Happy Jack Uraninite: A New Reference Material for High Spatial Resolution Analysis of U‐Rich Matrices     

Corinne Dorais  Antonio Simonetti  Loretta Corcoran  Tyler L. Spano  Peter C. Burns 《Geostandards and Geoanalytical Research》2020,44(1):125-132

There is currently a lack of well‐characterised matrix‐matched reference materials (RMs) for forensic analysis of U‐rich materials at high spatial resolution. This study reports a detailed characterisation of uraninite (nominally UO_2+x) from the Happy Jack Mine (UT, USA). The Happy Jack uraninite can be used as a RM for the determination of rare earth element (REE) mass fractions in nuclear materials, which provide critical information for source attribution purposes. This investigation includes powder X‐ray diffraction (pXRD) data, as well as major, minor and trace element abundances determined using a variety of micro‐analytical techniques. The chemical signature of the uraninite was investigated at the macro (cm)‐scale with micro‐X‐ray fluorescence (µXRF) mapping and at high spatial resolution (tens of micrometre scale) using electron probe microanalysis (EPMA) and laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) analyses. Based on EPMA results, the uraninite is characterised by homogeneous UO₂ and CaO contents of 91.57 ± 1.49% m/m (2s uncertainty) and 2.70 ± 0.38% m/m (2s), respectively. Therefore, CaO abundances were used as the internal standard when conducting LA‐ICP‐MS analyses. Overall, the major element and REE compositions are homogeneous at both the centimetre and micrometre scales, allowing this material to be used as a RM for high spatial resolution analysis of U‐rich samples.  相似文献   

Cartoblography: Experiments in Using and Organising the Spatial Context of Micro‐blogging     

Kenneth Field  James O'Brien 《Transactions in GIS》2010,14(Z1):5-23

Blogs, micro‐blogs and online forums underpin a more interconnected world. People communicate ever more and are increasingly keen to explain and illustrate their lives; showing where they are and what they are doing. Desktop, online and mobile mapping landscapes have never been as rich or diverse yet this challenges cartography to adapt and remain relevant in the modern mapping world. We explore the spatial expression and potential value of micro‐blogging and Twitter as a social networking tool. Examples of “twitter maps” are reviewed that leverage the Twitter API and online map services to locate some component of the “tweet”. Scope, function and design are illustrated through development of two proof‐of‐concept map mashups that support collaborative real‐time mapping and the organisation and display of information for mass user events. Through the experiments in using and organising data in this way we demonstrate the value of “cartoblography”– a framework for mapping the spatial context of micro‐blogging.  相似文献   

Tetrachloroethene Release and Degradation During Combined ERH and Sodium Persulfate Oxidation          下载免费PDF全文

Tyler Marcet  Natalie L. Cápiro  Kurt D. Pennell 《Ground Water Monitoring & Remediation》2017,37(4):43-50

Electrical resistance heating (ERH) is a thermal treatment technology that involves passing electrical current through soil to increase subsurface temperatures. In addition to volatizing and recovering contaminant mass in the gas phase, heating the subsurface has the potential to decompose contaminants by increasing the rate of degradation reactions. Prior laboratory studies using convective heating demonstrated that the rate of tetrachloroethene (PCE) degradation was not sufficient to cause substantial in situ PCE mass destruction. However, similar experiments have not been performed using ERH, which has the potential to degrade PCE in reaction with the heating electrodes and electrochemically. Thus, the objective of this study was to determine the extent of PCE degradation during thermal treatment of PCE‐contaminated soil using a bench‐scale ERH system. The contaminated soil, a silty clay loam, was collected from a single borehole at a former dry cleaning facility prior to undergoing ERH treatment. After 30 days of ERH, 52% of the initial PCE mass was recovered, potentially indicating that 48% of the PCE was degraded during ERH. Although potential degradation products such as carbon dioxide were observed, their presence was attributed to the degradation of soil organic carbon and carbonates rather than PCE destruction. A second ERH experiment was conducted to assess the potential benefit of adding the heat‐activated oxidant, sodium‐persulfate, during treatment. After 19 days of ERH and three persulfate injections, 93% of the initial PCE was recovered, with 3% PCE destruction based on chloride evolution. However, the difference in mass recovery between the first and second experiments could have been due to differences in the initial mass of PCE, even though soil from the same core was used in both experiments. The results of this work suggest that the majority of mass recovered during ERH of the PCE‐contaminated soil at the former dry cleaning facility will be due to volatilization and gas phase extraction rather than abiotic degradation, even with the addition of sodium persulfate.  相似文献   

