DOAS observations of formaldehyde and its impact on the HO<Subscript>x</Subscript> balance in the tropical Atlantic marine boundary layer     

Anoop S. Mahajan  Lisa K. Whalley  Elena Kozlova  Hilke Oetjen  Luis Mendez  Kate L. Furneaux  Andrew Goddard  Dwayne E. Heard  John M. C. Plane  Alfonso Saiz-Lopez 《Journal of Atmospheric Chemistry》2010,66(3):167-178

Measurements of formaldehyde (HCHO) were made at the Cape Verde Atmospheric Observatory between November 2006 and June 2007 using the Long-Path Differential Optical Absorption Spectroscopy (LP-DOAS) technique. Observations show that typical HCHO mixing ratios ranged between 350 and 550 pptv (with typical 2-σ uncertainties of ~110 pptv), with several events of high HCHO, the maximum being 1,885?±?149 pptv. The observations indicate a lack of strong seasonal or diurnal variations, within the uncertainty of the measurements. A box model is employed to test whether the observations can be explained using known hydrocarbon photochemistry; the model replicates well the typical diurnal profile and monthly mean values. The model results indicate that on average 20% of HO₂ production and 10% of OH destruction can be attributed to the mean HCHO levels, suggesting that even at these low average mixing ratios HCHO plays an important role in determining the HO_x (HO₂+OH) balance of the remote marine boundary layer.  相似文献   

Effects of temperature and chemical formulation on the acute toxicity of pentachlorophenol to Simocephalus vetulus (Schoedler, 1858) (Crustacea: Cladocera)     

Kate J. Willis  Nicholas Ling  M. Ann Chapman 《新西兰海洋与淡水研究杂志》2013,47(2):289-294

Abstract

The influence of temperature on the acute toxicity of a technical formulation (86%) and pure formulation (99%) of pentachlorophenol (PCP) to less than 24‐h‐old Simocephalus vetulus neonates was determined with 48‐h static toxicity tests. The technical grade PCP was significantly more toxic to S. vetulus than the pure PCP (P < 0.05). Sensitivity of S. vetulus to technical PCP also significantly increased with temperature (P < 0.05), but a significant temperature effect was not found with the pure PCP. The mean 48‐h LC₅₀ values for neonates exposed to technical PCP were 140 and 199 μg l^?1 at 22°C and 16°C, respectively, and for those exposed to pure PCP were 262 and 304 μg l^?1, respectively.  相似文献   

Variation in sunscreen compounds (mycosporine‐like amino acids) for marine species along a gradient of ultraviolet radiation transmission within doubtful sound,New Zealand     

Miles D. Lamare  Michael P. Lesser  Mike F. Barker  Thomas M. Barry  Kate B. Schimanski 《新西兰海洋与淡水研究杂志》2013,47(5):775-793

We examined the response of four species of New Zealand marine algae (Ecklonia radiata, Apophlaea lyallii, Rhodymenia spp., Ulva lactuca) and a sea urchin (Evechinus chloroticus) to spatial variation in ultraviolet radiation (UV‐R) by examining the concentration of UV‐R absorbing compounds known as mycosporine‐like amino acids (MAAs). The purpose was to understand how, and the degree to which, local marine species could potentially respond to any future increases in incident UV‐R in the New Zealand marine environment. The research was undertaken in Doubtful Sound, where we observed a gradient of water column UV‐R transmission along the 40 km length of the fiord. We examined spatial differences in MAAs along the UV‐B gradient in the macrophytes and temporal changes in MAAs in sea urchin gonads. Among the algae, thallus MAA concentrations (nmol mg^–1 protein) ranged from 12.5 to 87.8 in E. radiata, from 433.1 to 1446.4 in A. lyallii, 12.7 to 103.4 in Rhodymenia spp., but were not detected in U. lactuca. For E. chloroticus, gonadal MAA concentrations ranged from 83.9 to 224.3 nmol mg^–1 protein spatially, and over the year from 1.85 to 14.12 nmol mg^–1 dry weight (DW) depending on site and gametogenic cycle. Laboratory manipulations indicated that concentrations of MAAs in E. chloroticus gonads and eggs are influenced by diet. MAA concentration could be correlated with UV‐B intensities in two of the algal species. E. chloroticus MAA concentrations could also be correlated with UV‐B transmission, which we concluded was a reflection of the greater ingestion and accumulation of MAA‐rich macrophytes at those sites where higher ambient UV‐R induced greater MAA concentrations to occur in the algae. Given this, we suggest that one response of marine species to increases in UV‐B would be an increase in the synthesis and/or accumulation of MAAs for photoautotrophs and a dietary accumulation of those MAAs in E. chloroticus, an important herbivore in this system.  相似文献   

