On the interest of using field primary production data to calibrate phytoplankton rate processes in ecosystem models     

Karine Grangeré  Sébastien Lefebvre  Alain Ménesguen  Fabien Jouenne 《Estuarine, Coastal and Shelf Science》2009

In many ecosystem models based on empirical formulations, parameters generally are calibrated in order to achieve the best fit between measured and simulated chlorophyll a standing stocks. An accurate calibration of rate processes as primary production rarely is taken into account. In this paper, we test the usefulness of calibration of phytoplankton photosynthetic processes in an ecosystem model using field primary production data. We used 18 months of photosynthetic process data from the Baie des Veys ecosystem (Normandy, France). Five empirical formulations of photosynthesis–irradiance curve models amongst the most widely used were tested. In each formulation, the variability of photosynthetic parameters (i.e. the light-saturated rate of photosynthesis (P_max^B) and the initial slope of the photosynthesis–light curve (α^B)) was considered depending on environmental factors (temperature and nutrient availability). The fit of the five equations as well as the calibration of parameters on field measurements (i.e. the light-saturated rate of photosynthesis (P_ref^B), the initial slope of the photosynthesis–light curve (α_ref^B), the half-saturation constant for nitrogen (K_N) and silicates uptake (K_Si), and the coefficient in the exponential thermal effect (K_T)) was performed using the whole available data set of P vs. E curves (n = 143, P vs. E curves). Then, the Smith formulation allowing the best simulation of the Baie des Veys primary production and corresponding parameters were introduced in an ecosystem box model. This formulation led directly to a satisfactory representation of the Baie des Veys phytoplankton dynamics without additional calibration. Results obtained were compared with a more classical approach in which ecosystem models were calibrated using published values of parameters. This comparison showed that for the two years studied, annual primary production estimated through the ecosystem model was 13% and 26% higher with our approach than with the more classical approach. This work emphasizes the importance of accurately representing rate processes in ecosystem models in order to adequately simulate production as well as standing stocks.  相似文献   

Accounting for evolving pore size distribution in water retention models for compacted clays          下载免费PDF全文

Gabriele Della Vecchia  Anne‐Catherine Dieudonné  Cristina Jommi  Robert Charlier 《国际地质力学数值与分析法杂志》2015,39(7):702-723

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Role of the volatile fraction of submicron marine aerosol on its hygroscopic properties     

Karine Sellegri  Paolo Villani  David Picard  Regis Dupuy  Colin O'Dowd  Paolo Laj 《Atmospheric Research》2008,90(2-4):272-ICNAA07

The hygroscopic growth factor (HGF) of 85 nm and 20 nm marine aerosol particles was measured during January 2006 for a three-week period within the frame of the EU FP6 project MAP (Marine Aerosol Production) winter campaign at the coastal site of Mace Head, using the TDMA technique. The results are compared to aerosol particles produced in a simulation tank by bubbling air through sea water sampled near the station, and through synthetic sea water (inorganic salts). This simulation is assimilated to primary production. Aitken and mode particles (20 nm) and accumulation mode particles (85 nm) both show HGF of 1.92 and 2.01 for particles generated through bubbling in natural and artificial sea water respectively. In the Aitken mode, the marine particles sampled in the atmosphere shows a monomodal HGF slightly lower than the one measured for sea salt particles artificially produced by bubble bursting in natural sea water (HGF = 1.83). This is also the case for the more hygroscopic mode of accumulation mode particles. In addition, the HGF of 85 nm particles observed in the atmosphere during clean marine sectors exhibits half of its population with a 1.4 HGF. An external mixture of the accumulation mode marine particles indicates a secondary source of this size of particles, a partial processing during transport, or an inhomogeneity of the sea water composition. A gentle 90 °C thermo-desorption results in a significant decrease of the number fraction of moderately hygroscopic (HGF = 1.4) particles in the accumulation mode to the benefit of the seasalt mode, pointing to the presence of semi-volatile compounds with pronounced hydrophobic properties. The thermo-desorption has no effect on the HGF of bubble generated aerosols, neither for synthetic or natural sea water, nor on the atmospheric Aitken mode, indicating that these hydrophobic compounds are secondarily integrated in the particulate phase. No difference between night and day samples is observed on the natural marine aerosols regarding hygroscopicity, but a more pronounced sensitivity to volatilization of the 1.4 HGF mode in the accumulation mode is observed during the day.  相似文献   

Does sediment resuspension by storms affect the fate of polychlorobiphenyls (PCBs) in the benthic food chain? Interactions between changes in POM characteristics, adsorption and absorption by the mussel Mytilus galloprovincialis   总被引：1，自引：0，他引：1  

Franois Charles  Susanna Lopez-Legentil  Antoine Grmare  Jean Michel Amouroux  Martin Desmalades  Gilles Vtion  Karine Escoubeyrou 《Continental Shelf Research》2005,25(19-20):2533

