The F,Cl, Br and I Contents of Reference Glasses BHVO‐2G,BIR‐1G,BCR‐2G,GSD‐1G,GSE‐1G,NIST SRM 610 and NIST SRM 612          下载免费PDF全文

Michael A. W. Marks  Mark A. Kendrick  G. Nelson Eby  Thomas Zack  Thomas Wenzel 《Geostandards and Geoanalytical Research》2017,41(1):107-122

Halogen contents for the widely distributed reference glasses BHVO‐2G, BIR‐1G, BCR‐2G, GSD‐1G, GSE‐1G, NIST SRM 610 and NIST SRM 612 were investigated by pyrohydrolysis combined with ion chromatography, total reflection X‐ray fluorescence analysis, instrumental neutron activation analysis, the noble gas method, electron probe microanalysis and laser ablation‐inductively coupled plasma‐mass spectrometry. Glasses BHVO‐2G, GSD‐1G and GSE‐1G have halogen contents that can be reproduced at the 15% level by all bulk techniques and cover a significant range in halogen mass fractions for F (~ 20–300 μg g^?1), Cl (~ 70–1220 μg g^?1) and Br (~ 0.2–285 μg g^?1) and I (~ 9–3560 ng g^?1). The BIR‐1G glass has low F (< 15 μg g^?1), Cl (~ 20 μg g^?1), Br (15 ng g^?1) and I (3 ng g^?1). The halogen contents for the silica‐rich NIST SRM 610 and 612 glasses were poorly reproduced by the different techniques. The relatively high Cl, Br and I abundances in glasses GSD‐1G and GSE‐1G mean that these glasses are well suited for calibrating spatially resolved micro‐analytical studies on silicate glasses, melt and fluid inclusions. Combined EPMA and laser ablation‐inductively coupled plasma‐mass spectrometry data for glass GSE‐1G demonstrate homogeneity at the 10% level for Cl and Br.  相似文献   

USE OF BOMB-¹⁴C TO INVESTIGATE THE GROWTH AND CARBON TURNOVER RATES OF A CRUSTOSE LICHEN     

BY MARK H. GARNETT  TOM BRADWELL 《Geografiska Annaler: Series A, Physical Geography》2010,92(1):53-63

The reliability of lichenometric dating is dependent on a good understanding of lichen growth rates. The growth rate of lichens can be determined from direct measurement of growing lichens or indirect methods by measuring lichens growing on surfaces of known age, although there are limitations to both approaches. Radiocarbon (¹⁴C) analysis has previously been used in only a handful of studies to determine lichen growth rates of two species from a small area of North America. These studies have produced mixed results; a small amount of carbon turnover appears to occur in one of the species ( Caloplaca spp.) previously investigated introducing uncertainty in the growth rate, while much higher carbon cycling occurred in another ( Rhizocarpon geographicum ), making the ¹⁴C approach unsuitable for estimating growth rates in the species most commonly used in lichenometric dating. We investigated the use of bomb-¹⁴C analysis to determine the growth rate of a different crustose species ( Pertusaria pseudocorallina ) common to Northern Europe. ¹⁴C-based growth rates were considerably higher than growth rates of morphologically similar species based on direct measurement made at locations nearby and elsewhere in the UK. This observation strongly suggests that a degree of carbon turnover probably occurs in Pertusaria pseudocorallina , and that bomb-¹⁴C analysis alone cannot be used to determine lichen age or absolute growth rates in this lichen species.  相似文献   

Carbon cycle studies based on the distribution of O₂ in air   总被引：1，自引：1，他引：0  

MICHAEL L. BENDER  MARK O. BATTLE 《Tellus. Series B, Chemical and physical meteorology》1999,51(2):165-169

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The type section of the Vikinghôgda Formation: a new Lower Triassic unit in central and eastern Svalbard     

ATLE MØRK  GEIR ELVEBAKK  ARNE W. FORSBERG  MARK W. HOUNSLOW.  HANS ARNE NAKREM.  JORUNN OS VIGRAN  WOLFGANG WEITSCHAT 《Polar research》1999,18(1):51-82

