter type). This implies that Thompson's approach should be used with caution in the SCB. Among the several mechanisms, rapid and thick deposition of Pliocene sediments and subsequent high heating rate on the Maikop Formation and Diatom Suite is probably the most plausible way of explaining the origin of light hydrocarbons in the Guneshli and Bahar fields. 相似文献
12.
近年来示踪技术作为研究水动力和泥沙冲淤规律的工具得到越来越广泛的应用。示踪技术比传统的水文观测方法方便、准确。传统研究方法往往只能进行定点或走航采样监测,而示踪技术则能准确判定某一区域泥沙或水流的具体运动过程和最终运动结果,甚至给出定量的结论,从而为数学模型参数的确定提供有效的依据。Pujol使用3H监测西班牙Ebro河的横向扩散速率[1],Albert在Ebo河用同样的方法研究水 相似文献
13.
Faruk?AydinEmail author Axel?K.?Schmitt Wolfgang?Siebel Mustafa?S?nmez Yal??n?Ersoy Abdurrahman?Lermi Kadir?Dirik Robert?Duncan 《Contributions to Mineralogy and Petrology》2014,168(5):1078
The late Neogene to Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia is one of the most impressive volcanic fields of Turkey because of its extent and spectacular erosionally sculptured landscape. The late Neogene evolution of the CVP started with the eruption of extensive andesitic-dacitic lavas and ignimbrites with minor basaltic lavas. This stage was followed by Quaternary bimodal volcanism. Here, we present geochemical, isotopic (Sr–Nd–Pb and δ18O isotopes) and geochronological (U–Pb zircon and Ar–Ar amphibole and whole-rock ages) data for bimodal volcanic rocks of the Ni?de Volcanic Complex (NVC) in the western part of the CVP to determine mantle melting dynamics and magmatic processes within the overlying continental crust during the Quaternary. Geochronological data suggest that the bimodal volcanic activity in the study area occurred between ca. 1.1 and ca. 0.2 Ma (Pleistocene) and comprises (1) mafic lavas consisting of basalts, trachybasalts, basaltic andesites and scoria lapilli fallout deposits with mainly basaltic composition, (2) felsic lavas consisting of mostly rhyolites and pumice lapilli fall-out and surge deposits with dacitic to rhyolitic composition. The most mafic sample is basalt from a monogenetic cone, which is characterized by 87Sr/86Sr = 0.7038, 143Nd/144Nd = 0.5128, 206Pb/204Pb = 18.80, 207Pb/204Pb = 15.60 and 208Pb/204Pb = 38.68, suggesting a moderately depleted signature of the mantle source. Felsic volcanic rocks define a narrow range of 143Nd/144Nd isotope ratios (0.5126–0.5128) and are homogeneous in Pb isotope composition (206Pb/204Pb = 18.84–18.87, 207Pb/204Pb = 15.64–15.67 and 208Pb/204Pb = 38.93–38.99). 87Sr/86Sr isotopic compositions of mafic (0.7038–0.7053) and felsic (0.7040–0.7052) samples are similar, reflecting a common mantle source. The felsic rocks have relatively low zircon δ18O values (5.6 ± 0.6 ‰) overlapping mantle values (5.3 ± 0.3 %), consistent with an origin by fractional crystallization from a mafic melt with very minor continental crustal contamination. The geochronological and geochemical data suggest that mafic and felsic volcanic rocks of the NVC are genetically closely related to each other. Mafic rocks show a positive trend between 87Sr/86Sr and Th, suggesting simultaneous assimilation and fractional crystallization, whereas the felsic rocks are characterized by a flat or slightly negative variation. High 87Sr/86Sr gneisses are a potential crustal contaminant of the mafic magmas, but the comparatively low and invariant 87Sr/86Sr in the felsic volcanics suggests that these evolved dominantly by fractional crystallization. Mantle-derived basaltic melts, which experienced low degree of crustal assimilation, are proposed to be the parent melt of the felsic volcanics. Geochronological and geochemical results combined with regional geological and geophysical data suggest that bimodal volcanism of the NVC and the CVP, in general, developed in a post-collisional extensional tectonic regime that is caused by ascending asthenosphere, which played a key role during magma genesis. 相似文献
14.
