Detection and discrimination of sulfate minerals using reflectance spectroscopy   总被引：1，自引：0，他引：1  

Edward A. Cloutis  Frank C. Hawthorne  Katherine Krenn  Dionne Marcino  Johnathon Strong  Diana L. Blaney  Faith Vilas 《Icarus》2006,184(1):121-157

A suite of sulfate minerals were characterized spectrally, compositionally, and structurally in order to develop spectral reflectance-compositional-structural relations for this group of minerals. Sulfates exhibit diverse spectral properties, and absorption-band assignments have been developed for the 0.3-26 μm range. Sulfate absorption features can be related to the presence of transition elements, OH, H₂O, and SO₄ groups. The number, wavelength position, and intensity of these bands are a function of both composition and structure. Cation substitutions can affect the wavelength positions of all major absorption bands. Hydroxo-bridged Fe³⁺ results in absorption bands in the 0.43, 0.5, and 0.9 μm regions, while the presence of Fe²⁺ results in absorption features in the 0.9-1.2 μm interval. Fundamental SO bending and stretching vibration absorption bands occur in the 8-10, 13-18, and 19-24 μm regions (1000-1250, 550-770, and 420-530 cm⁻¹). The most intense combinations and overtones of these fundamentals are found in the 4-5 μm (2000-2500 cm⁻¹) region. Absorption features seen in the 1.7-1.85 μm interval are attributable to HOH/OH bending and translation/rotation combinations, while bands in the 2.1-2.7 μm regions can be attributed to H₂O- and OH-combinations as well as overtones of SO bending fundamentals. OH- and H₂O-bearing sulfate spectra are fundamentally different from each other at wavelengths below ∼6 μm. Changes in H₂O/OH content can shift SO band positions due to change in bond lengths and structural rearrangement. Differences in absorption band wavelength positions enable discrimination of all the sulfate minerals used in this study in a number of wavelength intervals. Of the major absorption band regions, the 4-5 μm region seems best for identifying and discriminating sulfates in the presence of other major rock-forming minerals.  相似文献   

Identification of magnetite in lunar regolith breccia 60016: Evidence for oxidized conditions at the lunar surface     

Katherine H. Joy  Channon Visscher  Michael E. Zolensky  Takashi Mikouchi  Kenji Hagiya  Kazumasa Ohsumi  David A. Kring 《Meteoritics & planetary science》2015,50(7):1157-1172

Lunar regolith breccias are temporal archives of magmatic and impact bombardment processes on the Moon. Apollo 16 sample 60016 is an “ancient” feldspathic regolith breccia that was converted from a soil to a rock at ~3.8 Ga. The breccia contains a small (70 × 50 μm) rock fragment composed dominantly of an Fe‐oxide phase with disseminated domains of troilite. Fragments of plagioclase (An_95‐97), pyroxene (En_74‐75, Fs_21‐22,Wo_3‐4), and olivine (Fo_66‐67) are distributed in and adjacent to the Fe‐oxide. The silicate minerals have lunar compositions that are similar to anorthosites. Mineral chemistry, synchrotron X‐ray absorption near edge spectroscopy (XANES) and X‐ray diffraction (XRD) studies demonstrate that the oxide phase is magnetite with an estimated Fe³⁺/ΣFe ratio of ~0.45. The presence of magnetite in 60016 indicates that oxygen fugacity during formation was equilibrated at, or above, the Fe‐magnetite or wüstite–magnetite oxygen buffer. This discovery provides direct evidence for oxidized conditions on the Moon. Thermodynamic modeling shows that magnetite could have been formed from oxidization‐driven mineral replacement of Fe‐metal or desulphurisation from Fe‐sulfides (troilite) at low temperatures (<570 °C) in equilibrium with H₂O steam/liquid or CO₂ gas. Oxidizing conditions may have arisen from vapor transport during degassing of a magmatic source region, or from a hybrid endogenic–exogenic process when gases were released during an impacting asteroid or comet impact.  相似文献   

Environmental variability during the Last Interglacial: a new high‐resolution pollen record from Tenaghi Philippon,Greece     

