Sources of variability in springwater chemistry in Fool Creek,a high-elevation catchment of the Rocky Mountains,Colorado, USA     

Charles C. Rhoades  Timothy S. Fegel  Timothy P. Covino  Kathleen A. Dwire  Kelly Elder 《水文研究》2021,35(3):e14089

Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km² Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.  相似文献   

Optimal forcing of ENSO either side of the 1970’s climate shift and its implications for predictability     

Christopher M. Aiken  Agus Santoso  Shayne McGregor  Matthew H. England 《Climate Dynamics》2015,45(1-2):47-65

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Photonic dating of prehistoric irrigation canals at Phoenix,Arizona, U.S.A.*     

Glenn W. Berger  T. Kathleen Henderson  D. Banerjee  Fred L. Nials 《Geoarchaeology》2004,19(1):1-19

A number of archeological features, including in‐filled irrigation canals of uncertain prehistoric age, occur within the Holocene floodplain of the Salt River at Phoenix, Arizona. In the first attempt to date irrigation‐canal sediments using luminescence methods, we obtained age estimates of 1640 ± 190 yr B.P. (1σ) (multi‐aliquot or MA) and 1621 ± 95 yr B.P. (post‐IR single‐aliquot‐regenerative‐dose or SAR) for a single sample from the base of the oldest canal‐infilling deposits (all IR‐PSL ages reported in this article are in calendar years before A.D. 2001). For the remaining canal samples, weighted mean luminescence ages of 819 ± 45 yr (MA) and 826 ± 32 yr (post‐IR SAR) were obtained. Thus from photonic dating we can resolve the first and last phases of canal use at this Phoenix site: initiation at ca. 1600 years ago and final use at ca. 800 years ago. These results demonstrate the power of SAR luminescence sediment dating to enhance our understanding of prehistoric irrigation‐canal development and usage here and elsewhere in the world. © 2004 Wiley Periodicals, Inc.  相似文献   

Field Demonstration of the Horizontal Treatment Well (HRX Well®) for Passive In Situ Remediation     

Craig E. Divine  Jesse Wright  Michelle Crimi  J.F. Devlin  Michael Lubrecht  Jack Wang  Jeff McDonough  Michael Kladias  Jesse Hinkle  Allison Cormican  Trevor Osorno  Blossom N. Nzeribe  Fiona Laramay  Daniel Ombalski  Kathleen Gerber  Hunter Anderson 《Ground Water Monitoring & Remediation》2020,40(3):42-54

The horizontal reactive media treatment well (HRX Well®) uses directionally drilled horizontal wells filled with a treatment media to induce flow-focusing behavior created by the well-to-aquifer permeability contrast to passively capture proportionally large volumes of groundwater. Groundwater is treated in situ as it flows through the HRX Well and downgradient portions of the aquifer are cleaned via elution as these zones are flushed with clean water discharging from the HRX Well. The HRX Well concept is particularly well suited for sites where long-term mass discharge control is a primary performance objective. This concept is appropriate for recalcitrant and difficult-to-treat constituents, including chlorinated solvents, per- and polyfluoroalkyl substances (PFAS), 1,4-dioxane, and metals. A full-scale HRX Well was installed and operated to treat trichloroethene (TCE) with zero valent iron (ZVI). The model-predicted enhanced flow through the HRX Well (compared to the flow in and equivalent cross-sectional area orthogonal to flow in the natural formation before HRX Well installation) and treatment zone width was consistent with flows and widths estimated independently by point velocity probe (PVP) testing, HRX Well tracer testing, and observed treatment in downgradient monitoring wells. The actual average capture zone width was estimated to be between 45 and 69 feet. Total TCE mass discharge reduction was maintained through the duration of the performance monitoring period and exceeded 99.99% (%). Decreases in TCE concentrations were observed at all four downgradient monitoring wells within the treatment zone (ranging from 50 to 74% at day 436), and the first arrival of treated water was consistent with model predictions. The field demonstration confirmed the HRX Well technology is best suited for long-term mass discharge control, can be installed under active infrastructure, requires limited ongoing operation and maintenance, and has low life cycle energy and water requirements.  相似文献   

Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone          下载免费PDF全文

Benjamin G. Petri  Radek Fučík  Tissa H. Illangasekare  Kathleen M. Smits  John A. Christ  Toshihiro Sakaki  Carolyn C. Sauck 《Ground water》2015,53(5):685-698

The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.  相似文献   

Analytic Element Modeling of Steady Interface Flow in Multilayer Aquifers Using AnAqSim          下载免费PDF全文

Charles R. Fitts  Joshua Godwin  Kathleen Feiner  Charles McLane  Seth Mullendore 《Ground water》2015,53(3):432-439

This paper presents the analytic element modeling approach implemented in the software AnAqSim for simulating steady groundwater flow with a sharp fresh‐salt interface in multilayer (three‐dimensional) aquifer systems. Compared with numerical methods for variable‐density interface modeling, this approach allows quick model construction and can yield useful guidance about the three‐dimensional configuration of an interface even at a large scale. The approach employs subdomains and multiple layers as outlined by Fitts (2010) with the addition of discharge potentials for shallow interface flow (Strack 1989). The following simplifying assumptions are made: steady flow, a sharp interface between fresh‐ and salt water, static salt water, and no resistance to vertical flow and hydrostatic heads within each fresh water layer. A key component of this approach is a transition to a thin fixed minimum fresh water thickness mode when the fresh water thickness approaches zero. This allows the solution to converge and determine the steady interface position without a long transient simulation. The approach is checked against the widely used numerical codes SEAWAT and SWI/MODFLOW and a hypothetical application of the method to a coastal wellfield is presented.  相似文献   

