Application of electron paramagnetic resonance spectroscopy to examination of carbonized coal blends     

B. Pilawa  S. Pusz  M. Krzesi&#x;ska  A. Koszorek  B. Kwieci&#x;ska 《International Journal of Coal Geology》2009,77(3-4):372-376

Paramagnetic centers in two- and three-component coal blends carbonized at 1000 °C were studied by X-band (9.3 GHz) electron paramagnetic resonance (EPR) technique. The blends were prepared from three different Polish coals with carbon contents [wt.%]: 88.66, 86.21, and 82.67, respectively. The aim of this work was to compare EPR parameters and concentrations of paramagnetic centers in the initial and carbonized coal samples. Furthermore the spin–spin and spin–lattice interactions were characterized.EPR spectra were measured with magnetic modulation 100 kHz and microwave power 0.7 mW. Amplitudes and linewidths of EPR spectra were obtained. g-Factors were calculated from resonance condition. Concentrations of paramagnetic centers in the samples were determined. Influence of microwave power in the range 0.7–70 mW on EPR spectra was analyzed.All the studied samples revealed paramagnetism. Unpaired electrons are localized in the same atoms, because similar g-values in the range 2.0035–2.0038 were obtained for all the original samples. The EPR parameters of coal blends were additive in comparison with the parent coals. EPR spectra strongly changed after carbonization of the coal samples. Narrower EPR lines were measured for the original coal samples than for carbonized ones. We detected lower concentrations of paramagnetic centers in carbonized three-component coal blends than in two-component carbonized blends. EPR lines of the studied carbonized blends were not saturated at the microwave power used, which suggests fast spin–lattice relaxation processes in the samples. EPR examination proved chemical interactions between coal constituents during carbonization of coal blends.  相似文献   

Binary gas sorption/desorption experiments on a bituminous coal: Simultaneous measurements on sorption kinetics,volumetric strain and acoustic emission     

Zofia Majewska  Grażyna Ceglarska-Stefańska  Stanisław Majewski  Jerzy Ziętek 《International Journal of Coal Geology》2009,77(1-2):90-102

There is still no clear understanding of the specific interactions between coal and gas molecules. In this context sorption–desorption studies of methane and carbon dioxide, both in a single gas environment and gas mixtures, are of fundamental interest. This paper presents the results of unique simultaneous measurements of sorption kinetics, volumetric strain and acoustic emission (AE) on three tetragonal coal samples subjected to sorption of carbon dioxide and methane mixtures. The coal was a high volatile bituminous C coal taken from the Budryk mine in the Upper Silesia Basin, Poland. Three different gas mixtures were used in the sorption tests, with dominant CO₂, with dominant CH₄ and a 50/50 mixture.The experimental set-up was designed specially for this study. It consisted of three individual units working together: (i) a unit for gas sorption experiments using a volumetric method, (ii) an AE apparatus for detecting, recording and analysing AE, and (iii) a strain meter for measuring strains induced in the coal sample by gas sorption/desorption. All measurements were computer aided.The experiments indicated that the coal tested showed preferential sorption of CH₄ at 2.6 MPa pressure and exhibited comparable affinities for CH₄ and CO₂ at higher pressures (4.0 MPa). The results of chromatographic analysis of the gas released on desorption suggested that the desorption of methane from the coal was favoured. The relationship between the volumetric strain and the amount of sorbed gas was found to be non-linear. These results were contrary to common opinions on the coal behaviour. Furthermore, it appeared that the swelling/shrinkage of coal was clearly influenced by the network of fractures. Besides, the AE and strain characteristics suggested common sources of sorption induced AE and strain.The present results may have implications for the sequestration of carbon dioxide in coal seams and enhanced coalbed methane recovery (ECBM).  相似文献   