Calculations on the energetics of water dissolution in wadsleyite     

Wright  Kate  Catlow  C. R. A. 《Physics and Chemistry of Minerals》1996,23(1):38-41

Physics and Chemistry of Minerals - Computer simulation techniques are used to investigate the energetics and mechanisms of dissolution of water in the upper mantle mineral wadsleyite (β(Mg,...  相似文献   

Stratigraphic and structural expression of the lateral growth of thrust fault-propagation folds: results and implications from kinematic modelling     

Kate A. Cooper  Stuart Hardy  Rob Gawthorpe 《Basin Research》2003,15(2):165-182

In order to better understand the development of thrust fault‐related folds, a 3D forward numerical model has been developed to investigate the effects that lateral slip distribution and propagation rate have on the fold geometry of pre‐ and syn‐tectonic strata. We consider a fault‐propagation fold in which the fault propagates upwards from a basal decollement and along‐strike normal to transport direction. Over a 1 Ma runtime, the fault reaches a maximum length of 10 km and accumulates a maximum displacement of 1 km. Deformation ahead of the propagating fault tip is modelled using trishear kinematics while backlimb deformation is modelled using kink‐band migration. The applicability of two different lateral slip distributions, namely linear‐taper and block‐taper, are firstly tested using a constant lateral propagation rate. A block‐taper slip distribution replicates the geometry of natural fold‐thrusts better and is then used to test the sensitivity of thrust‐fold morphology to varied propagation rates in a set of fault‐propagation folds that have identical final displacement to length (D_max/L_max) ratios. Two stratigraphic settings are considered: a model in which background sedimentation rates are high and no topography develops, and a model in which a topographic high develops above the growing fold and local erosion, transport and deposition occur. If the lateral propagation rate is rapid (or geologically instantaneous), the fault tips quickly become pinned as the fault reaches its maximum lateral extent (10 km), after which displacement accumulates. In both stratigraphic settings, this leads to strike‐parallel rotation of the syn‐tectonic strata near the fault tips; high sedimentation rates relative to rates of uplift result in along‐strike thinning over the structural high, while low sedimentation rates result in pinchout against it. In contrast, slower lateral propagation rates (i.e. up to one order of magnitude greater than slip rate) lead to the development of along‐strike growth triangles when sedimentation rates are high, whereas when sedimentation rates are low, offflap geometries result. Overall we find that the most rapid lateral propagation rates produce the most realistic geometries. In both settings, time‐equivalent units display both nongrowth and growth stratal geometries along‐strike and the transition from growth to nongrowth has the potential to delineate the time of fault/fold growth at a given location. This work highlights the importance of lateral fault‐propagation and fault tip pinning on fault and fold growth in three dimensions and the complex syn‐tectonic geometries that can result.  相似文献   

A computer simulation study of (OH) defects in olivine     

Kate Wright  C. R. A. Catlow 《Physics and Chemistry of Minerals》1994,20(7):515-518

Recent experiments (Miller et al. 1987; Bell and Rossman 1992; Bai and Kohlstedt 1992) have shown that olivine, the dominant mineral in the Earth's upper mantle, can contain substantial amounts of water in the form of OH. There is uncertainty, however, as to the mechanisms by which water dissolves into the mineral structure and as to the site it occupies in the host lattice. We have therefore used atomistic computer simulation techniques based on the Born model of solids, to investigate the structures and energies of OH defects in olivine. Our calculations suggest that the most favourable route for incorporation of OH into olivine involves reactions with water accompanied by the reduction of ferric iron for which we obtain a solution energy of 0.46 eV. We propose therefore that the OH content will be largely controlled by the concentration of Fe³⁺.  相似文献   

Celebrating a Nation’s heritage on music stamps: Constructing an international community     

Kate Covington  Stanley D. Brunn 《GeoJournal》2006,65(1-2):125-135

Stamps convey important visible messages about a state’s heritage and worldview. They are images or official visible products seen by those living within the state’s borders and those beyond. They also can be considered as “imagined communities,” as like festivals, holidays, or WWW pages, they represent attachments to and images of place. We investigate stamps as elements of visual culture by examining salient music themes and topics from several countries and then focus on the music stamps of Brazil, Hungary, and Senegal. In each case, we examine the number and variety of issues, the importance they place on musical instruments, composers and performers, and musical events.  相似文献   

