Spatial variability of metals in the inter-tidal sediments of the Medway Estuary,Kent, UK   总被引：7，自引：0，他引：7  

Spencer KL 《Marine pollution bulletin》2002,44(9):933-944

Concentrations of major and trace metals were determined in eight sediment cores collected from the inter-tidal zone of the Medway Estuary, Kent, UK. Metal associations and potential sources have been investigated using principal component analysis. These data provide the first detailed geochemical survey of recent sediments in the Medway Estuary. Metal concentrations in surface sediments lie in the mid to lower range for UK estuarine sediments indicating that the Medway receives low but appreciable contaminant inputs. Vertical metal distributions reveal variable redox zonation across the estuary and historically elevated anthropogenic inputs. Peak concentrations of Cu, Pb and Zn can be traced laterally across the estuary and their positions indicate periods of past erosion and/or non-deposition. However, low rates of sediment accumulation do not allow these sub surface maxima to be used as accurate geochemical marker horizons. The salt marshes and inter-tidal mud flats in the Medway Estuary are experiencing erosion, however the erosion of historically contaminated sediments is unlikely to re-release significant amounts of heavy metals to the estuarine system.  相似文献   

U-Pb ages and tectonomagmatic relationships of early Ordovician low-Ti tholeiites, boninites and related plutonic rocks in central Newfoundland, Canada     

Kate MacLachlan  Greg Dunning 《Contributions to Mineralogy and Petrology》1998,133(3):235-258

The Wild Bight Group (WBG) and South Lake Igneous Complex (SLIC) together comprise one of the Ordovician accreted oceanic terranes of the central mobile belt of the Newfoundland Appalachians. Combined detailed mapping, geochemistry, Sm-Nd isotopic studies and U-Pb geochronology have shown that sheeted dykes and hornblende diorite and tonalite plutons of the SLIC are genetically related to a discrete package of volcanic rocks in the WBG. These igneous rocks are geochemically, isotopically and temporally distinct from volcanic rocks in the rest of the WBG. Plutonic rocks of the SLIC range in age from 486 ± 3 Ma to 489 ± 3 Ma, and a cross-cutting gabbro dyke gives a minimum age of 486 ± 4 Ma for the related volcanic sequence. Volcanic rocks in the rest of the WBG sequence are predominantly younger than 472 ± 3 Ma. The older volcanic sequence of the WBG and the SLIC occur as fault-bounded packages interleaved within the younger WBG sequence. A conformable stratigraphic relationship between the older and younger sequences of the WBG has not been demonstrated. The mafic rocks of the older package include boninites and low-Ti, high-Mg tholeiitic island arc basalts which are interpreted to be genetically related, and normal island arc tholeiites (IAT). The high-Mg mafic rocks are interpreted to have formed in an extensional setting during subduction zone initiation, and the normal IAT are thought to represent stabilisation of the volcanic front. The associated high-Si, low-K rhyolite and tonalite are interpreted to be the products of secondary melting at the base of thickened early arc crust. Sm-Nd isotopic compositions indicate that the characteristic trace element signature of the boninites developed at or near their time of generation and was not a long lived characteristic of the source region. The boninites and low-Ti tholeiites are interpreted to have originated from a similar source, which was metasomatized by different subduction-related components. Apparent decoupling of Sm-Nd geochemical and isotopic compositions suggests that these very depleted rocks may be recording the effect of subduction zone processes not yet fully understood. Received: 31 October 1997 / Accepted: 6 May 1998  相似文献   

Landuse mapping by air photo technique     

R. C. Pathak  J. M. Kate 《Journal of the Indian Society of Remote Sensing》1988,16(2):47-51

Land use on earth's landscape primarly indicates the degree of human interferance. Though landuse is controlled by several factors like soil, hydrologic, climatic, socio-economic and political yet geology and geomorphology play an important role in shaping landforms. The landforms processes mainly depend upon inherent lithology and structure of the earth. In the present paper an attempt has been made to study a sample area by air photo-interpretation technique using stereo-models and then evolve a methodology of land use mapping like photogeological and photopedological aspects. Also in brief, environmental aspects have been discussed. A sample area of 15 sq kms has been studied. The study opens up a new dimension for appreciation of resource and landuse management  相似文献   