Das Neokom in Polen und seine paläogeographische Bedeutung     

Jan Lewiński 《International Journal of Earth Sciences》1932,23(5):258-276

Zusammenfassung Die geologische Geschichte Nordwest-Polens zur Zeit der unteren Kreide kann in allgemeinen Zügen folgenderma\en dargestellt werden:Gegen Ende des Jura, ungefähr zur Zeit des Münder Mergels, sind hier Bewegungen eingetreten, die das Land teilweise trockengelegt und der Denudation preisgegeben haben. In den durch die Bewegungen gebildeten Senken blieben Lagunen erhalten, deren einige brackisches Wasser führten, während in anderen durch Eindampfung Gipslager abgesetzt wurden. Der Serpulit brachte eine positive Meeresbewegung mit, die sich im Infravalanginian derart verstärkte, da\ sich seine Ablagerungen nicht nur in den alten Senken kontinuierlich auf dem Serpulit abgesetzt, sondern auch auf denudierte, früher gehobene Schollen transgressiv ausgebreitet haben. Die Infravalanginian-See war brackisch und hat in NW-Polen typische Wealdenablagerungen abgesetzt, bei Tomaszów aber, etwas südlicher, ist das Infravalangian zwar litoral, aber rein marin ausgebildet, wobei es viele ähnlichkeit mit dem Infravalangian der Teschener Karpathen aufweist. Die Wealdensee und das karpathische Meer waren durch einen Sund verbunden, der sich über Tomaszów längs dem Polnischen Mittelgebirge gegen die Karpathen hinzog. Im Valanginian erreicht die neokome Transgression ihren Höhepunkt, es werden dunkle Tone mit reicher Hilsfauna abgesetzt; wahrscheinlich hat sich diese Transgression von Ru\land über die Polesje-Schwelle und über das westliche Polen nach Deutschland und weiter bis nach Ost-England erstreckt. Das polnische Becken stand in direkter Verbindung mit dem nordwestdeutschen; es war ebenfalls, obwohl dürftiger, mit dem karpathischen Meere verbunden; gerade hier ist der Weg zu suchen, den die Migrationen der nördlichen Elemente ins alpine Becken eingeschlagen haben. Im oberen Valanginian fängt eine Regression an, die in Zentral-Ru\land einsetzt und zu dessen Trockenlegung und zum Abschlu\ der Verbindung des polnischen Beckens mit dem Osten führt. Mit dem Anfang des Hauterivians macht sich die Regression auch in Polen fühlbar und verursacht die Verflachung des Meeres in Polen sowie den Abbruch der Verbindung mit dem karpathischen Meere, in welchem von nun ab keine nordischen eingewanderten Faunenelemente mehr erscheinen. Im oberen Hauterivian zieht sich das Meer von Polen und NO-Deutschland zurück. Auf dem neuen Lande herrscht mächtige Denudation, deren gröbere Produkte sich als sehr mächtige Flu\- und Seesande anhäufen. Das Landstadium dauert während des ganzen BarrÊme, Apt und eines Teiles des Albians an, bis zum Anfang der gro\en Gault-Transgression, die wieder in die Senken vordringt.  相似文献   

Holocene paleohydrological reconstruction of Lake Strzeszyńskie (western Poland) and its implications for the central European climatic transition zone     

Krzysztof Pleskot  Rik Tjallingii  Mirosław Makohonienko  Norbert Nowaczyk  Witold Szczuciński 《Journal of Paleolimnology》2018,59(4):443-459