Insight into sediment transport processes on saline rangeland hillslopes using three‐dimensional soil microtopography changes          下载免费PDF全文

Sayjro K. Nouwakpo  Mark A. Weltz  Kenneth C. McGwire  Jason C. Williams  Al‐Hamdan Osama  Colleen H.M. Green 《地球表面变化过程与地形》2017,42(4):681-696

In arid and semi‐arid rangeland environments, an accurate understanding of runoff generation and sediment transport processes is key to developing effective management actions and addressing ecosystem response to changes. Yet, many primary processes (namely sheet and splash and concentrated flow erosion, as well as deposition) are still poorly understood due to a historic lack of measurement techniques capable of parsing total soil loss into these primary processes. Current knowledge gaps can be addressed by combining traditional erosion and runoff measurement techniques with image‐based three‐dimensional (3D) soil surface reconstructions. In this study, data (hydrology, erosion and high‐resolution surface microtopography changes) from rainfall simulation experiments on 24 plots in saline rangelands communities of the Upper Colorado River Basin were used to improve understanding on various sediment transport processes. A series of surface change metrics were developed to quantify and characterize various erosion and transport processes (e.g. plot‐wide versus concentrated flow detachment and deposition) and were related to hydrology and biotic and abiotic land surface characteristics. In general, erosivity controlled detachment and transport processes while factors modulating surface roughness such as vegetation controlled deposition. The extent of the channel network was a positive function of slope, discharge and vegetation. Vegetation may deflect runoff in many flow paths but promoted deposition. From a management perspective, this study suggests that effective runoff soil and salt load reduction strategies should aim to promote deposition of transported sediments rather than reducing detachment which might not be feasible in these resource‐limited environments. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

海陆风环流的计算方法   总被引：3，自引：0，他引：3  

张铭  张立凤  颜兆辉  杨纲凯 《大气科学》1999,23(6):693-702

给出海陆风环流的计算方法,得到了计算方程,该方程为一个复偏微分方程,可用松弛迭代法数值求解。利用该方程,对珠江口及香港地区的海陆风环流作了高分辨率的计算,结果表明用该方法计算得到的海陆风环流是可信的,其与实际观测及Mass模式的计算结果十分吻合。  相似文献   

A model for the evolution of CO2 on Mars     

Haberle RM  Tyler D  McKay CP  Davis WL 《Icarus》1994,109(1):102-120

We have constructed a model that predicts the evolution of CO2 on Mars from the end of the heavy bombardment period to the present. The model draws on published estimates of the main processes believed to affect the fate of CO2 during this period: chemical weathering, regolith uptake, polar cap formation, and atmospheric escape. Except for escape, the rate at which these processes act is controlled by surface temperatures which we calculate using a modified version of the Gierasch and Toon energy balance model (1973, J. Atmos. Sci. 30, 1502-1508). The modifications account for the change in solar luminosity with time, the greenhouse effect, and a polar and solar equatorial energy budget. Using published estimates for the main parameters, we find no evolutionary scenario in which CO2 is capable of producing a warm (global mean temperatures>250 K) and wet (surface pressures>30 mbar) early climate, and then evolves to present conditions with approximately 7 mbar in the atmosphere, <300 mbar in the regolith, and <5 mbar in the caps. Such scenarios would only exist if the early sun were brighter than standard solar models suggest, if greenhouse gases other than CO2 were present in the early atmosphere, or if the polar albedo were significantly lower than 0.75. However, these scenarios generally require the storage of large amounts of CO2 (>1 bar) in the carbonate reservoir. If the warm and wet early Mars constraint is relaxed, then we find best overall agreement with present day reservoirs for initial CO2 inventories of 0.5-1.0 bar. We also find that the polar caps can a profound effect on how the system evolves. If the initial amount of CO2 is less than some critical value, then there is not enough heating of the poles to prevent permanent caps from forming. Once formed, these caps control how the system evolves, because they set the surface pressure and, hence, the thermal environment. If the initial amount of CO2 is greater than this critical value, then caps do not form initially, but can form later on, when weathering and escape lower the surface pressure to a point at which polar heating is no longer sufficient to prevent cap formation and the collapse of the climate system. Our modeling suggests this critical initial amount of CO2 is between 1 and 2 bar, but its true value will depend on all factors affecting the polar heat budget.  相似文献   