The Vikinghøgda Formation (250 m) is defined with a stratotype in Deltadalen-Vikinghøgda in central Spitsbergen. The Vikinghøgda Formation replaces the Vardebukta and Sticky Keep Formations of Buchan et al. (1965) and the lower part of the Barentsøya Formation of Lock et al. (1978) as extended geographically by Mørk, Knarud et al. (1982) in central Spitsbergen, Barentsøya and Edgeøya. The formation consists of three member: the Deltadalen Member (composed of mudstones with sandstones and siltstones), the Lusitaniadalen Member (dominated by mudstones with thin siltstone beds and some limestone concretions) and the Vendomdalen Member (composed of dark shales with dolomite interbeds and nodules). The Lusitaniadalen and Vendomdalen members replace the former Sticky Keep Formation/ Member in the siirne areu. The Vikinghøda Formation can be followed through central and eastern Spitsbergen to Barentøya and Edgeøya and includes all sediments between the chert-rich Kapp Starostin Formation (Permian) and the organic-rich shales of the Botneheia Formation (Middle Triassic). The subdivision into three members is also reflected in the organic carbon content and palynofacies. Upwards. each succeeding member becomes more distal, organic-rich and oil-prone than the one below.
The Vikinghøda Formation is well-dated by six ammonoid zones. although the transitional beds between the Deltadalen and Lusitaniadalen members lack age diagnostic macrofossils. Corresponding palynozonation and magnetustratigraphy have also been determined. The overall stratigraphical development correlates well with other key Triassic areas in the Arctic, although intervals in the late Dienerian and early Smithian may be condensed or missing.  相似文献   

A preliminary history of Holocene colluvial (debris-flow) activity,Leirdalen, Jotunheimen,Norway     

JOHN A. MATTHEWS  SVEIN-OLAF DAHL  MARK S. BERRISFORD  ATLE NESJE  P. QUENTIN DRESSER  LISA DUMAYNE-PEATY 《第四纪科学杂志》1997,12(2):117-129

A stratigraphic succession of alternating peat and minerogenic sediments at the foot of a steep mountain slope provides the basis for the reconstruction of a preliminary colluvial history from the alpine zone of Jotunheimen, southern Norway. Layers of silty sand and sandy silt, typically 5–10 cm thick and interpreted as distal debris-flow facies, are separated by layers of peat that have been radiocarbon dated. Deposition from at least 7500 to about 3800 ¹⁴C yr BP of predominantly minerogenic material suggests relatively infrequent but large-magnitude debris-flow events in an environment warmer and/or drier than today. Particularly low colluvial activity between about 6500 and 3900 ¹⁴C yr BP was terminated by a succession of major debris-flow events between about 3800 and 3400 ¹⁴C yr BP. Unhumified peats indicative of higher water tables, separate six debris-flows that occurred between about 3300 and 2300 ¹⁴C yr BP and signify a continuing high frequency of colluvial activity. Uninterrupted peat accumulation between about 2400 and 1600 ¹⁴C yr BP indicates reduced debris-flow activity; subsequent renewed activity appears to have culuminated in the ‘Little Ice Age’ after about 600 ¹⁴C yr BP. This pattern of colluvial deposition demonstrates a long history of natural Holocene low-alpine landscape instability, suggests an increase first in the magnitude and then in the frequency of debris-flow activity coincident with late Holocene climatic deterioration, and points to the potential of debris-flow records as a unique source of palaeoclimatic information related to extreme rainfall events. © 1997 John Wiley & Sons, Ltd.  相似文献   

Source,timing, frequency and flux of ice‐rafted detritus to the Northeast Atlantic margin, 30–12 ka: testing the Heinrich precursor hypothesis     

ANNA I. HAAPANIEMI  JAMES D. SCOURSE  VICTORIA L. PECK  HILARY KENNEDY  PAUL KENNEDY  SIDNEY R. HEMMING  MARK F. A. FURZE  ANNA J. PIEŃKOWSKI  WILLIAM E. N. AUSTIN  JOHN WALDEN  EMILIE WADSWORTH  IAN R. HALL 《Boreas: An International Journal of Quaternary Research》2010,39(3):576-591

