Quick clay—A case study of chemical perspective in Southwest Sweden     

Yvonne Andersson-Sköld  J. Kenneth Torrance  Karin Odén  Karin Rankka 《Engineering Geology》2005,82(2):107-118

Quick clay, a soil that changes from normal firm ground to a liquid mass when it is disturbed, has been involved in most of the large and serious clay slides in Sweden, Norway and Canada. The location, time of occurrence and size of quick clay slides are difficult to predict and large slides may cause great devastation. Some geochemical studies of Swedish quick clay were done in the 1960s and early 1970s, but no systematic studies of the interrelationships of pore water chemistry, mineralogy, geotechnical properties and other parameters on quick clays in Sweden have been published. Such studies are of national and general interest because of the many combinations of rock flour source areas and sedimentation conditions that occurred across central Sweden and into the Baltic Sea area during deglaciation. In this study, geotechnical properties related to the in situ chemistry at one quick clay site were extensively studied, and spot sampling was conducted at two other locations in Southwest Sweden. In this area the clay minerals mainly are non-expanding phyllosilicate minerals (illite) and primary minerals (quartz, feldspar), which is consistent with previous studies of quick clay mineralogy. Extensive leaching has occurred at all three locations. At the extensively studied site, Surte, the lowest salinity was found at the greatest depth, inferring that the leaching by fresh water was accomplished by water movement upward and laterally through the sediment from the underlying bedrock. This is consistent with the local setting where bedrock hills rise sharply to over 100 m above the marine sediment surface. An artesian pressure would also be anticipated at this location. There is a correlation (negative) between sensitivity and salinity but there is an indication that the maximum salinity or electrical conductivity consistent with the quick clay behaviour is higher than reported elsewhere. However, for high sensitivities the salinity is about the same as reported elsewhere. In the deepest part of the borehole, there is a higher content of Fe and Al in the pore water, indicating reduced state. Further work is needed to confirm the difference in salinity and to investigate the possible interplay of salinity and potential dispersing agents such as the role of anoxic conditions, in this region. Further work is especially needed in the locations where the sediment accumulation occurred under lower salinity conditions. At all three locations, high remoulded shear strength and low sensitivity have been seen near the surface together with a decrease in pore water cation concentrations.  相似文献   

Environmental changes in an alpine lake (Gossenköllesee, austria) over the last two centuries – the influence of air temperature on biological parameters     

Karin A. Koinig  Christian Kamenik  Roland Schmidt  Anna Agustí-Panareda  Peter Appleby  Andrea Lami  Miroslava Prazakova  Neil Rose  Øyvind A. Schnell  Richard Tessadri  Roy Thompson  Roland Psenner 《Journal of Paleolimnology》2002,28(1):147-160

Changes in microfossils (diatoms, chrysophytes, chironomids and cladocera remains), geochemistry and deposition of atmospheric pollutants have been investigated in the sediment records of the alpine lake Gossenköllesee (Tyrol, Austria) spanning the last two centuries. The sediment records were compared with seasonal and annual air temperature trends calculated for the elevation (2417 m a.s.l.) and the geographical position (47° 1346N, 11° 0051E) of the lake, and with precipitation records available since 1866 from Innsbruck. Temperature trends followed a 20–30 year oscillation between cold and warm periods. Regarding long-term changes, temperature trends showed a U-shaped trend between 1780 and 1950, followed by a steep increase since 1975.Physical, geochemical, and organic parameters were not controlled by air temperature. Among the biological records only diatoms and chrysophytes reacted to air temperature changes: the relative abundance of planktonic diatoms increased during warm periods and changes in mean annual alpine air temperature explained 36.5% of their variation. The relation between abundance of seasonal stomatocyst types and air temperature varied on two different time scales: while summer stomatocysts were influenced by short term temperature fluctuations, the autumn stomatocysts were affected only by the long term changes. Other biological parameters exhibited a constant species composition (chironomids, pigments) or changes were small and independent of temperature (cladocera). Spheroidal carbonaceous fly-ash particles, and trends in Pb and Cr indicated increasing deposition of atmospheric pollutants but had no detectable effects on the biological parameters either. In respect to temperature variations over the last 200 years, this alpine lake is much less sensitive than expected and has thus to be regarded as a well buffered site. However, temperature alone is not sufficient to understand changes in species composition and other biogeochemical processes with unknown historical patterns might have affected species composition more strongly.  相似文献   

Gaseous and Particulate Oxidized and Reduced Nitrogen Species in the Atmospheric Boundary Layer in Scandinavia in Spring     

Asgeir Sorteberg  Øystein Hov  Sverre Solberg  Kjetil Tørseth  Hans Areskoug  Martin Ferm  Kit Granby  Heikki Lättilä  Karin Persson  David Simpson 《Journal of Atmospheric Chemistry》1998,30(2):241-271