Methane,carbon monoxide and methylchloroform in the southern hemisphere   总被引：1，自引：0，他引：1  

P. J. Fraser  P. Hyson  R. A. Rasmussen  A. J. Crawford  M. A. K. Khalil 《Journal of Atmospheric Chemistry》1986,4(1):3-42

New observational data on CH₄, CO and CH₃CCl₃ in the southern hemisphere are reported. The data are analysed for long term trends and seasonal cycles. CH₃CCl₃ data are used to scale the OH fields incorporated in a two dimensional model, which in turn, is used to constrain the magnitude of a global CH₄ source function. The possible causes of observed seasonality of CH₃CCl₃, CH₄ and CO are identified, and several other aspects of observed CH₄ variability are discussed.Possible future research directions are also given.  相似文献   

Africa in the rise of rights-based development     

Kate Manzo 《Geoforum》2003,34(4):437-456

This paper explores the rise of rights-based development (RBD) and its endorsement by prominent international institutions (such as the United Nations) and International Development Agencies (IDAs) like the World Bank. It situates RBD in global political context and analyses it in relation to the international politics of development, especially the politics of neo-liberal adjustment policies in Africa. The paper shows how RBD emerged against a backdrop of debate about four international issues associated with neo-liberalism and its discontents, namely globalisation and uneven development; capability and good governance; human rights and human development; and NGOs in the politics of development. Debates about those four issues keep repositioning the state as the central actor in RBD, and holding the state accountable for development (or the lack thereof) under international law. The paper’s basic point is that state-centric RBD is paradoxical and highly political. Greater accountability is being demanded of states––especially in Africa––from the same neo-liberal forces (such as the World Bank) charged with weakening state capacity, undermining democracy, and diminishing state authority. In terms of international power relations and the politics of development, RBD does signal something of a willingness to rethink certain aspects of the dominant neo-liberal agenda. And yet adjusted states are being subjected––in the name of RBD––to novel methods of international surveillance and forms of conditionality. States are ultimately held responsible for human rights violations, even when it is non-state actors (and their neo-liberal policies) that caused those rights to be violated in the first place. RBD is, therefore, a partial answer (at best) to the questions of empowerment and change raised by critics of neo-liberalism.  相似文献   

A 16,000 C yr B.P. packrat midden series from the USA–Mexico Borderlands     

Camille A. Holmgren  M. Cristina Pealba  Kate Aasen Rylander  Julio L. Betancourt 《Quaternary Research》2003,60(3):319-329

A new packrat midden chronology from Playas Valley, southwestern New Mexico, is the first installment of an ongoing effort to reconstruct paleovegetation and paleoclimate in the U.S.A.–Mexico Borderlands. Playas Valley and neighboring basins supported pluvial lakes during full and/or late glacial times. Plant macrofossil and pollen assemblages from nine middens in the Playas Valley allow comparisons of two time intervals: 16,000–10,000 and 4000–0 ¹⁴C yr B.P. Vegetation along pluvial lake margins consisted of open pinyon–juniper communities dominated by Pinus edulis, Juniperus scopulorum, Juniperus cf. coahuilensis, and a rich understory of C₄ annuals and grasses. This summer-flowering understory is also characteristic of modern desert grassland in the Borderlands and indicates at least moderate summer precipitation. P. edulis and J. scopulorum disappeared or were rare in the midden record by 10,670 ¹⁴C yr B.P. The late Holocene is marked by the arrival of Chihuahuan desert scrub elements and few departures as the vegetation gradually became modern in character. Larrea tridentata appears as late as 2190 ¹⁴C yr B.P. based on macrofossils, but may have been present as early as 4095 ¹⁴C yr B.P. based on pollen. Fouquieria splendens, one of the dominant desert species present at the site today, makes its first appearance only in the last millennium. The midden pollen assemblages are difficult to interpret; they lack modern analogs in surface pollen assemblages from stock tanks at different elevations in the Borderlands.  相似文献   

Impurities and nonstoichiometry in the bulk and on the (101?4) surface of dolomite     

Kate Wright  Randall T CyganBen Slater 《Geochimica et cosmochimica acta》2002,66(14):2541-2546

