Chemical and structural relations of epitaxial xenotime and zircon substratum in sedimentary and hydrothermal environments: a TEM study     

Kerstin Drost  Richard Wirth  Jan Košler  Hege Fonneland Jørgensen  Theodoros Ntaflos 《Contributions to Mineralogy and Petrology》2013,165(4):737-756

Xenotime overgrowths on detrital zircon in siliciclastic sediments have been reported in numerous studies. However, in natural samples, solid solution of zircon and xenotime is limited to near-end-member compositions. In order to characterize the interface region between both minerals and to draw inferences on the growth mechanisms of authigenic xenotime, we studied xenotime overgrowths on detrital zircon grains from two Phanerozoic sandstone samples with contrasting post-depositional histories. In one sample, the small (≤10 μm), pyramidal xenotime overgrowths are of diagenetic origin and grew without major discontinuity on the detrital zircon grain. The second sample shows up to >50-μm-wide, porous and inclusion-rich, hydrothermal xenotime overgrowths on detrital zircon, whereas the transition zone between both minerals is accompanied by large pore volume. Chemical compositions of the xenotime precipitates from the two samples differ particularly in Y, REE, Th and Sc concentrations, whereas high MREE availability in the diagenetic sample and the presence of Sc in the hydrothermal sample, respectively, appear to have promoted xenotime growth. Transmission electron microscopy on electron-transparent foils cut from the interface region shows that both the diagenetic xenotime and the hydrothermal xenotime are crystalline and grew in optical and crystallographic continuity to their detrital zircon substrata. Only a narrow transition zone (≤90 nm—diagenetic sample, 200–300 nm—hydrothermal sample) between zircon and xenotime is in part made up of nanometre-scale crystalline domains that are slightly distorted and may have formed from dissolution–re-precipitation processes at the zircon rim along with precipitation from the respective fluid.  相似文献   

Geochemistry and geochronology of meta-igneous rocks from the Tokat Massif, north-central Turkey: implications for Tethyan reconstructions     

Elizabeth J. Catlos  Kathryn Huber  Timothy A. Shin 《International Journal of Earth Sciences》2013,102(8):2175-2198

Located in the eastern Pontides of the Sakarya Zone in north-central Turkey, the Tokat Massif records the closure of both the Paleo-Tethyan (Karakaya Complex) and Neo-Tethyan ocean basins. Meta-igneous samples collected from the region were studied to determine their sources and ages. We find significant geochemical differences between metagabbros of the Karakaya and Neo-Tethyan units in terms of their trace elements: Neo-Tethyan rocks are consistent with generation in an island arc setting, whereas Karakaya assemblages were likely generated in an oceanic spreading-center environment. Karakaya metagabbros also contain glaucophane, consistent with subduction subsequent to formation. Small (2–50 μm) zircon and baddeleyite grains from four Karakaya metagabbros were dated in thin section using an ion microprobe. The results demonstrate the reliability of the method to directly constrain the tectonomagmatic history of these types of assemblages. The rocks yield Late Permian/Early Triassic ²³⁸U/²⁰⁶Pb crystallization ages of 258 ± 14 Ma (±1σ, zircon) and 254 ± 8 Ma (±1σ, baddeleyite) and an Early Cretaceous minimum metamorphic age of 137 ± 8 Ma (±1σ, zircon). Some zircon grains and baddeleyite grains with zircon overgrowths yield Early to Middle Jurassic ages. Here we present a model in which metamorphism and deformation in this region occurred during northward subduction and closure of a Paleo-Tethyan ocean basin and accretion of the Karakaya units to the Laurasian continental margin. This was followed by the onset of closure of the Neo-Tethys during the Campanian-Paleocene and accretion of island arc units to the Tokat region.  相似文献   

Potential impact of climate change on aquatic insects: A sensitivity analysis for European caddisflies (Trichoptera) based on distribution patterns and ecological preferences   总被引：1，自引：1，他引：0  

Daniel Hering  Astrid Schmidt-Kloiber  John Murphy  Sofie Lücke  Carmen Zamora-Muñoz  Manuel Jesús López-Rodríguez  Thomas Huber  Wolfram Graf 《Aquatic Sciences - Research Across Boundaries》2009,71(1):3-14

  相似文献   

Node-centered finite volume discretizations for the numerical simulation of multiphase flow in heterogeneous porous media     