This study provides a detailed account of the stepwise development of an empirical equation to estimate the number of lightning casualties in a given region. The factors considered in the development of the formula are; lightning density, population density and urbanization of a given region. The unknown constants of the equation have been evaluated by applying state-wise lightning death records and information on lightning density distribution in USA. The death figure per year due to lightning calculated for Sri Lanka using the empirical equation developed is in good agreement with the same figure reported for the country by actual data collected. The paper also discusses the limitations of the empirical equations that have been developed to calculate lightning density once the isokeraunic level is provided as the input parameter. 相似文献
15.
Asude Hanedar Kadir Alp Burcak Kaynak Jaemeen Baek Edip Avsar M. Talat Odman 《Atmospheric Research》2011,99(3-4):391-399
The chemical mass balance model was applied to atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) in Istanbul, Turkey. A total of 326 airborne samples were collected and analyzed for 16 PAHs and Total Suspended Particles (TSP) in the September 2006–December 2007 period at three monitoring stations: Yildiz, DMO (urban sites) and Kilyos (rural site). The total average PAH concentrations were 100.66 ± 61.26, 84.63 ± 46.66 and 25.12 ± 13.34 ng m?3 and the TSP concentrations were 101.16 ± 53.22, 152.31 ± 99.12, 49.84 ± 18.58 μg m?3 for Yildiz, DMO and Kilyos stations respectively. At all the sites, the lighter compounds were the most abundant, notably Nap, AcPy and PA. The average correlation values between TSP and total heavier PAH were greater than 0.5 for Yildiz and DMO stations. The patterns of PAH and TSP concentrations showed spatial and temporal variations. PAH concentrations were evaluated for the PAH contribution from four sources (diesel engines, gasoline engines, natural gas combustion, and coal + wood burning). Vehicle emissions appear to be the major source with contributions of 61.2%, 63.3% and 54.1% for Yildiz, DMO and Kilyos stations respectively. Seasonal and yearly variations had different trends for all sites. 相似文献
16.
Assessment of temporal variation and sources of PCBs in the sediments of Mediterranean Sea, Mersin Bay, Turkey 总被引：1，自引：0，他引：1
Information on temporal distribution of polychlorinated biphenyls (PCBs) in the coastal sediments of Mediterranean Sea, Mersin was compiled using data published between 1980 and 2009, and the present study. The first congener specific PCB results from the region yield concentration levels of Σ41PCBs in sediments ranging from 0.61 to 1.04 ng g−1. Sediment profiles show penta-, hexa- and hepta-chlorobiphenyls, specifically, #149 and 153 as the most abundant congeners in all samples. Comparison of total PCB concentrations over time suggests no recent PCB input to the region. Using congener specific PCB data for the region, identity and contribution of PCB sources were also predicted using a chemical mass balance -based (CMB) receptor model. The CMB model identified Aroclor 1260 to be the major PCB source in coastal sediments. The potential sources for the PCBs were briefly discussed in terms of their use in various industrial applications. 相似文献
17.
Mass movements are very common problems in the eastern Black Sea region of Turkey due to its climate conditions, geological, and geomorphological characteristics. High slope angle, weathering, dense rainfalls, and anthropogenic impacts are generally reported as the most important triggering factors in the region. Following the portal slope excavations in the entrance section of Cankurtaran tunnel, located in the region, where the highly weathered andesitic tuff crops out, a circular toe failure occurred. The main target of the present study is to investigate the causes and occurrence mechanism of this failure and to determine the feasible remedial measures against it using finite element method (FEM) in four stages. These stages are slope stability analyses for pre- and postexcavation cases, and remediation design assessments for slope and tunnel. The results of the FEM-SSR analyses indicated that the insufficient initial support design and weathering of the andesitic tuffs are the main factors that caused the portal failure. After installing a rock retaining wall with jet grout columns and reinforced slope benching applications, the factor of safety increased from 0.83 to 2.80. In addition to slope stability evaluation, the Rock Mass Rating (RMR), Rock Mass Quality (Q) and New Austrian Tunneling Method (NATM) systems were also utilized as empirical methods to characterize the tunnel ground and to determine the tunnel support design. The performance of the suggested empirical support design, induced stress distributions and deformations were analyzed by means of numerical modelling. Finally, it was concluded that the recommended stabilization technique was essential for the dynamic long-term stability and prevents the effects of failure. Additionally, the FEM method gives useful and reasonably reliable results in evaluating the stability of cut slopes and tunnels excavated both in continuous and discontinuous rock masses. 相似文献
18.