Alice M. Milner  Ulrich C. Müller  Katherine H. Roucoux  Richard E. L. Collier  Jörg Pross  Stavros Kalaitzidis  Kimon Christanis  Polychronis C. Tzedakis 《第四纪科学杂志》2013,28(2):113-117

A new high‐resolution Last Interglacial pollen record from the Tenaghi Philippon peatland, northeast Greece, documents variability in forest composition and cover, which we attribute to changes in temperature and moisture availability. The declining stage of the interglacial was marked by a stepwise decrease in temperate tree populations and culminated in the complete collapse of forest at the onset of the ensuing stadial. The coincidence of the onset of the stepwise declining trend with the increased prominence of North Atlantic ice‐rafting events suggests that ecological thresholds in southern Europe were only crossed once ice rafting events intensified, and implies that changes in North Atlantic ocean circulation were an important contributing factor to the declining temperate forest cover in southern Europe. Our results provide evidence for intra‐interglacial variability in the low mid latitudes and suggest a coupling between the high northern latitudes and the northeast Mediterranean during this interval. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Hydrogeological response to climate change in alpine hillslopes          下载免费PDF全文

Katherine H. Markovich  Reed M. Maxwell  Graham E. Fogg 《水文研究》2016,30(18):3126-3138

Climate change threatens water resources in snowmelt‐dependent regions by altering the fraction of snow and rain and spurring an earlier snowmelt season. The bulk of hydrological research has focused on forecasting response in streamflow volumes and timing to a shrinking snowpack; however, the degree to which subsurface storage offsets the loss of snow storage in various alpine geologic settings, i.e. the hydrogeologic buffering capacity, is still largely unknown. We address this research need by assessing the affects of climate change on storage and runoff generation for two distinct hydrogeologic settings present in alpine systems: a low storage granitic and a greater storage volcanic hillslope. We use a physically based integrated hydrologic model fully coupled to a land surface model to run a base scenario and then three progressive warming scenarios, and account for the shifts in each component of the water budget. For hillslopes with greater water retention, the larger storage volcanic hillslope buffered streamflow volumes and timing, but at the cost of greater reductions in groundwater storage relative to the low storage granite hillslope. We found that the results were highly sensitive to the unsaturated zone retention parameters, which in the case of alpine systems can be a mix of matrix or fracture flow. The presence of fractures and thus less retention in the unsaturated zone significantly decreased the reduction in recharge and runoff for the volcanic hillslope in climate warming scenarios. This approach highlights the importance of incorporating physically based subsurface flow in to alpine hydrology models, and our findings provide ways forward to arrive at a conceptual model that is both consistent with geology and hydrologic principles. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

RCP4.5: a pathway for stabilization of radiative forcing by 2100   总被引：3，自引：2，他引：1  

Allison M. Thomson  Katherine V. Calvin  Steven J. Smith  G. Page Kyle  April Volke  Pralit Patel  Sabrina Delgado-Arias  Ben Bond-Lamberty  Marshall A. Wise  Leon E. Clarke  James A. Edmonds 《Climatic change》2011,109(1-2):77-94

Representative Concentration Pathway (RCP) 4.5 is a scenario that stabilizes radiative forcing at 4.5?W?m^?2 in the year 2100 without ever exceeding that value. Simulated with the Global Change Assessment Model (GCAM), RCP4.5 includes long-term, global emissions of greenhouse gases, short-lived species, and land-use-land-cover in a global economic framework. RCP4.5 was updated from earlier GCAM scenarios to incorporate historical emissions and land cover information common to the RCP process and follows a cost-minimizing pathway to reach the target radiative forcing. The imperative to limit emissions in order to reach this target drives changes in the energy system, including shifts to electricity, to lower emissions energy technologies and to the deployment of carbon capture and geologic storage technology. In addition, the RCP4.5 emissions price also applies to land use emissions; as a result, forest lands expand from their present day extent. The simulated future emissions and land use were downscaled from the regional simulation to a grid to facilitate transfer to climate models. While there are many alternative pathways to achieve a radiative forcing level of 4.5?W?m^?2, the application of the RCP4.5 provides a common platform for climate models to explore the climate system response to stabilizing the anthropogenic components of radiative forcing.  相似文献   