Environmental parameters and gross sedimentation rates (GSR) were monitored at a fixed site located in the Bay of Banyuls-sur-Mer (NW Mediterranean), between March 1997 and April 1998, together with the main biochemical characteristics of both sedimenting and sedimented particulate organic matter (POM). Three storms which occurred during this time period resulted in natural sediment resuspension. This is indicated by the corresponding increase in GSR and a decrease in the enzymatically hydrolysable amino acids/totally hydrolysable amino acids ratio (EHAA/THAA), within the sedimenting POM. Only the strongest storm resulted in (1) a transitory increase in fine-grained particles, (2) concomitant increases in organic carbon, carbohydrates, lipids and THAA, and (3) a decrease in the EHAA/THAA ratio in surficial sediments. For most of the assayed parameters, the values recorded after the December 1997 storm corresponded to extremes for the whole period under study. This emphasises the role of storms in controlling the characteristics of sedimented and sedimenting POM.Ten sediment types, with contrasting biochemical characteristics, were selected for experiments; these were based on the results of the monitoring survey and were used during adsorption and absorption experiments involving ¹⁴C tetrachlorobiphenyl (TCB). Adsorption rates differed significantly between the sediment types, but did not correlate with any of the assayed biochemical parameters. Absorption efficiency by the mussel Mytilus galloprovincialis also differed between the sediment types; it correlated positively with all the assayed biochemical parameters, except lipids. Comparison between the magnitudes of the increase in GSR, together with the decrease in absorption efficiency during resuspension events, suggests that resuspension tends to enhance the transfer of organic pollutants in the benthic food chain.  相似文献   

Geochemistry of cumulates from the Bjerkreim–Sokndal layered intrusion (S. Norway). Part I: Constraints from major elements on the mechanism of cumulate formation and on the jotunite liquid line of descent     

J.C. Duchesne  B. Charlier 《Lithos》2005,83(3-4):229-254

Whole-rock major element compositions are investigated in 99 cumulates from the Proterozoic Bjerkreim–Sokndal layered intrusion (Rogaland Anorthosite Province, SW Norway), which results from the crystallization of a jotunite (Fe–Ti–P-rich hypersthene monzodiorite) parental magma. The scattering of cumulate compositions covers three types of cumulates: (1) ilmenite–leuconorite with plagioclase, ilmenite and Ca-poor pyroxene as cumulus minerals, (2) magnetite–leuconorite with the same minerals plus magnetite, and (3) gabbronorite made up of plagioclase, Ca-poor and Ca-rich pyroxenes, ilmenite, Ti-magnetite and apatite. Each type of cumulate displays a linear trend in variation diagrams. One pole of the linear trends is represented by plagioclase, and the other by a mixture of the mafic minerals in constant proportion. The mafic minerals were not sorted during cumulate formation though they display large density differences. This suggests that crystal settling did not operate during cumulate formation, and that in situ crystallization with variable nucleation rate for plagioclase was the dominant formation mechanism. The trapped liquid fraction of the cumulate plays a negligible role for the cumulate major element composition. Each linear trend is a locus for the cotectic composition of the cumulates. This property permits reconstruction by graphical mass balance calculation of the first two stages of the liquid line of descent, starting from a primitive jotunite, the Tjörn parental magma. Another type of cumulate, called jotunite cumulate and defined by the mineral association from the Transition Zone of the intrusion, has to be subtracted to simulate the most evolved part of the liquid line of descent. The proposed model demonstrates that average cumulate compositions represent cotectic compositions when the number of samples is large (> 40). The model, however, does not account for the K₂O evolution, suggesting that the system was open to contamination by roof melts. The liquid line of descent corresponding to the Bjerkreim–Sokndal cumulates differs slightly from that obtained for jotunitic dykes in that the most Ti-, P- and Fe-rich melts (evolved jotunite) are lacking. The constant composition of the mafic poles during intervals where cryptic layering is conspicuous is explained by a compositional balance between the Fe–Ti oxide minerals, which decrease in Fe content in favour of Ti, and the pyroxenes which increase in Fe.  相似文献   

Low-latitude “dusty events” vs. high-latitude “icy Heinrich events”     

Elsa Jullien  Francis Grousset  Bruno Malaiz  Josette Duprat  Maria Fernanda Sanchez-Goni  Frdrique Eynaud  Karine Charlier  Ralph Schneider  Aloys Bory  Viviane Bout  Jose Abel Flores 《Quaternary Research》2007,68(3):379-386

It has been proposed that tropical events could have participated in the triggering of the classic, high-latitude, iceberg-discharge Heinrich events (HE). We explore low-latitude Heinrich events equivalents at high resolution, in a piston core recovered from the tropical north-western African margin. They are characterized by an increase of total dust, lacustrine diatoms and fibrous lacustrine clay minerals. Thus, low-latitude events clearly reflect severe aridity events that occurred over Africa at the Saharan latitudes, probably induced by southward shifts of the Inter Tropical Convergence Zone. At a first approximation, it seems that there is more likely synchronicity between the high-latitude Heinrich Events (HEs) and low-latitude events (LLE), rather than asynchronous behaviours.  相似文献   

Rapid open-system assembly of a large silicic magma body: time-resolved evidence from cored plagioclase crystals in the Oruanui eruption deposits, New Zealand   总被引：2，自引：1，他引：1  

