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Geologic seepage of methane and light (C2-C5) alkanes was measured at the La Brea Tar Pits in Los Angeles. Samples were collected using flux chambers with stainless steel canisters and analyzed using gas chromatography. Average seepage rates from individual seepage sites were 970 ± 330 mg/h of methane, 14.0 ± 5.5 mg/h of ethane, 9.1 ± 3.7 mg/h of propane, 3.7 ± 1.6 mg/h of i-butane, 0.33 ± 0.16 mg/h of n-butane, 260 ± 120 μg/h of i-pentane, and 5.3 ± 1.9 μg/h of n-pentane, while maximum seepage rates exceeded 17 g/h of methane, 270 mg/h of ethane, 190 mg/h of propane, 95 mg/h of i-butane, 10 mg/h of n-butane, 7 mg/h of i-pentane, and 0.1 mg/h of n-pentane. These absolute fluxes have an additional unknown amount of error associated with them due to sampling methodology, and should be taken as the lower limit of emissions. Samples collected revealed generally dry gas, with high methane emissions relative to the light alkanes. Overall emissions from the tar pits were found to come not only from the active geologic seepage, but also from the outgassing of the standing asphalt at the site. Using the gas ratios, which are negligibly affected by errors introduced by sampling methodology, observed in this study, daily emissions of C2 – C5 alkanes from the La Brea area were estimated to be 4.7 ± 1.6 Mg, which represents 2–3 % of total emissions in the entire Los Angeles region.  相似文献   
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Possible configurations of the magnetic field in the outer magnetosphere during geomagnetic polarity reversals are investigated by considering the idealized problem of a magnetic multipole of order m and degree n located at the centre of a spherical cavity surrounded by a boundless perfect diamagnetic medium. In this illustrative idealization, the fixed spherical (magnetopause) boundary layer behaves as a perfectly conducting surface that shields the external diamagnetic medium from the compressed multipole magnetic field, which is therefore confined within the spherical cavity. For a general magnetic multipole of degree n, the non-radial components of magnetic induction just inside the magnetopause are increased by the factor 1 + [(n + 1)/n] relative to their corresponding values in the absence of the perfectly conducting spherical magnetopause. An exact equation is derived for the magnetic field lines of an individual zonal (m = 0), or axisymmetric, magnetic multipole of arbitrary degree n located at the centre of the magnetospheric cavity. For such a zonal magnetic multipole, there are always two neutral points and n – 1 neutral rings on the spherical magnetopause surface. The two neutral points are located at the poles of the spherical magnetopause. If n is even, one of the neutral rings is coincident with the equator; otherwise, the neutral rings are located symmetrically with respect to the equator. The actual existence of idealized higher-degree (n > 1) axisymmetric magnetospheres would necessarily imply multiple (n + 1) magnetospheric cusps and multiple (n) ring currents. Exact equations are also derived for the magnetic field lines of an individual non-axisymmetric magnetic multipole, confined by a perfectly conducting spherical magnetopause, in two special cases; namely, a symmetric sectorial multipole (m = n) and an antisymmetric sectorial multipole (m = n – 1). For both these non-axisymmetric magnetic multipoles, there exists on the spherical magnetopause surface a set of neutral points linked by a network of magnetic field lines. Novel magnetospheric processes are likely to arise from the existence of magnetic neutral lines that extend from the magnetopause to the surface of the Earth. Finally, magnetic field lines that are confined to, or perpendicular to, either special meridional planes or the equatorial plane, when the multipole is in free space, continue to be confined to, or perpendicular to, these same planes when the perfectly conducting magnetopause is present.Also Honorary Research Associate, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX, UK and Visiting Reader in Physics. University of Sussex, Falmer, Brighton BN1 9QH, UK  相似文献   
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Willis  Bhattacharya  Gabel  & White 《Sedimentology》1999,46(4):667-688
The Frewens sandstone is composed of two elongate tide-influenced sandstone bodies that are positioned directly above and slightly landward of a more wave-influenced lobate sandstone. The 20-km-long, 3-km-wide Frewens sandstone bodies coarsen upwards and fine away from their axes, have gradational bases and margins and have eroded tops abruptly overlain by marine shales. These sandstones are superbly exposed in large cliffs on the banks of the South Fork of the Powder River in central Wyoming, USA. The deposits change upwards from thinly interbedded sandstones and mudstones to metre-thick heterolithic cross-strata and, finally, to metres-thick sandstone-dominated cross-strata. There is abundant evidence for tidal modulation of depositional flows; however, palaeocurrents