Observations of the concentration of several nitrogen containing compounds at five rural Scandinavian sites during March–June 1993 are reported. Total nitrate (NO ₃ ^- + HNO₃) and total ammonium (NH ₄ ⁺ + NH₃) were measured by denuder and filter pack. In general the methods agree well. At all sites the particulate fraction dominated, with the largest fraction of NO ₃ ^- and the lowest of NH ₄ ⁺ at the sites which were closest to the emission sources. The fraction of NO ₃ ^- of total nitrate increased with increasing NO₂ concentrations, indicating that the nighttime conversion of NO₂ to NO ₃ ^- is an important route of formation for NO ₃ ^- . A positive correlation was found between HNO₃ and O₃ in June at all sites, while no correlation was found early in the spring. Model calculations were made with a lagrangian boundary layer photooxidant model for the whole period, and compared to the measured concentrations. The calculated ratio between mean observed and modelled daily maximum concentrations of ozone over the measurement period were within +/–10% at all sites. The models ability to describe the daily ozone maximum concentration was satisfactory with an average deviation of 19–22% from the observed concentrations. HNO₃ was underestimated by over 50% at all sites except the one closest to the emission sources. The correlation between modelled and observed concentrations was generally best for the sites with shortest transport distance from the sources of emission.  相似文献   

Modelling of uranium and neptunium chemistry in a deep rock environment     

Iréne Lundén  Karin Andersson  Gunnar Skarnemark 《Aquatic Geochemistry》1996,2(4):345-358

According to the present concept for final storage of spent nuclear fuel in Sweden, the spent fuel, encapsulated in copper or copper/steel canisters, will be placed in tunnels in a deep rock formation. The canisters will be surrounded by compacted bentonite clay acting as a buffer material. In connection with a safety analysis of such a storage facility, the total solubility of certain elements (e.g., uranium) as well as the transport properties (e.g., retardation due to sorption on mineral surfaces) of the long-lived radionuclides released from the canister have to be predicted or measured. The chemical conditions, governing the solubility and speciation of trace elements encountered in and around the repository depend on interactions between the ground water and the engineering materials in the repository and a production of oxidants due to radiolysis in the spent fuel. In the present study the speciation and solubility of uranium and neptunium in a bentonite-ground water system and in ground waters with compositions measured at a site at äspö, SE Sweden, have been calculated. The calculations have been carried out using a recent version of the geochemical computer code PHREEQE and the database HATCHES 5.0. Predictions of the uranium and neptunium concentrations in the ground water in the vicinity of a damaged high level waste repository have also been performed. The uranium concentration in the water in the bentonite barrier is predicted to be of the same order of magnitude or lower than that found in some granitic ground waters. For neptunium the calculations are uncertain due to the small amount of experimentally determined thermodynamic data and few verifications under the conditions (pH - Eh - carbonate concentration) considered. The predicted concentrations (ca 10^–12 m, corresponds to ca 0.006 Bq/l) may be regarded as high, considering the high toxicity of neptunium and its long half-life.  相似文献   

Warming at 18,000 yr B.P. in the Tropical Andes     

Karin F. Helmens  Peter Kuhry  Nathaniel W. Rutter  Klaas Van Der Borg  Arie F. M. De Jong 《Quaternary Research》1996,45(3):289-299

Palynological, paleopedological, and glacial geomorphological evidence from the area of the high plain of Bogotá in the Colombian Eastern Cordillera indicates a significant climatic warming around 18,000¹⁴C yr B.P. Comparison of dated vegetation changes, pedogenic episodes, and glacier fluctuations provides the basis for defining the so-called “La Laguna Interstadial” that lasted from 19,500 to 17,000 yr B.P. During this interstadial period, mean annual temperatures in the tropical Andes were up to 4°C higher than during the preceding and following stadial periods, when full-glacial conditions prevailed and temperatures were up to 8°C colder than at present.  相似文献   

Growth and mortality rates of larval American shad,Alosa sapidissima,at different salinities     

Karin E. Limburg  Robert M. Ross 《Estuaries and Coasts》1995,18(2):335-340

The tolerance of post yolk-sac American shad Alosa sapidissima larvae to salinities typically seen in estuaries was assessed experimentally. Sixteen-day-old Hudson River (experiment I) and 35-d-old Delaware River (experiment II) larvae were held for 8 d and 9 d respectively in low (0–1‰), medium (9–11‰), and highly (19–20‰) brackish water, and mortality and growth rates were measured. Growth rates did not vary significantly among salinity treatments. Mortality in experiment I did not vary significantly among salinity treatments however, in experiment II, mortality was zero at 10‰ but higher and statistically indistinguishable between 0‰ and 20‰ In experiment II relative condition increased with salinity. These results imply that estuarine salinities neither depress growth rates nor elevate mortality rates of larval American shad when compared with freshwater conditions. We conclude that ecological factors other than the physiological effects of salinity have played more important roles in the evolution of the upriver spawning and nursery preference shown by this species.  相似文献   

