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51.
New high-resolution spectra in the 0.33 to 0.92 μm range of Iapetus, Hyperion, Phoebe, Dione, Rhea, and three D-type asteroids were obtained on the Palomar 200-inch telescope and the double spectrograph. The spectra of Hyperion and the low-albedo hemisphere of Iapetus can both be closely matched by a simple model that is the linear admixture of the spectrum of a medium-sized, high-albedo icy saturnian satellite and D-type material. Our results support an exogenous origin to the dark material on Iapetus; furthermore, this material may share a common origin and a similar means of transport with material on the surface of Hyperion. The recently discovered retrograde satellites of Saturn (Gladman et al., Nature412, 163-166) may be the source of this material. The leading sides of Callisto and the Uranian satellites may be subjected to a similar alteration mechanism as that of Iapetus: accretion of low-albedo dust originating from outer retrograde satellites. Phoebe does not appear to be related to either Iapetus or Hyperion. Separate spectra of the two hemispheres of Phoebe show no identifiable global compositional differences.  相似文献   
52.
Optical and near-IR signatures of water ice on the Moon's surface were sought in the permanently shadowed regions near its poles. Significant amounts of multiply-scattered radiation partly illuminate primary shadows cast by craters and other features. If there is water ice in the permanently shadowed regions of the Moon's surface, its spectral signature should appear in this multiply-scattered light. This investigation can be done most effectively with observations obtained by spacecraft, because most selenocentric positions occupied by the Earth will also be occupied by the Sun at some point in time, and because the lunar poles are seen only obliquely to a terrestrial observer. Images obtained by Clementine are particularly well-suited to this task, because the spacecraft's polar orbit allowed images of the poles to be acquired on nearly every orbit, resulting in literally thousands of images taken within a few degrees of each pole, and because the filters on the ultraviolet-visual camera (UVVIS) and the near infrared camera (NIR) occur at major absorption bands or within important continuum features of water ice. Approximately 5800 images obtained by the UVVIS camera and 1800 images obtained by the NIR camera were calibrated and combined into coadded mosaics to create multispectral maps of the lunar poles with the highest possible signal-to-noise. Unfortunately, analysis of our UVVIS mosaics indicates that any possible signal from multiply-scattered light in primary shadows was overwhelmed by instrumental stray light. For the NIR camera, we were able to determine the normalized reflectance of several regions that were identified by Margot et al. (1999, Science284, 1658-1660) as permanent shadows. We have identified one permanently shadowed crater with a 1.5-μm band spectral signature indicative of between 2.5 and 21% fractional coverage of H2O frost. However, the same region shows a 2.0 μm spectral signature that is inconsistent with the presence of any water.  相似文献   
53.
Patterns of social interaction influence how knowledge is generated, communicated, and applied. Theories of social capital and organizational learning suggest that interactions within disciplinary or functional groups foster communication of knowledge, whereas interactions across groups foster generation of new knowledge. We used social network analysis to examine patterns of social interaction reported in survey data from scientists and managers who work on fish and fire issues. We found that few fish and fire scientists and managers interact with one another, suggesting low bridging social capital and thus, limited opportunity for generation of new knowledge. We also found that although interaction occurs among scientists—suggesting modest bonding social capital—few managers interact with other managers, indicating limited opportunity for communication of scientific knowledge for the purposes of application. We discuss constraints and opportunities for organizational learning evident in these patterns of social interaction among fish and fire scientists and managers.  相似文献   
54.
Urban forest management is being increasingly recognized as a viable policy vehicle for improving community health, sustainable development, and well-being for city dwellers. To improve our understanding of public concern for the local urban forest, a theoretical framework employing concepts traditionally explored in social–psychological and environmental concern studies was tested using data from a public opinion survey of 800 homeowners living in a major urban area in Southern Appalachia, USA. Publicly available geographic information system (GIS) data were analyzed to measure tree canopy density around survey respondents’ properties. Structural equation modeling was used to test the validity of the hypothesized relationships among the survey-derived constructs and the spatial data as predictors of public support for urban forest protection policy. The results suggest that homeowners living around urban trees place greater importance on various attributes of trees, and that tree knowledge and experience are indirectly and positively related to support for urban forest protection.  相似文献   
55.
The mechanism by which olivine grains became embedded within iron‐nickel alloy in pallasite meteorites continues to be a matter of scientific debate. Geochemical and textural observations have failed to fully elucidate the origin and history of the olivine crystals; however, little research attention has been devoted to their crystallographic orientations within the metal matrix. Using electron backscatter diffraction, we have collected crystallographic orientation data for 296 crystals within ~65 cm2 sample surface from Springwater. Though no global crystallographic preferred orientation exists, very low misorientations are observed among [100] axes of olivine crystals within specific texturally defined domains. Combined with a thorough characterization of large‐scale Springwater textures, the definitively nonrandom spatial distribution of olivine orientations provides clues regarding the nature of the olivine's initial formation environment as well as the sequence of events subsequent to metal incorporation.  相似文献   
56.
