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31.
Using a recently developed petrogenetic grid for MORB + H2O, we propose a new model for the transportation of water from the subducting slab into the mantle transition zone. Depending on the geothermal gradient, two contrasting water-transportation mechanisms operate at depth in a subduction zone. If the geothermal gradient is low, lawsonite carries H2O into mantle depths of 300 km; with further subduction down to the mantle transition depth (approximately 400 km) lawsonite is no longer stable and thereafter H2O is once migrated upward to the mantle wedge then again carried down to the transition zone due to the induced convection. At this depth, hydrous β-phase olivine is stable and plays a role as a huge water reservoir. In contrast, if the geothermal gradient is high, the subducted slab may melt at 700–900 °C at depths shallower than 80 km to form felsic melt, into which water is dissolved. In this case, H2O cannot be transported into the mantle below 80 km. Between these two end-member mechanisms, two intermediate types are present. In the high-pressure intermediate type, the hydrous phase A plays an important role to carry water into the mantle transition zone. Water liberated by the lawsonite-consuming continuous reaction moves upward to form hydrous phase A in the hanging wall, which transports water into deeper mantle. This is due to a unique character of the reaction, because Phase A can become stable through the hydration reaction of olivine. In the case of low-pressure intermediate type, the presence of a dry mantle wedge below 100 km acts as a barrier to prevent H2O from entering into deeper mantle.  相似文献   
32.
Detailed experimental and theoretical studies of the k=0 vibrational spectra of anhydrite and gypsum are reported. The dielectric constants and the infrared reflection and Raman spectra of the single crystal have been measured. The frequencies of the phonon spectrum, the contribution of potential terms to potential energy and detailed mode assignments have been determined based on a polarizable-ion model. The relative experimental intensity of the spectra, the observed crystal field effects, the rotatory lattice modes of the H2O molecule and the mixed character of translatory and rotatory modes of the Ca, SO4, and H2O groups are discussed based on the theoretical vibrational modes and the potential energy distribution. The principal moments of inertia of the water molecule and the Lennard-Jones potential constants for nonbonded oxygen-oxygen interactions are presented.  相似文献   
33.
Leg 2 of the French-Japanese 1984 Kaiko cruise has surveyed the trench triple junction off central Japan, where the Japan, Izu-Bonin and Sagami Trenches intersect. The Izu-Bonin Trench is deeper than the Japan Trench and filled by a thick turbiditic series. Its anomalous depth is explained by the westward retreat of the edge of the northwestward moving Philippine Sea plate. On the contrary to what happens in the Japan Trench, horst and graben structures of the Pacific plate obliquely enters the Izu-Bonin Trench, suggesting that the actual boundary between these two trenches is located to the north of the triple junction. The inner wall of the Izu-Bonin Trench is characterized in the triple junction area by a series of slope basins whose occurrence is related to the dynamics of this area. The northernmost basin is overthrust by the edge of the fore-arc area of the Northeast Japan plate. The plate boundary is hardly discernible further east, which makes it impossible to locate precisely the triple junction itself. These features suggest that large intra-plate deformation occurs there due to the interaction of the plates involved in the triple junction and the weak mechanical strength of the wedge-shaped margin of the overriding plates.  相似文献   
34.