were strongly ebb-dominated and nearly parallel the trend of sandstone-body elongation. Detailed mapping of stratal geometry and facies across these exposures shows a complex internal architecture. Large-scale bedding units within sandstone bodies are defined by alternations in facies, bed thickness and the abundance of shales. Such bedsets are inclined (5°–15°) in walls oriented parallel to palaeoflow and gradually decrease in dip over hundreds of metres as they extend from the sandstone-dominated deposits higher in a sandstone body to muddier deposits lower in the body. Where viewed perpendicular to palaeoflow, bedsets are 100-metre-wide lenses that shingle off the sandstone-body axis towards its margins. The sandstone bodies are interpreted as sand ridge deposits formed on the shoreface of a tide-influenced river delta. Metres-thick cross-strata in the upper parts of sandstone bodies resemble deposits of bars (sandwaves) formed where tidal currents moved across shallows and the tops of tidal ridges. Heterolithic deposits lower in sandstone bodies record fluctuating currents caused by ebb and flood tides and varying river discharge. Erosion surfaces capping sandstone bodies record tidal ravinement. The tidal ridges were abandoned following transgression and covered with marine mud as waters deepened.  相似文献   
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This paper investigates the impact of rapid small-scale water vapor fluctuations on GPS height determination. Water vapor measurements from a Raman lidar are used for documenting the water vapor heterogeneities and correcting GPS signal propagation delays in clear sky conditions. We use data from four short observing sessions (6 h) during the VAPIC experiment (15 May–15 June 2004). The retrieval of wet delays from our Raman lidar is shown to agree well with radiosonde retrievals (bias and standard deviation (SD) were smaller than 1 and 2.8 mm, respectively) and microwave radiometers (from two different instruments, bias was 6.0/−6.6 mm and SD 1.3/3.8 mm). A standard GPS data analysis is shown to fail in accurately reproducing fast zenith wet delay (ZWD) variations. The ZWD estimates could be improved when mean post-fit phase residuals were removed. Several methodologies for integrating zenith lidar observations into the GPS data processing are also presented. The final method consists in using lidar wet delays for correcting a priori the GPS phase observations and estimating a scale factor for the lidar wet delays jointly with the GPS station position. The estimation of this scale factor allows correcting for a mis-calibration in the lidar data and provides in the same way an estimate of the Raman lidar instrument constant. The agreement of this constant with an independent determination using radiosonde data is at the level of 1–4%. The lidar wet delays were derived by ray-tracing from zenith pointing measurements: further improvement in GPS positioning is expected from slant path lidar measurements that would properly account for water vapor anisotropy.  相似文献   
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Choosing a simple class of flows, with characteristics that may be present in the Earth's core, we study the ability to generate a magnetic field when the flow is permitted to oscillate periodically in time. The flow characteristics are parameterised by D, representing a differential rotation, M, a meridional circulation, and C, a component characterising convective rolls. The dynamo action of all solutions with fixed parameters (steady flows) is known from earlier studies. Dynamo action is sensitive to these flow parameters and fails spectacularly for much of the parameter space where magnetic flux is concentrated into small regions, leading to high diffusion. In addition, steady flows generate only steady or regularly reversing oscillatory fields and cannot therefore reproduce irregular geomagnetic-type reversal behaviour. Oscillations of the flow are introduced by varying the flow parameters in time, defining a closed orbit in the space ( D,?M ). When the frequency of the oscillation is small, the net growth rate of the magnetic field over one period approaches the average of the growth rates for steady flows along the orbit. At increased frequency time-dependence appears to smooth out flux concentrations, often enhancing dynamo action. Dynamo action can be impaired, however, when flux concentrations of opposite signs occur close together as smoothing destroys the flux by cancellation. It is possible to produce geomagnetic-type reversals by making the orbit stray into a region where the steady flows generate oscillatory fields. In this case, however, dynamo action was not found to be enhanced by the time-dependence. A novel approach is being taken to solve the time-dependent eigenvalue problem where, by combining Floquet theory with a matrix-free Krylov-subspace method, we can avoid large memory requirements for storing the matrix required by the standard approach.  相似文献   
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