Haapaniemi, A.I., Scourse, J.D., Peck, V.L., Kennedy, H., Kennedy, P., Hemming, S.R., Furze, M.F.A., Pieńkowski, A.J., Austin, W.E.N., Walden, J., Wadsworth, E. & Hall, I.R. 2010: Source, timing, frequency and flux of ice‐rafted detritus to the Northeast Atlantic margin, 30–12 ka: testing the Heinrich precursor hypothesis. Boreas, Vol. 39, pp. 576–591. 10.1111/j.1502‐3885.2010.00141.x. ISSN 0300‐9483. Increased fluxes of ice‐rafted detritus (IRD) from European ice sheets have been documented some 1000–1500 years before the arrival of Laurentide Ice Sheet (LIS)‐sourced IRD during Heinrich (H) events. These early fluxes have become known as ‘precursor events’, and it has been suggested that they have mechanistic significance in the propagation of H events. Here we present a re‐analysis of one of the main cores used to generate the precursor concept, OMEX‐2K from the Goban Spur covering the last 30 ka, in order to identify whether the British–Irish Ice Sheet (BIIS) IRD fluxes occur only as precursors before H layers. IRD characterization and planktonic foraminiferal δ¹⁸O measurements constrained by a new age model have enabled the generation of a continuous record of IRD sources, timing, frequency and flux, and of local contemporary hydrographic conditions. The evidence indicates that BIIS IRD precursors are not uniquely, or mechanistically, linked to H events, but are part of the pervasive millennial‐scale cyclicity. Our results support an LIS source for the IRD comprising H layers, but the ambient glacial sections are dominated by assemblages typical of the Irish Sea Ice Stream. Light isotope excursions associated with H events are interpreted as resulting from the melting of the BIIS, with ice‐sheet destabilization attributed to eustatic jumps generated by LIS discharge during H events. This positive‐feedback mechanism probably caused similar responses in all circum‐Atlantic ice‐sheet margins, and the resulting gross freshwater flux contributed to the perturbation of the Atlantic Meridional Overturning Circulation during H events.  相似文献   

Halogens and noble gases in sedimentary formation waters and Zn–Pb deposits: A case study from the Lennard Shelf,Australia     

M.A. Kendrick  D. Phillips  M. Wallace  J.McL. Miller 《Applied Geochemistry》2011,26(12):2089-2100

Halogen ratios (Br/Cl and I/Cl) and concentrations provide important information about how sedimentary formation waters acquire their salinity, but the possible influence of organic Br derived from sedimentary wall-rocks is rarely quantified. Here, it is demonstrated that Br/Cl versus I/Cl mixing diagrams can be used to deconvolve organic Br contributions; that organic matter has a limited range of Br/I ratios; and that organic Br is a more significant component in Zn–Pb deposit ore fluids than previously recognised. The significance of these findings is illustrated for the Lennard Shelf Zn–Pb deposits of Western Australia.Fluid inclusions related to Lennard Shelf Zn–Pb mineralisation have variable salinity and hydrocarbon contents. The halogen data from these fluid inclusions require mixing of three fluid end-members: (1) an evaporated seawater bittern brine (30 wt.% NaCl equiv.) with greater than seawater Br/Cl ratio; (2) a lower salinity pore fluid (?5 wt.% NaCl equiv.) with moderately elevated Br/Cl and I/Cl; and (3) fluids with Br/Cl ratios of ～5 times seawater and extremely elevated I/Cl ratios of ～11,500 times seawater. The first two fluids have ⁴⁰Ar/³⁶Ar of 300–400 and greater than air saturated water ³⁶Ar concentrations that are typical of fluid inclusions related to Zn–Pb mineralisation. The third ‘organic-rich’ fluid has the highest ⁴⁰Ar/³⁶Ar ratio of up to 1500 and a depleted ³⁶Ar concentration.Mineralisation is interpreted to have resulted from mixing of Zn-rich evaporitic brines and H₂S present in hydrocarbons. It is suggested that aqueous fluids acquired organic Br and I from hydrocarbons, and that hydrocarbons exsolving from the aqueous fluid removed noble gases from solution. Interaction of variably saline brines and hydrocarbons could account for the variable Br/Cl and I/Cl composition, and ³⁶Ar concentrations, recorded by Lennard Shelf fluid inclusions. The distinct ⁴⁰Ar/³⁶Ar signature of the fluid with the highest I/Cl ratio suggests the hydrocarbons and brines were sourced independently from different parts of the sedimentary basin. These data indicate the complementary nature of halogen and noble gas analysis and provide new constraints on important mixing processes during sediment-hosted Zn–Pb mineralisation.  相似文献   