圣安德烈斯断层南段大地震发生的准周期性     

Katherine M Scharer  Glenn P Biasi  Ray J Weldon II  Tom E Fumal  梁凯利  赵菡姿 《国际地震动态》2011,(8):21-27

圣安德烈斯断层(美国加州)南段最后一次大地震距今已有153年了,而其平均震间间隔却仅为～100年.如果大地震的复发具有周期性,而并非随机发生或群集发生,则这个时间长度是很值得关注的,而且通常意味着概率意义上的地震危险性增大.遗憾的是,多数地震记录都很简单,这就限制了对单条断层上地震复发的分布特征的描述.本文利用加州Wr...  相似文献   

The Bioavailability of Effluent-derived Organic Nitrogen along an Estuarine Salinity Gradient     

Katherine C. Filippino  Margaret R. Mulholland  Peter W. Bernhardt  George E. Boneillo  Ryan E. Morse  Matthew Semcheski  Harold Marshall  Nancy G. Love  Quinn Roberts  Deborah A. Bronk 《Estuaries and Coasts》2011,34(2):269-280

Total maximum daily loads for nitrogen (N) are currently being established for the Chesapeake Bay watershed. While we know inorganic N is bioavailable in the environment and therefore its input contributes to cultural eutrophication, the bioavailability of organic N is unclear. Using bioassay experiments, we examined the impact of effluent-derived organic nitrogen (EON) from wastewater treatment plants on natural water samples collected along an estuarine/salinity gradient within the lower Chesapeake Bay watershed. All of the inorganic N and between 31% and 96% of the EON was removed during biotic bioassays within the first 2 days. Further, there was substantial abiotic reactivity of effluent N when it was added to natural water samples. Results demonstrate that organic and inorganic N in effluent is removed to support the growth of microbial communities. These are the first results aimed at assessing the reactivity of EON in natural waters along an estuarine/salinity gradient.  相似文献   

Remediation of Dissolved BTEX Through Surface Application: A Prototype Field Investigation     

Katherine E. O'Leary  James F. Barker  Robert W. Gillham 《Ground Water Monitoring & Remediation》1995,15(4):99-109

The feasibility of surface application for remediating monoaromatic hydrocarbons (benzene, toluene, ethylbenzene, and xylenes — termed BTEX as a croup) dissolved in ground water under field conditions was investigated at a site within Canadian Forces Base. Borden. Ontario. The surface area was 25 m² and underlain by 3 to 3.5 m of unsaturated sands soil. For periods of at least 216 hours, between 43 and 72 cm/d of water containing BTEX at concentrations that averaged between 8 and 11 mg/L were continuously applied by drip irrigation. Nitrogen was added to the soil as a nutrient for the final third of the investigation.
Before the applied water reached the water table. BTEX mass losses ranged from of to essentially KM) percent. Less than 6 percent of the BTEX mass losses could be attributed to volatilization from the unsaturated soil. The remaining BTEX mass losses were attributed to biodegradation, mostly in the top 50 cm of the soil, which contained more inorganic nitrogen and organic carbon than the deeper soil. Biodegradation rates increased with applied concentration, nitrogen addition, and exposure to BTEX. Benzene concentrations in ground water attained compliance with Canadian and American drinking water standards only after nitrogen application.  相似文献   