Arsenic incorporation into FeS₂ pyrite and its influence on dissolution: A DFT study   总被引：3，自引：0，他引：3  

Marc Blanchard  Maria Alfredsson  Kate Wright 《Geochimica et cosmochimica acta》2007,71(3):624-630

FeS₂ pyrite can incorporate large amounts of arsenic (up to ca. 10 wt%) and hence has a strong impact on the mobility of this toxic metalloid. Focussing on the lowest arsenic concentrations for which the incorporation occurs in solid solution, the substitution mechanisms involved have been investigated by assuming simple incorporation reactions in both oxidising and reducing conditions. The solution energies were calculated by Density Functional Theory (DFT) calculations and we predict that the formation of AsS dianion groups is the most energetically favourable mechanism. The results also suggest that the presence of arsenic will accelerate the dissolution and thus the generation of acid drainage, when the crystal dissolves in oxidising conditions.  相似文献   

Investigation of the Ablation Behaviour of Andradite-Grossular Garnets and Rutile with Implications for U-Pb Geochronology     

Kate Jenkins  Karsten Goemann  Ivan Belousov  Maxwell Morissette  Leonid Danyushevsky 《Geostandards and Geoanalytical Research》2023,47(2):267-295

U-Pb dating of andradite-grossular garnet (grandite) and rutile by LA-ICP-MS can be used to constrain various metamorphic, metasomatic and igneous geological processes. In this study, we examine and compare the impact of different analytical conditions (fluence, pulse width, laser beam size and ablation frequency) on the ablation crater morphology, ablation rates, down-hole fractionation and U-Pb ages of grandite and rutile samples of different compositions. The shapes of grandite ablation craters suggest the mineral ablates by classical evaporation with significant melting that cannot be eliminated even at fluences just above the ablation threshold. Grandite garnets with higher andradite proportions have faster ablation rates. The overall low U contents of grandite require using large laser beam sizes to obtain acceptable precision of U-Pb ages. At such conditions and crater depths < 10 μm, fluences of 2.1 and 3.5 J cm^-2, laser pulse width of 5 ns and 20 ns, and ablation frequencies between 3.5 and 6.5 Hz, obtain similar and reproducible ages when the proportion of grossular is < 35%. Rutile ablation crater morphology shows evidence of melt splashing and thermal stress cracking. They have significant crater bottom features, which increase in relief with lower fluences and a higher number of laser shots, indicating the features are probably energy-related and making higher fluences, such as 5 J cm^-2, necessary for uniform ablation when using 193 nm excimer lasers. The slow ablation rate at low fluences and then steep increase at around 2.0 J cm^-2 suggests a transition in the ablation mechanism from exfoliation to classical vaporisation. Crater bottom features and other ablation behaviour vary between samples, which could be related to their difference in colour. Although the down-hole fractionation patterns of the samples are similar at 5 J cm^-2, the U-Pb ages of some samples vary significantly with different analytical conditions and/or measurement sessions, particularly when using laser beam sizes of 30 μm, suggesting differences in mass bias and more variable ablation behaviour. A laser beam size of at least 60 μm is recommended for reproducible U-Pb dating of rutile.  相似文献   

Prairie or planted? Using time-series NDVI to determine grassland characteristics in Montana     

Sarah K. Olimb  Adam P. Dixon  Emmalee Dolfi  Ryan Engstrom  Kate Anderson 《GeoJournal》2018,83(4):819-834

Temperate grasslands are a highly threatened global biome. Complicating management and conservation strategy development, modern grasslands can be difficult to characterize across landscapes since they range from native and semi-native to completely non-native species compositions such as those found in heavily managed pastures. Similar to methods used to differentiate C3 and C4 grasses, we investigate the ability of using temporal variations in growth characteristics as an alternative pathway to predicting native versus introduced species composition across grassland landscapes. To do this, we conducted an exploratory analysis using a time-series of Normalized Difference Vegetation Index values as a measure of vegetation greenness with Landsat 5 TM imagery across a growing season and performed an unsupervised classification. Results from the classification were compared with field observation to determine if we can differentiate between native and introduced grassland types in the Northwest Glaciated Plains subecoregion of northeastern Montana. Our results indicated that we predicted grassland cover with 81% accuracy within our 200 km² study area and 71% accuracy in our 5000 km² secondary study area. Further extrapolation of our methodology, combined with the refinement of vegetation indices of time-series imagery, classification algorithms and the availability of data from planned Landsat and Sentinel missions, may provide the spatial detail necessary to improve grassland monitoring and rangeland management over large areas.  相似文献