Ralf Huber  Rainer Helmig 《Computational Geosciences》2000,4(2):141-164

Three node-centered finite volume discretizations for multiphase porous media flow are presented and compared. By combination of these methods two additional discretization methods are generated. The ability of these schemes to describe flows at textural interfaces of different geologic formations is investigated. It was found that models with nonzero-entry pressures for the capillary pressure-saturation relationship in conjunction with the Box discretization may give rise to spurious oscillations for flows around low permeable lenses. Furthermore, the applicability and sensitivity of the discretization methods with regard to the used computational grids is discussed. The schemes are used for the numerical study of two-phase flow in porous media with zones of different material properties. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Climate sensitivity to changes in land surface characteristics     

Jacob O. Sewall  Lisa Cirbus Sloan  Matthew Huber  Scott Wing 《Global and Planetary Change》2000,26(4)

Using a recently developed global vegetation distribution, topography, and shorelines for the Early Eocene in conjunction with the Genesis version 2.0 climate model, we investigate the influences that these new boundary conditions have on global climate. Global mean climate changes little in response to the subtle changes we made; differences in mean annual and seasonal surface temperatures over northern and southern hemispheric land, respectively, are on the order of 0.5°C. In contrast, and perhaps more importantly, continental scale climate exhibits significant responses. Increased peak elevations and topographic detail result in larger amplitude planetary 4 mm/day and decreases by 7–9 mm/day in the proto Himalayan region. Surface temperatures change by up to 18°C as a direct result of elevation modifications. Increased leaf area index (LAI), as a result of altered vegetation distributions, reduces temperatures by up to 6°C. Decreasing the size of the Mississippi embayment decreases inland precipitation by 1–2 mm/day. These climate responses to increased accuracy in boundary conditions indicate that “improved” boundary conditions may play an important role in producing modeled paleoclimates that approach the proxy data more closely.  相似文献   

Long-term effects of a toxic algal bloom on subtidal soft-sediment macroinvertebrate communities in Wellington Harbour, New Zealand   总被引：3，自引：1，他引：2  

Kerstin Krger  Jonathan P.A. Gardner  Ashley A. Rowden  Robert G. Wear 《Estuarine, Coastal and Shelf Science》2006,67(4):589-604

The long-term effects (>1 year) of a naturally occurring toxic plankton bloom (Karenia brevisulcata) on subtidal benthic macroinvertebrate communities were investigated in Wellington Harbour, a semi-enclosed temperate embayment in New Zealand. For 3 years communities were sampled at three different sites in the harbour. Analyses revealed that community recovery following the bloom was site-specific. Multivariate analyses indicated that at one site community composition was approaching recovery 3 years post-bloom. At the second site, a sequential recovery process was indicated, whereas at the third site the community composition oscillated from year to year, but did not show any signs of a sequential recovery process. The nature of the hydrodynamic regime was identified as a major factor influencing the observed recovery processes. Communities exposed to an active hydrodynamic regime were less affected by the bloom and differed little in their composition pre- and post-bloom, as they were naturally in a perpetual state of recovery as indicated by a dominance of r-selected species. The community at the hydrodynamically less active site was more affected by the bloom and exhibited temporal differences in composition consistent with successional models. Complete recovery to a pre-disturbance climax community dominated by K-selected species is likely to take 4–5 years, if not interrupted by other disturbances. Given the increased occurrence of harmful algal blooms worldwide, more monitoring and manipulative studies are needed to further evaluate the effects of such disturbances on macrobenthic communities.  相似文献   

Multi-angle backscatter classification and sub-bottom profiling for improved seafloor characterization     

Evangelos Alevizos  Mirjam Snellen  Dick Simons  Kerstin Siemes  Jens Greinert 《Marine Geophysical Researches》2018,39(1-2):289-306