Atomistic computer simulation methods have been used to model the nature of nonstoichiometry and impurity defects in the bulk and at the (101?4) surface of dolomite (MgCa(CO₃)₂). Calcium and Mg in the bulk and at the surface have been replaced with divalent Ni, Co, Zn, Fe, Mn, and Cd. The results of these calculations indicate that in the bulk, these impurities will prefer to substitute at the Ca site rather than the Mg site. Ca excess in dolomite is most likely incorporated as basal stacking faults; this nonstoichiometry can influence the site distribution of impurities. The calculated surface segregation energies suggest that of all the impurities studied, only Cd will show a strong preference for the (101?4) surface of dolomite.  相似文献   

Variations in the distribution of magma in the lower crust and at the Moho beneath the East Pacific Rise at 9°-10°N     

Wayne C. Crawford  Spahr C. Webb 《Earth and Planetary Science Letters》2002,203(1):117-130

Measurements of the seafloor deformation under ocean waves (compliance) reveal an asymmetric lower crustal partial melt zone (shear velocity less than 1.8 km/s) beneath the East Pacific Rise axis between 9° and 10°N. At 9°48′N, the zone is less than 8 km wide and is centered beneath the rise axis. The zone shifts west of the rise axis as the rise approaches the westward-stepping 9°N overlapping spreading center discontinuity and is anomalously wide at the northern tip of the discontinuity. The ratio of the compliance determined shear velocity to the compressional velocities (estimated by seismic tomography) suggests that the melt is well-connected in high-aspect ratio cracks rather than in isolated sills. The shear and compressional velocities indicate less than 18% melt in the lower crust on average. The compliance measurements also reveal a separate lower crustal partial melt zone 10 km east of the rise axis at 9°48′N and isolated melt bodies near the Moho beneath four of the 39 measurement sites (three on-axis and one off-axis). The offset of the central melt zone from the rise axis correlates strongly with the offset of the overlying axial melt lens and the inferred center of mantle melting, but its shape appears to be controlled by crustal processes.  相似文献   

Floodplain formation processes and archaeological implications at the Grand Banks site,lower Grand River,southern, Ontario     

Ian J. Walker  Joseph R. Desloges  Gary W. Crawford  David G. Smith 《Geoarchaeology》1997,12(8):865-887

Processes of floodplain development and the record of Princess Point cultural occupation (A.D. 500–1000) were examined at the Grand Banks site in the lower Grand River of southern Ontario. The Princess Point Complex of the early Late Woodland is significant because it represents the first shift to horticulture in this region in which inhabitants made significant use of floodplains. The floodplain of the lower Grand River has been constructed primarily via vertical accretion of sediment in a low energy environment conducive to limited erosion and slow burial of middle and late Holocene sediments. At this site, cultural materials are preferentially preserved in two buried soils each corresponding to relatively stable periods of valley infilling at or before 3200 B.P. and 1500 B.P. (¹⁴C years). Initial formation of the floodplain and subsequent stability of the floodplain surface can be tied to middle Holocene, and later, base-level fluctuations in Lake Erie. Understanding floodplain development is crucial in determining the linkages between settlement pattern and chronology, and, conversely, the archaeological record in floodplain settings provides important contemporary data for modeling floodplain geomorphological processes. © 1997 John Wiley & Sons, Inc.  相似文献   

A rock test cell with true triaxial capability     

B.D.G. Smart  J.M. Somerville  B.R. Crawford 《Geotechnical and Geological Engineering》1999,17(3-4):157-176

Conventional so-called triaxial test cells apply the axial stress to a cylindrical sample using steel platens, with the confining stress developed via an annulus of hydraulic fluid retained by a liner in a pressure cell. This does not allow differentiation between the two principal stresses around the core and inhibits the realism with which the rocks can be tested, for example in determining the effect of the intermediate principal stress on the strength of the sample.This paper describes the development and application of a new test cell – believed to be the first in the world – which enables truly triaxial stresses to be applied to cylindrical core samples, opening up the possibility to test rocks routinely in a more realistic manner. An array of 24 trapped tubes replace the single annulus which usually generates the uniform radial stress. Selective pressurization of the tubes enables differential radial stresses to be generated, while axial stresses are applied as before through steel platens. The first results of multi-state failure and permeability stress sensitivity of samples tested in the cell are presented. These demonstrate the influence of the intermediate principal stress on measured rock properties and the orientation of induced fracture planes.  相似文献