Downstream effects of stream flow diversion on channel characteristics and riparian vegetation in the Colorado Rocky Mountains,USA          下载免费PDF全文

Simeon T. Caskey  Tyanna S. Blaschak  Ellen Wohl  Elizabeth Schnackenberg  David M. Merritt  Kathleen A. Dwire 《地球表面变化过程与地形》2015,40(5):586-598

Flow diversions are widespread and numerous throughout the semi‐arid mountains of the western United States. Diversions vary greatly in their structure and ability to divert water, but can alter the magnitude and duration of base and peak flows, depending upon their size and management. Channel geometry and riparian plant communities have adapted to unique hydrologic and geomorphic conditions existing in the areas subject to fluvial processes. We use geomorphic and vegetation data from low‐gradient (≤3%) streams in the Rocky Mountains of north‐central Colorado to assess potential effects of diversion. Data were collected at 37 reaches, including 16 paired upstream and downstream reaches and five unpaired reaches. Channel geometry data were derived from surveys of bankfull channel dimensions and substrate. Vegetation was sampled using a line‐point intercept method along transects oriented perpendicular to the channel, with a total of 100 sampling points per reach. Elevation above and distance from the channel were measured at each vegetation sampling point to analyze differences in lateral and vertical zonation of plant communities between upstream and downstream reaches. Geomorphic data were analyzed using mixed effects models. Bankfull width, depth, and cross‐sectional area decreased downstream from diversions. Vegetation data were analyzed using biological diversity metrics, richness, evenness and diversity, as well as multivariate community analysis. Evenness increased downstream from diversions, through reduced frequency of wetland indicator species and increased frequency of upland indicator species. Probability of occurrence for upland species downstream of a diversion increases at a greater rate beginning around 0·5 m above active channel. The results suggest that channel morphology and riparian plant communities along low‐gradient reaches in montane environments in the Colorado Rocky Mountains are impacted by diversion‐induced flow alteration, with the net effect of simplifying and narrowing the channel and homogenizing and terrestrializing riparian plant communities. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Europe between the oceans: Themes and variations: 9000 BC–AD 1000. Barry Cunliffe, 2008, Yale University Press,New Haven and London, 480 pp., ISBN: 978‐0‐300‐11923‐7, $39.95 (hardcover)     

Kathleen A. Nicoll 《Geoarchaeology》2009,24(6):855-856

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Behaviour of hatchery‐reared and wild‐caught 4th and 5th stage American lobsters,Homarus americanus     

Kathleen M. Castro  J. Stanley Cobb 《新西兰海洋与淡水研究杂志》2013,47(4):963-972

Behavioural deficiencies in 4th and 5th stage hatchery‐reared lobsters were examined using time budget analysis and predator trials. Hatchery‐reared 4th stage lobsters were found to behave differently than wild‐caught lobsters and differences existed between hatchery‐reared lobsters from different sources. Local hatchery‐reared 4th stage lobsters spent less time on shelter and suffered higher predator rates in laboratory trials than both wild‐caught 4th stage and lobsters reared in a hatchery in Maine. Fifth stage hatchery‐reared lobsters spent significantly more time in shelter than their wild‐caught counterparts. These differences may be attributable to the lack of development of proper predator‐avoidance behaviour and need to be understood and corrected to maximise the effect of enhancement projects.  相似文献   

New marine ΔR values for Arctic Canada   总被引：1，自引：0，他引：1  

Roy D. Coulthard  Mark F.A. Furze  Anna J. Pieńkowski  F. Chantel Nixon  John H. England 《Quaternary Geochronology》2010,5(4):419-434

For more than four decades, the reporting of ¹⁴C dates on marine molluscs from Arctic Canada has been notable for the lack of consistently applied marine reservoir corrections. We propose that the common approach of reporting Canadian Arctic marine ¹⁴C dates using presumed time-invariant reservoir corrections be abandoned in favour of calibration of ¹⁴C dates, using the current standard protocol. This approach best facilitates inter- and intra-regional correlation, and correlation with other geochronometers. In order to enable the consistent calibration of marine ¹⁴C dates from Arctic Canada, we analysed a ¹⁴C database of 108 marine mollusc samples collected live between 1894 and 1956, and determined regional reservoir offset values (ΔR) for eight oceanographically distinct regions. The following new ΔR values should be used for ¹⁴C calibration: NW Canadian Arctic Archipelago, 335 ± 85 yrs; Foxe Basin, 310 ± 90 yrs; NE Baffin Island, 220 ± 20 yrs; SE Baffin Island, 150 ± 60 yrs; Hudson Strait, 65 ± 60 yrs; Ungava Bay, 145 ± 95 yrs; Hudson Bay, 110 ± 65 yrs; and James Bay, 365 ± 115 yrs.  相似文献