Identifying key processes in the hydrochemistry of a basin through the combined use of factor and regression models   总被引：5，自引：0，他引：5  

SANDOW MARK YIDANA  BRUCE BANOENG-YAKUBO  PATRICK ASAMOAH SAKYI 《Journal of Earth System Science》2012,121(2):491-507

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Stratigraphy,sedimentology, age and palaeoenvironment of marine varved clay in the Middle Swedish end‐moraine zone     

MARK D. JOHNSON  YLVA STÅHL 《Boreas: An International Journal of Quaternary Research》2010,39(2):199-214

Johnson, M. D. & Ståhl, Y. 2009: Stratigraphy, sedimentology, age and palaeoenvironment of marine varved clay in the Middle Swedish end‐moraine zone. Boreas, 10.1111/j.1502‐3885.2009.00124.x. ISSN 0300‐9483 Deglaciation of the Middle Swedish end‐moraine zone and age of the sediment in and between the moraines have been discussed for about a hundred years. The goal of this project was to determine the stratigraphy and age of the sediment in and between the moraines. Inter‐moraine flats are underlain by clay, 10–25 m thick, overlying thin sand and gravel or till on bedrock. The clay is overlain by a few metres of sand and gravel. Much of the clay beneath the flats consists of rhythmites that grade from grey to red and are 2–74 cm thick. Our interpretation of these rhythmites as being varves is supported by grain size and mineralogical and elemental variations. Foraminifera and ostracods show that the clay was deposited in an arctic marine environment, while radiocarbon dating of the microfossils indicates that the clay was deposited 12 150 cal. ¹⁴C years ago, during the Younger Dryas chronozone (YD). Most of the optical stimulated luminescence dates on the clay are much older, containing quartz sand that was insufficiently bleached. The stratigraphy indicates that the moraines are composed of YD clay pushed into ridge forms during ice‐front oscillations. It is not possible to determine how far north the Scandinavian Ice Sheet retreated prior to the YD advance. We neither support nor reject the suggestion that the ice margin retreated to the northern edge of Mt. Billingen during the Allerød, causing the Baltic Ice Lake to drain.  相似文献   

Holocene fire disturbance in the boreal forest of central Sweden     

Kendrick J. Brown  Thomas Giesecke 《Boreas: An International Journal of Quaternary Research》2014,43(3):639-651

Holocene fire disturbance and vegetation history were reconstructed using macroscopic charcoal and pollen accumulation rates from two lake sediment records (Holtjärnen and Klotjärnen) collected in the boreal forest of central Sweden. The records were used to examine the potential drivers associated with changes in fire regime. Climate, vegetation and human activity were all identified as factors variously influencing the fire regime. In the early Holocene, near bicentennial fire return intervals were regionally widespread, suggesting that fire disturbance was largely regulated by climate at that time. In the mid‐ and late Holocene, vegetation exerted an important control on the fire regime. During the mid‐Holocene, the expansion of thermophilous broadleaf vegetation offset the influence of warmer climate by altering the local microclimate and by changing the structure and flammability of the available fuels. During the transition to the late Holocene, thermophilous vegetation decreased in abundance and Pinus increased, resulting in a more flammable forest even though the climate was cooling and moistening. Fire disturbance correspondingly increased. The modern boreal forest was established in the late Holocene as Picea expanded regionally as the climate cooled, moistened, and became increasingly continental. Although no change in the frequency of fire was apparent at this time, increased stand densities likely facilitated greater fuel consumption in subsequent fires. Within the last millennium, human action markedly modified the forested landscape, altering the fire regime.  相似文献