This study applies three classification methods exploiting the angular dependence of acoustic seafloor backscatter along with high resolution sub-bottom profiling for seafloor sediment characterization in the Eckernförde Bay, Baltic Sea Germany. This area is well suited for acoustic backscatter studies due to its shallowness, its smooth bathymetry and the presence of a wide range of sediment types. Backscatter data were acquired using a Seabeam1180 (180 kHz) multibeam echosounder and sub-bottom profiler data were recorded using a SES-2000 parametric sonar transmitting 6 and 12 kHz. The high density of seafloor soundings allowed extracting backscatter layers for five beam angles over a large part of the surveyed area. A Bayesian probability method was employed for sediment classification based on the backscatter variability at a single incidence angle, whereas Maximum Likelihood Classification (MLC) and Principal Components Analysis (PCA) were applied to the multi-angle layers. The Bayesian approach was used for identifying the optimum number of acoustic classes because cluster validation is carried out prior to class assignment and class outputs are ordinal categorical values. The method is based on the principle that backscatter values from a single incidence angle express a normal distribution for a particular sediment type. The resulting Bayesian classes were well correlated to median grain sizes and the percentage of coarse material. The MLC method uses angular response information from five layers of training areas extracted from the Bayesian classification map. The subsequent PCA analysis is based on the transformation of these five layers into two principal components that comprise most of the data variability. These principal components were clustered in five classes after running an external cluster validation test. In general both methods MLC and PCA, separated the various sediment types effectively, showing good agreement (kappa >0.7) with the Bayesian approach which also correlates well with ground truth data (r²?>?0.7). In addition, sub-bottom data were used in conjunction with the Bayesian classification results to characterize acoustic classes with respect to their geological and stratigraphic interpretation. The joined interpretation of seafloor and sub-seafloor data sets proved to be an efficient approach for a better understanding of seafloor backscatter patchiness and to discriminate acoustically similar classes in different geological/bathymetric settings.  相似文献   

Accretionary lapilli from the Sudbury impact event          下载免费PDF全文

Matthew S. Huber  Christian Koeberl 《Meteoritics & planetary science》2017,52(6):1257-1276

Meteorite impact‐generated accretionary lapilli are not well studied. The recently discovered distal ejecta from the 1850 Ma Sudbury impact event contain abundant accretionary lapilli generated during the impact and deposited at great distances from the crater. We petrographically and geochemically examined lapilli from five sites (McClure, Connors Creek, Hwy 588, Pine River, and Grand Trunk Pacific, approximately 480–750 km from the center of the Sudbury structure). The compositions of quartz, K‐feldspar, calcite, biotite, and chlorite minerals are similar to each other in all of the samples, although the relative proportions of the minerals vary from site to site. The lapilli occur in a matrix of coarse‐grained quartz, carbonate, and feldspar grains. Zonation within lapilli appears to be due to grain size distribution rather than compositional variation. The inner zones are coarser grained than outer zones. The relative abundances of calcite, phyllosilicates, and feldspars are similar in each zone within individual lapilli. A meteoritic component is indicated by up to 1.8 ppb Ir in one lapillus from the Pine River site, and Ni and Cr ratios are on a chondritic trend line for many of the lapilli. Mechanisms previously proposed for accretionary lapilli formation seem inadequate to explain deposition of distal accretionary lapilli resulting from impact events. A new mechanism for upper atmospheric accretion is proposed, whereby ash ejected from impact events concentrates at altitudes of neutral buoyancy, where it then accretes and is deposited later than ballistically emplaced particles. Likely, multiple processes are taking place in the chaotic postimpact environment.  相似文献   

Forest Beliefs in an Urbanizing World: Views on and Usage of Forest Areas Among Persons with and Without a Migration Biography in Germany and Sweden   总被引：1，自引：0，他引：1  

Annika Nordlund  Kerstin Westin 《社会与自然资源》2017,30(2):160-176

Previous studies have shown that environmental values of inhabitants of urban areas differ to some extent from those of people living in rural contexts. In the light of increasing urbanization, it is sometimes argued that these differences are becoming even greater, as people are becoming more and more alienated from nature. In the context of a larger survey study on beliefs about forests and forest management among the general public in Germany and Sweden, the influences of people’s migration biographies on their patterns of forest usage, their environmental concerns about forests, and the expectations and values they ascribe to forests are explored. While previous findings on differences between urban and rural populations are confirmed, we also find variation within these groups depending on their history of moving between the two spatial categories. This study thus adds a dynamic aspect to the discussion on the urban–rural perspective on beliefs about forests.  相似文献   

Über die Bestimmung von Aminopolycarbonsäuren durch Ionenpaarchromatographie     

W. Huber 《洁净——土壤、空气、水》1992,20(1):6-8

Determination of aminopolycarboxylic acids by ion pair chromatography. A method for the determination of aminopolycarboxylic acids, especially NTA and EDTA, is described, based on ion pair chromatography. The detection is done in UV at about 260 nm. The analytes are transformed into the Fe(III)-complexes before separation. For lower concentrations this can automatically be achieved by injecting the analyte into the Fe(III)-containing eluent. For higher concentrations, Fe(III) has to be added separately. Determination is possible down to 10 μg/1 concentration.  相似文献