Geophysical mapping of hyporheic processes controlled by sedimentary architecture within compound bar deposits     

Jeffery Tyler McGarr  Corey D. Wallace  Dimitrios Ntarlagiannis  Daniel M. Sturmer  Mohamad Reza Soltanian 《水文研究》2021,35(9):e14358

Hyporheic exchange influences water quality and controls numerous physical, chemical, and biological processes. Despite its importance, hyporheic exchange and the associated dynamics of solute mixing are often difficult to characterize due to spatial (e.g., sedimentary heterogeneity) and temporal (e.g., river stage fluctuation) variabilities. This study coupled geophysical techniques with physical and chemical sediment analyses to map sedimentary architecture and quantify its influence on hyporheic exchange dynamics within a compound bar deposit in a gravel-dominated river system in southwestern Ohio. Electromagnetic induction (EMI) was used to quantify variability in electrical conductivity within the compound bar. EMI informed locations of electrode placement for time-lapse electrical resistivity imaging (ERI) surveys, which were used to examine changes in electrical resistivity driven by hyporheic exchange. Both geophysical methods revealed a zone of high electrical conductivity in the center of the bar, identified as a fine-grained cross-bar channel fill. The zone acts as a baffle to flow, evidenced by stable electrical conditions measured by time-lapse ERI over the study period. Large changes in electrical resistivity throughout the survey period indicate preferential flowpaths through higher permeability sands and gravels. Grain size analyses confirmed sedimentological interpretations of geophysical data. Loss on ignition and x-ray fluorescence identified zones with higher organic matter content that are locations for potentially enhanced geochemical activity within the cross-bar channel fill. Differences in the physical and geochemical characteristics of cross-bar channel fills play an important role in hyporheic flow dynamics and nutrient processing within riverbed sediments. These findings enhance our understanding of the applications of geophysical methods in mapping riverbed heterogeneity and highlight the importance of accurately representing geomorphologic features and heterogeneity when studying hyporheic exchange processes.  相似文献   

F,Cl and S input via serpentinite in subduction zones: implications for the nature of the fluid released at depth     

Baptiste Debret  Kenneth T. Koga  Christian Nicollet  Muriel Andreani  Stéphane Schwartz 《地学学报》2014,26(2):96-101

The abundances of F, Cl and S in arc magmas are systematically higher than in other mantle‐derived magmas, suggesting that these elements are added from the slab along with H₂O. We present ion probe microanalyses of F, Cl and S in serpentine minerals that represent the P–T evolution of the oceanic lithosphere, from its serpentinization at the ridge, to its dehydration at around 100 km depth during subduction. F, Cl and S are incorporated early into serpentine during its formation at mid‐ocean ridges, and serpentinized lithosphere then carries these elements to subduction zones. More than 50% of the F, Cl and S are removed from serpentine during the prograde metamorphic lizardite/antigorite transition. Due to the low solubility of F in water, and to the low amount of water released during this phase transition, the fluids mobilizing these elements must be dominated by SO_X rather than H₂O.  相似文献   

Efficient hydrogeological characterization of remote stream corridors using drones     

Martin A. Briggs  Cian B. Dawson  Christopher L. Holmquist‐Johnson  Kenneth H. Williams  John W. Lane 《水文研究》2019,33(2):316-319

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Environmental Perception,Sense of Place,and Residence Time in the Okavango Delta,Botswana     

Amelia C. Eisenhart  Kelley A. Crews Meyer  Brian King  Kenneth R. Young 《The Professional geographer》2019,71(1):109-122

Integral to the geographic discipline are cross-cultural analyses, many of which use languages outside of the researcher’s own. There are few analyses, however, that address issues of translation that are inherently geographic; namely, that language is understood as a manifestation of place and culture. This article argues that the results of environmental interviews must be interpreted through a lens that evaluates how the translation of a word, or even a concept, is understood differentially based on one’s sense of place. Interviews were conducted in three of the Etsha villages situated in the Okavango Delta, Botswana, comparing perceptions of changes in both the local area and the flooding regime. Findings show qualitatively and quantitatively how residents perceive environmental change in light of their residential histories and their production of place. These results highlight that environmental change in an area is perceived in the context of previous residences, including the length of time spent in residence and the environmental characterization of that place. The process of interviewing regarding such change, especially when translation is necessary, should therefore proceed by incorporating inquiries about previous residences and the environments of those areas to correctly contextualize environmental change in a particular area.  相似文献