Foreland basin systems   总被引：32，自引：1，他引：32  

Peter G. DeCelles  & Katherine A. Giles 《Basin Research》1996,8(2):105-123

A foreland basin system is defined as: (a) an elongate region of potential sediment accommodation that forms on continental crust between a contractional orogenic belt and the adjacent craton, mainly in response to geodynamic processes related to subduction and the resulting peripheral or retroarc fold-thrust belt; (b) it consists of four discrete depozones, referred to as the wedge-top, foredeep, forebulge and back-bulge depozones – which of these depozones a sediment particle occupies depends on its location at the time of deposition, rather than its ultimate geometric relationship with the thrust belt; (c) the longitudinal dimension of the foreland basin system is roughly equal to the length of the fold-thrust belt, and does not include sediment that spills into remnant ocean basins or continental rifts (impactogens). The wedge-top depozone is the mass of sediment that accumulates on top of the frontal part of the orogenic wedge, including ‘piggyback’ and ‘thrust top’ basins. Wedge-top sediment tapers toward the hinterland and is characterized by extreme coarseness, numerous tectonic unconformities and progressive deformation. The foredeep depozone consists of the sediment deposited between the structural front of the thrust belt and the proximal flank of the forebulge. This sediment typically thickens rapidly toward the front of the thrust belt, where it joins the distal end of the wedge-top depozone. The forebulge depozone is the broad region of potential flexural uplift between the foredeep and the back-bulge depozones. The back-bulge depozone is the mass of sediment that accumulates in the shallow but broad zone of potential flexural subsidence cratonward of the forebulge. This more inclusive definition of a foreland basin system is more realistic than the popular conception of a foreland basin, which generally ignores large masses of sediment derived from the thrust belt that accumulate on top of the orogenic wedge and cratonward of the forebulge. The generally accepted definition of a foreland basin attributes sediment accommodation solely to flexural subsidence driven by the topographic load of the thrust belt and sediment loads in the foreland basin. Equally or more important in some foreland basin systems are the effects of subduction loads (in peripheral systems) and far-field subsidence in response to viscous coupling between subducted slabs and mantle–wedge material beneath the outboard part of the overlying continent (in retroarc systems). Wedge-top depozones accumulate under the competing influences of uplift due to forward propagation of the orogenic wedge and regional flexural subsidence under the load of the orogenic wedge and/or subsurface loads. Whereas most of the sediment accommodation in the foredeep depozone is a result of flexural subsidence due to topographic, sediment and subduction loads, many back-bulge depozones contain an order of magnitude thicker sediment fill than is predicted from flexure of reasonably rigid continental lithosphere. Sediment accommodation in back-bulge depozones may result mainly from aggradation up to an equilibrium drainage profile (in subaerial systems) or base level (in flooded systems). Forebulge depozones are commonly sites of unconformity development, condensation and stratal thinning, local fault-controlled depocentres, and, in marine systems, carbonate platform growth. Inclusion of the wedge-top depozone in the definition of a foreland basin system requires that stratigraphic models be geometrically parameterized as doubly tapered prisms in transverse cross-sections, rather than the typical ‘doorstop’ wedge shape that is used in most models. For the same reason, sequence stratigraphic models of foreland basin systems need to admit the possible development of type I unconformities on the proximal side of the system. The oft-ignored forebulge and back-bulge depozones contain abundant information about tectonic processes that occur on the scales of orogenic belt and subduction system.  相似文献   

“These Maps Talk for Us:” Participatory Action Mapping as Civic Engagement Practice     

Amber J. Boll-Bosse  Katherine B. Hankins 《The Professional geographer》2018,70(2):319-326

Geographers have long been associated with mapping and cartography, because the visual representation of space fits neatly into the wide-ranging discipline that engages both the physical and the social worlds. Mapmaking remained in the domain of experts for centuries until the advent of new mapping technologies, which have widened the possibilities for mapmaking from experts and nonexperts alike. Simply widening participation in mapmaking does not necessarily democratize the knowledge-production process, however, as scholars have recently argued. What is required, we suggest, are critically trained geographers who take seriously both the conventions of professional cartography and the power relations embedded in and reflected in the map-making process and in maps themselves. We name participatory action mapping (PAM) as a methodology that seeks to be as effective in advancing the mapping needs of the public as it is critical in evaluating the processes through which maps are produced. PAM is a practice of civic engagement that borrows from community mapping and public participatory geographic information systems and that is deeply informed by participatory action research. We highlight the contours of PAM through a case study of our work with the Westside Atlanta Land Trust in Atlanta, Georgia.  相似文献