B. L. A. Charlier  C. J. N. Wilson  J. P. Davidson 《Contributions to Mineralogy and Petrology》2008,156(6):799-813

Rhyolitic pumices in the 26.5 ka Oruanui eruption (Taupo volcano, New Zealand) contain an average of 10 wt% crystals. About 2 wt% of the crystal population is feldspar crystals that display bluish–grey cloudy cores, the colour being imparted by exsolved needles of rutile. The volume of cloudy-cored feldspars thus amounts to ~1.0 km³ in a total magma volume of ~530 km³. The cored feldspars show great variability in detail, but in general have a rounded cloudy core bounded by a zone rich in glass and mineral inclusions, that was then overgrown by a euhedral clear rim. Sr-isotopic variations in eight representative crystals were measured on micromilled samples of selected growth zones in the cores and rims, and linked to feldspar compositions through microprobe traverses. The cloudy cores range from ⁸⁷Sr/⁸⁶Sr = 0.70547 to 0.70657, with compositions of An₄₃ to An₇₈. The overgrowth rims display wider variations: inner parts show extreme ranges in composition (maxima ⁸⁷Sr/⁸⁶Sr = 0.70764 and An₇₈), while outer parts in seven of eight crystals are zoned, with outward-decreasing Sr-isotopic and An values to figures that are in accord with the bulk pumice and other, clear-feldspar values, respectively. The three parts of the crystals represent distinct regimes. The cloudy cores are inherited from an intermediate plutonic protolith that has been subjected to melting. The inner overgrowth rims were crystallised from a high temperature, relatively radiogenic melt derived from Mesozoic-Palaeozoic metasedimentary rocks (“greywacke”). The outer euhedral rims reflect mixing into and continued growth within the growing Oruanui magma body. The cloudy-cored feldspars also contain rare zircon inclusions. Twenty one zircons were recovered by HF digestion of a bulk sample of cloudy feldspars and analysed by SHRIMP for U–Th isotopes with which to calculate model ages. Eighteen of 21 crystals returned finite ages, the model-age spectrum of which is similar to the age spectra from free zircons in Oruanui pumices. Assembly of the Oruanui magma body was not only rapid (over ~40 kyr, as shown by other data) but involved a wide open system, with significant contributions from partly-melted intermediate-composition igneous intrusions (cloudy cores) and greywacke melts (inner overgrowths) being introduced into the magma body up to the point of eruption. Such open system behaviour contrasts with that proposed in models for comparably voluminous silicic magmas derived dominantly by fractionation (such as the Bishop Tuff) where the magma and its crystal cargo were better insulated thermally and chemically from country-rock interaction.  相似文献   

Functioning and precipitation-displacement modelling of rainfall-induced deep-seated landslides subject to creep deformation   总被引：2，自引：2，他引：0  

A. Vallet  J. B. Charlier  O. Fabbri  C. Bertrand  N. Carry  J. Mudry 《Landslides》2016,13(4):653-670

We propose an approach to study the hydro-mechanical behaviour and evolution of rainfall-induced deep-seated landslides subjected to creep deformation by combining signal processing and modelling. The method is applied to the Séchilienne landslide in the French Alps, where precipitation and displacement have been monitored for 20 years. Wavelet analysis is first applied on precipitation and recharge as inputs and then on displacement time-series decomposed into trend and detrended signals as outputs. Results show that the detrended displacement is better linked to the recharge signal than to the total precipitation signal. The infra-annual detrended displacement is generated by high precipitation events, whereas annual and multi-annual variations are rather linked to recharge variations and thus to groundwater processes. This leads to conceptualise the system into a two-layer aquifer constituted of a perched aquifer (reactive aquifer responsible of high-frequency displacements) and a deep aquifer (inertial aquifer responsible of low-frequency displacements). In a second step, a new lumped model (GLIDE) coupling groundwater and a creep deformation model is applied to simulate displacement on three extensometer stations. The application of the GLIDE model gives good performance, validating most of the preliminary functioning hypotheses. Our results show that groundwater fluctuations can explain the displacement periodic variations as well as the long-term creep exponential trend. In the case of deep-seated landslides, this displacement trend is interpreted as the consequence of the weakening of the rock mechanical properties due to repeated actions of the groundwater pressure.  相似文献   

The influence of tidal streams on the pre-spawning movements of atlantic herring, Clupea harengus L., in the St Lawrence estuary     

Lacoste  Karine N.; Munro  Jean; Castonguay  Martin; Saucier  Francois J.; Gagne  Jacques A. 《ICES Journal of Marine Science》2001,58(6):1286-1298

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Tourism and the coastal zone: The case of Belgium     

Roger H. Charlier  Christian P. De Meyer 《Ocean & Coastal Management》1992,18(2-4)

The economic and human importance of the coastal zone, which is already considerable, is destined to increase rapidly as we near the next century. Owing to natural causes, compounded by anthropogenic actions, it is also under threat: erosion is steadily pushing back the shoreline. Tourism and shore recreation, major sources of income in the zone, are threatened. Various countermeasures have been taken, but often with disappointing results. Beach nourishment has shown great promise. The largest of such undertakings has recently been completed along a stretch of the Belgian coast.  相似文献