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21.
An integrated study combining facies analysis, multiple group biostratigraphy, identification of depositional sequences and mapping has been conducted on the Miocene Molasse Basin of the external Alps (southeastern France). The filling of the basin is described as resulting from a succession of fluvial incisions subsequently filled during marine transgressions. The major incision is dated as Latest Burdigalian and the major transgression as Langhian. This revised interpretation of the Miocene physiographic evolution of the Molasse Basin implies a re-examination of previous stratigraphic correlations within the basin. To cite this article: D. Besson et al., C. R. Geoscience 337 (2005).  相似文献   
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We present new partition coefficients for various trace elements including Cl between olivine, pyroxenes, amphibole and coexisting chlorine-bearing aqueous fluid in a series of high-pressure experiments at 2 GPa between 900 and 1,300 °C in natural and synthetic systems. Diamond aggregates were added to the experimental capsule set-up in order to separate the fluid from the solid residue and enable in situ analysis of the quenched solute by LA–ICP–MS. The chlorine and fluorine contents in mantle minerals were measured by electron microprobe, and the nature of OH defects was investigated by infrared spectroscopy. Furthermore, a fluorine-rich olivine from one selected sample was investigated by TEM. Results reveal average Cl concentrations in olivine and pyroxenes around 20 ppm and up to 900 ppm F in olivine, making olivine an important repository of halogens in the mantle. Chlorine is always incompatible with Cl partition coefficients D Cl olivine/fluid varying between 10?5 and 10?3, whereas D Cl orthopyroxene/fluid and D Cl clinopyroxene/fluid are ~10?4 and D Cl amphibole/fluid is ~5 × 10?3. Furthermore, partitioning results for incompatible trace element show that compatibilities of trace elements are generally ordered as D amph/fluid ≈ D cpx/fluid > D opx/fluid > D ol/fluid but that D mineral/fluid for Li and P is very similar for all observed silicate phases. Infrared spectra of olivine synthesized in a F-free Ti-bearing system show absorption bands at 3,525 and ~3,570 cm?1. In F ± TiO2-bearing systems, additional absorption bands appear at ~3,535, ~3,595, 3,640 and 3,670 cm?1. Absorption bands at ~3,530 and ~3,570 cm?1, previously assigned to humite-like point defects, profit from low synthesis temperatures and the presence of F. The presence of planar defects could not be proved by TEM investigations, but dislocations in the olivine lattice were observed and are suggested to be an important site for halogen incorporation in olivine.  相似文献   
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This article analyses how policies to foster social cohesion within diverse and unequal urban contexts are affected by New Public Management and austerity policies. Based on the analysis of a handful of governance arrangements in three cities that differ in their institutional structure and diversity policy approaches (Copenhagen, Leipzig and Milan), it is shown that negative effects are quite widespread yet cushioned by a strong welfare state structure, solid local government and high priority given to the recognition of diversity. Nevertheless, the shift towards the application of market logic to social work reduces innovative potential, increases efforts spent on procedures and weakens public coordination.  相似文献   
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Responses of bioindicator candidates for water quality were quantified in two studies on inshore coral reefs of the Great Barrier Reef (GBR). In Study 1, 33 of the 38 investigated candidate indicators (including coral physiology, benthos composition, coral recruitment, macrobioeroder densities and FORAM index) showed significant relationships with a composite index of 13 water quality variables. These relationships were confirmed in Study 2 along four other water quality gradients (turbidity and chlorophyll). Changes in water quality led to multi-faceted shifts from phototrophic to heterotrophic benthic communities, and from diverse coral dominated communities to low-diversity communities dominated by macroalgae. Turbidity was the best predictor of biota; hence turbidity measurements remain essential to directly monitor water quality on the GBR, potentially complemented by our final calibrated 12 bioindicators. In combination, this bioindicator system may be used to assess changes in water quality, especially where direct water quality data are unavailable.  相似文献   
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Dissolved and particulate organic matter (DOM and POM) distribution, lignin phenol signatures, bulk elemental compositions, fluorescence indices and microbial plankton (algae, bacteria, viruses) in a temperate river floodplain system were monitored from January to November 2003. We aimed to elucidate the sources and compositions of allochthonous and autochthonous organic matter (OM) in the main channel and a representative backwater in relation to the hydrological regime. Additionally, bacterial secondary production was measured to evaluate the impact of organic carbon source on heterotrophic prokaryotic productivity. OM properties in the backwater tended to diverge from those in the main channel during phases without surface water connectivity; this was likely enhanced due to the exceptionally low river discharge in 2003. The terrestrial OM in this river floodplain system was largely derived from angiosperm leaves and grasses, as indicated by the lignin phenol composition. The lignin signatures exhibited significant seasonal changes, comparable to the seasonality of plankton-derived material. Microbially-derived material contributed significantly to POM and DOM, especially during periods of low discharge. High rates of bacterial secondary production (up to 135 μg C L(-1) d(-1)) followed algal blooms and suggested that autochthonous OM significantly supported heterotrophic microbial productivity.  相似文献   
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The Central European watershed passes through the southern Franconian Jura in Bavaria, Germany. This principal watershed divides the Rhine/Main catchment and the Danube catchment. In the early Middle Ages, when ships were an important means of transportation, Charlemagne decided to connect these catchments by the construction of a canal known as the Fossa Carolina. In this paper, we present for the first time 14C data from the Fossa Carolina fill and document a high‐resolution stratigraphic record of the Carolingian and post‐Carolingian trench infilling. Our results provide clear evidence for peat layers in different levels of the trench infill, suggesting a chain of ponds. However, the majority of these peat layers yield mid‐Medieval and younger ages. The period of major peat growth was during the Medieval climatic optimum. Therefore, our preliminary results do not prove the use of the trench during Carolingian times. However, first results from the reconstruction of the Carolingian trench bottom support the hypothesis that the Fossa was primarily planned as a navigable chain of ponds and not as a continuous canal. In the eastern part of the trench, a dam is located that was postulated in former studies to be part of a barrage for supplying the Carolingian canal with water. New 14C data indicate much younger ages and do not support the Carolingian barrage concept.  相似文献   
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Sequestration of CO2 into a deep geological reservoir causes a complex interaction of different processes such as multiphase flow, phase transition, multicomponent transport, and geochemical reactions between dissolved CO2 and the mineral matrix of the porous medium. A prognosis of the reservoir behaviour and the feedback from large-scale geochemical alterations require efficient process-based numerical models. For this purpose, the multiphase flow and multicomponent transport code OpenGeoSys-Eclipse have been coupled to the geochemical model ChemApp. The newly developed coupled simulator was successfully verified for correctness and accuracy of the implemented reaction module by benchmarking tests. The code was then applied to assess the impact of geochemical reactions during CO2 sequestration at a hypothetical but typical Bunter sandstone formation in the Northern German Basin. Injection and spreading of 1.48 × 107 t of CO2 in an anticline structure of the reservoir were simulated over a period of 20 years of injection plus 80 years of post-injection time. Equilibrium geochemical calculations performed by ChemApp show only a low reactivity to the geochemical system. The increased acidity of the aqueous solution results in dissolution of small amounts of calcite, anhydrite, and quartz. Geochemical alterations of the mineral phase composition result in slight increases in porosity and permeability, which locally may reach up to +0.02 and 0.1 %, respectively.  相似文献   
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