The efficacy of water quality policies aiming to reduce or prevent nitrate contamination of waterbodies may be constrained by the inherent delay or “time lag” of water and solute transport through unsaturated (soil) and saturated (groundwater) pathways. These delays must be quantified in order to establish realistic deadlines, thresholds and policy expectations, and to design effective best management practices. The objective of this review is to synthesise the current state of research on nitrate-related time lags in both the European and North American environmental and legislative contexts. The durations of time lags have been found to differ according to climatic, pedological, landscape and management scenarios. Elucidation of these driving factors at a watershed scale is essential where water quality is impaired or at risk. Finally, the existence of time lags is increasingly being acknowledged at a policy level and incorporated into the development of environmental legislation. However, the full impact of these time lags is not yet fully understood or appreciated, and continued outreach and education in scientific, public and policy venues is still required.  相似文献   
57.
Activity ratios (AR) of radium isotopes have been used with success to constrain estimates of water ages and to approximate residence times in coastal waters. We compared two common radium sampling methods (grab sampling and stationary moorings) to estimate water ages and the residence time of St. Andrew Bay waters in northwest Florida, USA. Both sampling methods utilize manganese dioxide fibers (“Mn fibers”) to adsorb dissolved radium from the water column. Grab samples capture radium activities at a discrete time while moorings integrate radium activities over longer deployments. The two methods yielded similar results in this study and thus both approaches are useful for water age comparisons and residence time approximations. However, since radium often varies as a function of tidal stage, deploying moorings over a complete tidal cycle is the preferred approach. An estimated residence time for North Bay and West Bay of 8–11 days was approximated using ARs for both ex224Ra/223Ra and ex224Ra/228Ra. Some complications were introduced as St. Andrew Bay is a tidally dominated, rather than a river-dominated bay system where this method has previously been applied. The largest freshwater source to this bay system is from a man-made reservoir, with an average freshwater flow of only 20 m3 s?1. The activity concentrations and ARs measured by both sampling methods suggest that while the reservoir is the prominent radium source, it is not the only radium source. Nonetheless, a tidal mixing model applied to the western half of the system yielded an approximate flushing time of 10–12 days, similar to that derived from our radium-based water age approach.  相似文献   
58.
We measured the effects of a plant invasion (Phragmites australis) on resident fish (Fundulus heteroclitus) in New England salt marshes by assessing diet quality at the food web base and by quantifying the importance of primary producers to secondary production using a recently developed Bayesian mixing model (Stable Isotope Analysis in R, “SIAR”). Spartina alterniflora, the dominant native plant, exhibited significantly greater leaf toughness and higher C/N ratios relative to P. australis. Benthic microalgae and phytoplankton (as suspended particulate matter) exhibited the lowest C/N indicating higher diet quality. We conducted a sensitivity analysis in SIAR by modeling F. heteroclitus at three separate trophic levels (1.5, 2.0, and 2.5) using species-specific discrimination factors to determine basal resource contributions. Overall, the best-fitting models include those that assume F. heteroclitus resides approximately 2.0 trophic levels above primary producers. Using discrimination factors from a range of data sources reported in the literature, our analyses revealed that consumers rely less on benthic microalgae and phytoplankton in restricted marshes (7–23 % and 11–44 %, respectively) relative to reference marshes (5–34 % and 23–48 %, respectively), resulting in a shift in diet toward invasive plant consumption (0–27 %). This is likely due to increased P. australis cover and marsh surface shading leading to decreased microalgal biomass, combined with reduced flooding of the marsh surface that favors terrestrial invertebrate assemblages. Restoration decreased the quantity of P. australis in the food web (0–15 %) and increased the importance of microalgae (1–30 %), phytoplankton (19–48 %), and native plants (23–63 %), indicating a shift in ecological recovery toward reference conditions.  相似文献   
59.
Ti valence measurements in MgAl2O4 spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti+4. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti+3‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti+4‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ25Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ25Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ25Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti+4 concentrations in spinel.  相似文献   
60.
Much work in recent years has reported on the role of submarine groundwater discharge (SGD) on coastal biogeochemistry, but most of those studies have focused on temperate or tropical climates where year-round rainfall recharges surficial aquifers. The aim of this work, however, was to examine SGD behaviors in an arid setting??Marina Lagoon on the Egyptian Mediterranean coast. SGD was estimated via radon surveys and time-series measurements in lagoon waters during two campaigns (wet season in March 2009 and dry season in July 2010). Relatively higher values of radon were detected in March (maximum >30?dpm/L) compared to July (up to 16?dpm/L), which would indicate either enhanced input rates, or lower mixing/atmospheric losses during the wet season. Lower salinity waters within Marina Lagoon were characterized by higher radon and higher concentrations of dissolved inorganic nitrogen (DIN) and silica (DISi), characteristic of groundwater inputs. Based on lagoon and groundwater radon measurements and an advection-diffusion model, SGD average rates between 0.83 to 2.4?×?108?L/day were estimated for both surveys. Since no seasonal pattern was detected, we suspect that either (1) SGD is derived from a regional aquifer not influenced by recharge from local rainfall or (2) local water use for irrigation and domestic purposes artificially recharges the surficial aquifer in the dry summer (tourist) months, which compensates for the lack of rainfall occurring at that time.  相似文献   
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