Western Poland is located in the central European climatic transition zone, which separates the mild and humid Atlantic climate of Western Europe and the East European continental climate. This region is sensitive to lateral shifts of the European climate zones and is particularly suitable for reconstructing Holocene climate variability. This paper presents detailed analyses of the sedimentary record from Lake Strzeszyńskie since the Late Pleistocene. These include smear-slide and thin-section observations, X-ray fluorescence core scanning, magnetic susceptibility measurements, pollen analyses, and radiocarbon dating. The sediment record reveals three distinct sedimentary units consisting of: (1) an alternation of sand layers and laminated silt and clay deposits accumulated prior to 14,600 cal yr BP; (2) faintly laminated calcareous sediments intercalated with organic matter-rich layers deposited between 14,600 and 10,200 cal yr BP; and (3) massive calcareous mud deposited after 10,200 cal yr BP. The Holocene period is marked by nine phases of organic-rich sedimentation and enhanced Fe deposition, which occurred at ca. 10.1, 9.3, 6.4–6.1, 5.5–5.1, 4.7–4.5, 2.7–2.4, 1.3–1.2, 0.8–0.6, 0.4–0.2 kyr cal BP. These phases are associated with high lake levels and correspond with wet periods recognized in several other records from Poland and central Europe. These phases partly coincide with North Atlantic cold periods, which may suggest that high lake levels are triggered by an ocean-continent linking mechanism.  相似文献   

Integrating behavioural economics into climate-economy models: some policy lessons     

Karolina Safarzyńska 《Climate Policy》2018,18(4):485-498

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Sea water surface energy balance in the Arctic fjord (Hornsund,SW Spitsbergen) in May–November 2014     

Fortuniak  Krzysztof  Przybylak  Rajmund  Araźny  Andrzej  Pawlak  Włodzimierz  Wyszyński  Przemysław 《Theoretical and Applied Climatology》2017,130(3-4):959-970

Maize is grown by millions of smallholder farmers in South Asia (SA) under diverse environments. The crop is grown in different seasons in a year with varying exposure to weather extremes, including high temperatures at critical growth stages which are expected to increase with climate change. This study assesses the impact of current and future heat stress on maize and the benefit of heat-tolerant varieties in SA. Annual mean maximum temperatures may increase by 1.4–1.8 °C in 2030 and 2.1–2.6 °C in 2050, with large monthly, seasonal, and spatial variations across SA. The extent of heat stressed areas in SA could increase by up to 12 % in 2030 and 21 % in 2050 relative to the baseline. The impact of heat stress and the benefit from heat-tolerant varieties vary with the level of temperature increase and planting season. At a regional scale, climate change would reduce rainfed maize yield by an average of 3.3–6.4 % in 2030 and 5.2–12.2 % in 2050 and irrigated yield by 3–8 % in 2030 and 5–14 % in 2050 if current varieties were grown under the future climate. Under projected climate, heat-tolerant varieties could minimize yield loss (relative to current maize varieties) by up to 36 and 93 % in 2030 and 33 and 86 % in 2050 under rainfed and irrigated conditions, respectively. Heat-tolerant maize varieties, therefore, have the potential to shield maize farmers from severe yield loss due to heat stress and help them adapt to climate change impacts.  相似文献   

Thermal conduction between an accretion disc and a corona in active galactic nuclei: vertical structure of the transition layer     

A. Ró&#;a&#;ska 《Monthly notices of the Royal Astronomical Society》1999,308(3):751-762

We study the vertical structure of the transition layer between an accretion disc and a corona in the context of the existence of a two-phase medium in thermally unstable regions. The disc is illuminated by hard X-ray radiation, and satisfies the condition of hydrostatic equilibrium. We take into account the energy exchange between the hot, Compton-heated corona (∼10⁸ K) and cool disc (∼10⁴ K) arising from both radiative processes and thermal conduction. In the case including thermal conduction, we perform a local stability analysis, and conclude that thermal conduction does not suppress thermal instability. In spite of the continuous temperature profile T ( τ ) there are regions of strong temperature gradient, in which spontaneous perturbations can lead to cloud condensation in the transition layer. We determine the minimum size λ _TC of such a perturbation.  相似文献   