An analysis of the time series data sets collected from the 1960s to 1990s in the Oyashio Water revealed signs of alteration in the physical, chemical and biological properties of the water column in the western subarctic North Pacific. Wintertime salinity, phosphate concentration and apparent oxygen utilization (AOU) in the subsurface increased linearly over the 30 years. At the same time, salinity and phosphate in the surface mixed layer decreased. An increase in the density gradient in the surface and subsurface suggested that the water column stratification intensified, reducing the vertical exchange of water properties during the period. The Net Community Production (NCP), estimated from the phosphate consumption from February through August, also declined. Water column Chl a was approximately halved and diatoms decreased by one order of magnitude in spring, consistent with the multi-decadal decreasing trend of NCP. Zooplankton biomass was also nearly halved during the same period. In contrast, wintertime Chl a increased by 63% and diatom abundance doubled. Developmental timing became earlier in Neocalanus flemingeri, and spring occurrence of N. plumchrus increased after the 1980s. Reduced vertical water exchange might have limited nutrient supply to the level, decreasing winter-summer NCP for these three decades. It is speculated that, in the meantime, the earlier stabilization of the surface layer might have enhanced wintertime diatom production in the Oyashio's light-limited environment. This condition could allow zooplankton to effectively utilize diatoms from earlier timing, resulting in the apparent early developmental timing and abundance increase. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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The sorption of phosphorus by using four different natural materials (marble dust, sawdust, soil, and rice husk) was studied by conducting batch tests and kinetic sorption model. The kinetic sorption model based on a pseudo equation was applied to predict the rate constant of sorption. Thorough investigations to understand the mechanism of phosphorus sorption onto the natural materials using kinetic sorption models, pseudo first- and second-order kinetic sorption model showed that the kinetic sorption is consistent with the second-order model, from which it can be inferred that the mechanism of sorption is chemisorption. Batch tests and kinetic sorption model results showed that by using marble dust as sorbent, among other materials, could remove more than 93 % of phosphorus from aqueous solution.  相似文献   
38.
In order to understand the kinematics which likely facilitated the speedy rupturing process of the 1999 Mw 7.6 Taiwan Chi-Chi earthquake, we examined exposed rocks in the Taiwan Slate belt, where the pressure and temperature conditions most resembled the hypocentre of the Chi-Chi earthquake, i.e. sub-greenschist facies. Field observations and composition analyses of the silicified vein-rich zones beneath the duplex structure suggest that impermeable slate layers may serve as cap rocks for confining deep-seated fluids. These fluids most likely come from the Taiwan metamorphic complex at deeper depths by the dehydration and decarbonation reactions (or partial melting). In addition, the gouge zone of a link fault above the detachment also indicates the presence of overpressured fluids during faulting. It is probable that episodic leakage of the confined fluid reservoirs may provide essential fluids for fault lubrication during earthquake ruptures.  相似文献   
39.
A comparison between commonly used techniques for hydrograph recession analysis, namely the semi‐logarithmic plot of a single recession segment, the master recession and a relatively new approach based on wavelet transform was carried out. These methods were applied to a number of flood hydrograph events of two catchments in West Java, Indonesia. The results show that all the methods tested produce reasonable and comparable results. However, problems arise in the semi‐logarithmic plot and the master recession, i.e. determining the recession parameter K is not an easy task especially where the plotted data on a semi‐logarithmic plot is not a linear but a curved line. On a curved line, the end of direct flow or starting point of baseflow is not clear and it is quite difficult to identify. Hence, the best line as a basis for computing the recession parameter K becomes uncertain. The wavelet transform approach, however, produces promising results and minimizes a number of problems associated with hydrograph recession analysis. The end of direct flow and the location of the baseflow component are easily determined through the wavelet maps. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
40.
Nine submersible dives were made in three trenches off central Japan, between 2990 and 5900 m of water depth. Our observations confirm the interpretation that Daiichi-Kashima Seamount is a Cretaceous guyot formed on the Pacific plate that has traveled into the Japan Trench. We also confirmed the previous interpretation of a large normal fault that splits the seamount in two halves, the lower one being now subducting beneath the Japan margin. Compressional deformation was identified within the lower part of the inner slope in front of the seamount. The pattern of deformation that affects Quaternary sediments is in agreement with the present kinematics of the convergence between the Pacific plate and Japan. Deep-water (5700 m) clam colonies are associated with advection of fluids, driven by the subduction-related overpressures. In the northern slope of the Boso Canyon, along the Sagami Trough system (Philippine Sea plate-Japan boundary), the deformation affecting a thick upper Miocene to lower Pliocene sequence indicates two directions of shortening: a N175°E direction which is consistent with the present relative motion along the Sagami Trough (N285–N300°E) and a N30°E direction which could be related to a more northerly direction of convergence that occured during the early Quaternary and earlier.  相似文献   
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