Assessing streams in Germany with benthic invertebrates: development of a practical standardised protocol for macroinvertebrate sampling and sorting   总被引：4，自引：0，他引：4  

Peter Haase  Susanne Lohse  Steffen Pauls  Karin Schindehütte  Andrea Sundermann  Peter Rolauffs  Daniel Hering 《Limnologica》2004,34(4):349-365

In the past, no single standardised method for sampling and sorting benthic macroinvertebrates has been implemented in Germany. Therefore, we tested the suitability of two common sorting protocols, RIVPACS and AQEM/STAR, by taking samples with each protocol at 44 sampling sites. Our results reveal that different methods deliver slightly different assessment results. Moreover these two methods differ in costs. Although the AQEM/STAR protocol takes longer than the RIVPACS protocol, we favoured the AQEM/STAR protocol because of its higher level of standardisation. In order to limit costs to an acceptable level, a modification of the AQEM/STAR protocol (MAS method) is developed. This method is highly standardised, gives stable assessment results and is relatively inexpensive (€ 224.00 for processing of an average sample). A detailed protocol of the newly developed method is given.  相似文献   

Re–Os and Pb–Pb geochronology of the Archean Salobo iron oxide copper–gold deposit, Carajás mineral province, northern Brazil     

Karin Requia  Holly Stein  Lluís Fontboté  Massimo Chiaradia 《Mineralium Deposita》2003,38(6):727-738

Rhenium–osmium ages were determined for two molybdenite samples and a Pb–Pb age was derived from bornite–chalcopyrite–magnetite at the Salobo iron oxide copper–gold deposit to determine the timing of mineralization and its relation to the nearby Old Salobo Granite. Rhenium–osmium dating of molybdenite spatially associated with copper sulfide minerals yields ages with weighted means of 2576±8 and 2562±8 Ma. Removing the error multiplier introduced by the decay constant uncertainty, appropriate for comparing ages from the same isotopic system, these data convincingly argue for two temporally separated pulses of molybdenite deposition at 2576.1±1.4 Ma (n=2) and 2561.7±3.1 Ma (n=3). The 2576±8 Ma age coincides with a previously published U–Pb age of 2573±2 Ma for the Old Salobo Granite, suggesting that main stage ore formation may have been contemporaneous with granite magmatism. The slightly younger 2562 Ma age most likely represents new molybdenite precipitation associated with the development or reactivation of local shear zones. Lead–lead stepwise leaching of copper sulfide minerals yields a less precise isochron age of 2579±71 Ma, and supports an Archean age for the Salobo ores. This is the first documentation of an Archean iron oxide copper–gold deposit, and the Re–Os and Pb–Pb geochronology herein support 2580–2550 Ma estimates for basement reactivation and regional granite magmatism associated with the development of brittle–ductile shear zones.  相似文献   

Application of the weight-of-evidence approach to assess the decline of brown trout (<Emphasis Type="Italic">Salmo trutta</Emphasis>) in Swiss rivers     

Patricia Burkhardt-Holm  Karin Scheurer 《Aquatic Sciences - Research Across Boundaries》2007,69(1):51-70

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Accumulation of organochlorines and brominated flame retardants in estuarine and marine food chains: field measurements and model calculations     

Veltman K  Hendriks J  Huijbregts M  Leonards P  van den Heuvel-Greve M  Vethaak D 《Marine pollution bulletin》2005,50(10):1085-1102

Food chain accumulation of organochlorines and brominated flame retardants in estuarine and marine environments is compared to model estimations and fresh water field data. The food chain consists of herbivores, detritivores and primary and secondary carnivores i.e. fish, fish-eating birds and marine mammals. Accumulation of polychlorinated biphenyls is predicted well by OMEGA for herbi-detritivores and primary and secondary carnivorous fish. Ratios are similar to those found for fresh water species. Accumulation ratios for fish-eating birds and mammals are overestimated by the model, which is attributed partly to biotransformation of meta-para unsubstituted congeners. Additionally, birds may feed in other less polluted areas. For brominated diphenylethers (BDE) accumulation patterns are highly species and congener specific. Accumulation depends on both K(ow) and metabolization capacities. BDE47 is the predominant congener in lower trophic levels. For marine birds and mammals accumulation ratios of BDE99 and 100 are similar to or higher than ratios of persistent PCBs.  相似文献