Sensing underground coal gasification by ground penetrating radar     

Andrzej Kotyrba  Krzysztof Stańczyk 《Acta Geophysica》2017,65(6):1185-1196

The paper describes the results of research on the applicability of the ground penetrating radar (GPR) method for remote sensing and monitoring of the underground coal gasification (UCG) processes. The gasification of coal in a bed entails various technological problems and poses risks to the environment. Therefore, in parallel with research on coal gasification technologies, it is necessary to develop techniques for remote sensing of the process environment. One such technique may be the radar method, which allows imaging of regions of mass loss (voids, fissures) in coal during and after carrying out a gasification process in the bed. The paper describes two research experiments. The first one was carried out on a large-scale model constructed on the surface. It simulated a coal seam in natural geological conditions. A second experiment was performed in a shallow coal deposit maintained in a disused mine and kept accessible for research purposes. Tests performed in the laboratory and in situ conditions showed that the method provides valuable data for assessing and monitoring gasification surfaces in the UCG processes. The advantage of the GPR method is its high resolution and the possibility of determining the spatial shape of various zones and forms created in the coal by the gasification process.  相似文献   

Application of electrical and electromagnetic methods to study sedimentary covers in high mountain areas     

Sylwia Tomecka-Suchoń  Bogdan Żogała  Tomisław Gołębiowski  Grażyna Dzik  Tomasz Dzik  Krzysztof Jochymczyk 《Acta Geophysica》2017,65(4):743-755

The results of geophysical studies conducted with selected electrical and electromagnetic methods in the Kondratowa Valley in the Tatra Mountains (the Carpathian Mountains, Poland) are presented in the article. The surveys were performed with the following methods: electrical resistivity tomography (ERT), georadar (GPR) and conductivity meter (CM). The objective of the noninvasive geophysical measurements was to determine the thickness of the Quaternary postglacial sediments that fill the bottom of the valley and to designate the accumulation of boulders deposited on Quaternary sediments. The results of ERT surveys conducted along the axis of the valley allowed to determine the changeability of the thickness of the postglacial sediments and allowed to designate a few areas of occurrence of boulders. The ERT, GPR and CM surveys conducted across the valley allowed to designate with high accuracy the thickness of the accumulation of boulders sliding down the valley bottom from the couloirs surrounding the valley.  相似文献   

Piping dynamics in mid‐altitude mountains under a temperate climate: Bieszczady Mountains,eastern Carpathians          下载免费PDF全文

Anita Bernatek‐Jakiel  Michał Jakiel  Kazimierz Krzemień 《地球表面变化过程与地形》2017,42(9):1419-1433

Piping has been recognized as an important geomorphic, soil erosion and hydrologic process. It seems that it is far more widespread than it has often been supposed. However, our knowledge about piping dynamics and its quantification currently relies on a limited number of data for mainly loess‐derived areas and marl badlands. Therefore, this research aimed to recognize piping dynamics in mid‐altitude mountains under a temperate climate, where piping occurs in Cambisols, not previously considered as piping‐prone soils. It has been expressed by the estimation of erosion rates due to piping and elongation of pipes in the Bere?nica Wy?na catchment in the Bieszczady Mountains, eastern Carpathians (305 ha, 188 collapsed pipes). The research was based on the monitoring of selected piping systems (1971–1974, 2013–2016). Changes in soil loss vary significantly between different years (up to 27.36 t ha^?1 yr^?1), as well as between the mean short‐term erosion rate (up to 13.10 t ha^?1 yr^?1), and the long‐term (45 years) mean of 1.34 t ha^?1 yr^?1. The elongation of pipes also differs, from no changes to 36 m during one year. The mean total soil loss is 48.8 t ha^?1 in plots, whereas in the whole studied catchment it is 2.0 t ha^?1. Hence, piping is both spatially and temporally dependent. The magnitude of piping in the study area is at least three orders of magnitude higher than surface erosion rates (i.e. sheet and rill erosion) under similar land use (grasslands), and it is comparable to the magnitude of surface soil erosion on arable lands. It means that piping constitutes a significant environmental problem and, wherever it occurs, it is an important, or even the main, sediment source. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献