Influences of human activities and agriculture on groundwater quality of Kayseri-Incesu-Dokuzpınar springs,central Anatolian part of Turkey 总被引：3，自引：0，他引：3
Hatim?ElhatipEmail author Mustafa?Af?in lkay?Ku??u Kadir?Dirik Yakup?Kurma? Murat?Kavurmac? 《Environmental Geology》2003,44(4):490-494
Human activities and agriculture have had direct and indirect effects on the rates of contamination of groundwater in the Incesu-Dokuzp inar spring area. Direct effects include dissolution and transport of excess quantities of fertilizers with associated materials and hydrological alterations related to irrigation and drainage. Indirect effects may include changes in water–rock reactions in soils and aquifers caused by increased concentrations of dissolved oxidants, protons, and major ions. Agricultural activities have directly or indirectly affected the concentrations of a large number of inorganic chemicals in groundwater, for example NO 3, N 2, Cl, SO 4 2, H +, K, Mg, Ca, Fe, Cu, B, Pb, and Zn, as well as a wide variety of pesticides and other organic compounds. For reactive contaminants like NO 3, it is recommended that a combination of hydrochemical and environmental-tracer analytical approaches might be required to resolve changing inputs from subsequent alterations as causes of concentration gradients in groundwater. The water type of Dokuzp inar springs is mainly Na–Mg–Ca–Cl–HCO 3. Note that the water types of the springs were directly related to the hydrogeochemical properties of outcrops at the study area. Thus, the high concentration of Ca 2+ and HCO 3 is mainly related to the high CO 2 contents in the marbles, whereas the high Na concentration arises from the existing syenite, volcanic ash, basalt, and clay units, although the Incesu-Dokuzp inar springs cover most of the drinking and irrigation water demands of this area. The high concentrations of NO 3 and NaCl show that the area around the springs is continuously being contaminated by untreated sewage and agricultural wastes, especially during dry periods. Therefore, this approach is based on the vulnerability studies of the catchment area, determination of the transfer time of the pollutant, and the water-bearing formations of Incesu-Dokuzp inar springs. Vulnerability in this study is defined as the intrinsic hydrogeochemical characteristics of an aquifer, which may show the sensitivity of groundwater to be contaminated by different human activities. 相似文献
19.
This paper deals with the dissolution of magnesia in aqueous carbon dioxide, in the absence and presence of ultrasound. The particle size, reaction temperature and solid / liquid ratio were chosen parameters. The reaction was homogeneous first-order reaction model according to kinetic data and the activation energy was found to be 17.5 kJ/mol in both cases. The effect of ultrasound is on the pre-exponential factor A in the Arrhenius equation. An empirical relation was also given, which relates the rate constant to ultrasound power. 相似文献
20.
Kadir Gürgey Bernd R.T. Simoneit Zühtü Batı İsmail H. Karamanderesi Baki Varol 《Applied Geochemistry》2007
The KB-5 well is located at the intersection of the geothermally active Menderes and Gediz graben systems in western Turkey. Significant volumes of “petroleum-like material” (PLM) with its associated thermal water (120 °C) erupted onto the surface during drilling from a depth of 120–132 m (i.e., from the claystone and marl-rich Early to Middle Pliocene Kolonkoya formation). The purpose of this paper is: (1) to characterize this PLM, (2) to assess the source characteristics from which the PLM was likely generated, and (3) to recognize the generation mechanism considering the geothermal-gradual versus the hydrothermal-rapid processes. Analytical organic geochemistry using thin layer chromatographic separation followed by gas chromatography–mass spectrometry (GC–MS) was carried out. 相似文献