Common reed grass,<Emphasis Type="Italic">Phragmites australis</Emphasis>, expansion into constructed wetlands: Are we mortgaging our wetland future?     

Kirk?J.?HavensEmail author  Harry?Berquist  Walter?I.?Priest 《Estuaries and Coasts》2003,26(2):417-422

The use of constructed wetlands to replace natural wetlands has become a widespread management tool. Because of the inherent disturbed nature of these sites, constructed wetlands are susceptible to colonization by undesirable plant species. Vegetated communities in 15 constructed wetland sites ranging in age from 1 to 12 yr and in size from 0.4 to 5.3 ha were surveyed using differential global positioning system (GPS) technology in 1994. These sites were re-surveyed in 2000. Colonization of the sites byPhragmites australis expanded from 73% of the sites in 1994 to 80% of the sites in 2000. The total area colonized byP. australis within the sites increased from 3.47 to 4.96 ha. In some sites, the area ofP. australis decreased, which appears to be correlated with an increase in scrub-shrub vegetation (0.986, p=0.014). Similar to results from the previous study, sites that are surrounded by subtidal perimeter ditches have significantly lessP. australis than those sites without perimeter ditches (p=0.019).P. australis expansion rates within the sites varied from 0.1 to 5.6 yr^?1. Colonization of constructed wetland sites byP. australis should be a continued concern of resource managers. Activities such as planting scrub-shrub species on the upland-wetland berm and construction of subtidal perimeter ditches should be considered as methods to reduce the probability of invasion.  相似文献   

The Denali fault system and the tectonic development of Southern Alaska     

Robert G. Hickman  Campbell Craddock  Kirk W. Sherwood 《Tectonophysics》1978,47(3-4)

The Denali fault system forms an arc, convex to the north, across southern Alaska. In the central Alaska Range, the system consists of a northern Hines Creek strand and a southern McKinley strand, up to 30 km apart. The Hines Creek fault may preserve a record of the early history of the fault system. Strong contrasts between juxtaposed lower Paleozoic rocks appear to require large dextral strike-slip or a combination of dipslip and strike-slip displacements along this fault. Thus the fault system may mark a reactivated suture zone between continental rocks to the north and a late Paleozoic island arc to the south, as suggested by Richter and Jones (1973). Major movements on the Hines Creek fault ceased by the Late Cretaceous, but local dip-slip movements continued into the Cenozoic.The McKinley fault is an active dextral strike-slip fault with a mean Holocene displacement rate of 1–2 cm/y. Post-Late Cretaceous dextral offset on this fault is probably at least 30 km and possibly as great as 400 km. Patterns of early Tertiary folding and reverse faulting indicate that the McKinley fault was active at that time and suggest that this fault developed shortly after strike-slip activity ceased on the Hines Creek fault. Oligocene — middle Miocene tectonic stability and late Miocene—Pliocene uplift of crustal blocks may reflect periods of quiescence and activity, on the McKinley fault.The two strands of the Denali fault divide the central Alaska Range into northern, central, and southern terranes. During the Paleozoic—Mesozoic there is evidence for at least two episodes of compressive deformation in the northern terrane, four in the central terrane, and two in the southern. During each, the axis of maximum compressive strain was subhorizontal and about north—south. This pattern suggests a Paleozoic and Mesozoic setting dominated by plate convergence, despite the possible large pre-Late Cretaceous lateral movement on the Hines Creek fault.The Cenozoic pattern of faulting and folding appears compatible with a plate tectonic model of (1) rapid northward movement of the Pacific plate relative to Alaska during the early Tertiary; (2) slow northwestward movement of the Pacific plate during the Oligicene and (3) rapid northwestward movement of the Pacific plate from the end of the Oligocene to the present.  相似文献   

Thermochemical redox equilibria of ZoBell's solution     

Darrell Kirk Nordstrom 《Geochimica et cosmochimica acta》1977,41(12):1835-1841

The redox potential of ZoBell's solution, consisting of $\text{3.33 × 10}{}^{\mathrm{?3}}$ molar K₄Fe(CN)₆, $\text{3.33 × 10}{}^{\mathrm{?3}}$ molar K₃Fe(CN)₆ and 0.10 molar KCl, has been measured by a polished platinum electrode vs a saturated KCl, Ag/AgCl reference electrode. Measurements in the temperature range 8–85°C fit the equation $\text{E(}\text{volts}\text{) = 0.23145 ? 1.5220 × 10}{}^{\mathrm{?3}}\text{(t ? 25) ? 2.2449 × 10}{}^{\mathrm{?6}}\text{(t ? 25)}{}^2$ where $\text{t}$ is in degrees Celsius. Evaluation of literature data was necessary to obtain a reliable value for the Ag/AgCl half-cell reference potential as a function of temperature. Combining the measurements from this study with the literature evaluation of the Ag/AgCl reference potential yields the temperature dependent potential for ZoBell's solution: $\text{E(}\text{volts}\text{) = 0.43028 ? 2.5157 × 10}{}^{\mathrm{?3}}\text{(t ? 25) ? 3.7979 × 10}{}^{\mathrm{?6}}\text{(t ? 25)}{}^2$ relative to the standard hydrogen potential. From these data the enthalpy, entropy, free energy and heat capacity for the ferro-ferricyanide redox couple have been calculated. The temperature equation for the potential of ZoBell's solution may be used for checking potentiometric equipment in the determination of the redox potential of natural waters.  相似文献   

The effect of sulfate on aluminum concentrations in natural waters: some stability relations in the system Al₂O₃-SO₃-H₂O at 298 K     

Darrell Kirk Nordstrom 《Geochimica et cosmochimica acta》1982,46(4):681-692

While gibbsite and kaolinite solubilities usually regulate aluminum concentrations in natural waters, the presence of sulfate can dramatically alter these solubilities under acidic conditions, where other, less soluble minerals can control the aqueous geochemistry of aluminum. The likely candidates include alunogen, Al₂(SO₄)₃ · 17H₂O, alunite, KAl₃(SO₄)₂(OH)₆, jurbanite, Al(SO₄)(OH) · 5H₂O, and basaluminite, Al₄(SO₄)(OH)₁₀ · 5H₂O. An examination of literature values shows that the log $\text{K}{}_{\mathrm{sp}}\text{= ?85.4}$ for alunite and log $\text{K}{}_{\mathrm{sp}}\text{= ?117.7}$ for basaluminite. In this report the log $\text{K}{}_{\mathrm{sp}}\text{= ?7.0}$ is estimated for alunogen and log $\text{K}{}_{\mathrm{sp}}\text{= ?17.8}$ is estimated for jurbanite. The solubility and stability relations among these four minerals and gibbsite are plotted as a function of pH and sulfate activity at 298 K. Alunogen is stable only at pH values too low for any natural waters (<0) and probably only forms as efflorescences from capillary films. Jurbanite is stable from $\text{pH < 0}$ up to the range of 3–5 depending on sulfate activity. Alunite is stable at higher pH values than jurbanite, up to 4–7 depending on sulfate activity. Above these pH limits gibbsite is the most stable phase. Basaluminite, although kinetically favored to precipitate, is metastable for all values of pH and sulfate activity. These equilibrium calculations predict that both sulfate and aluminum can be immobilized in acid waters by the precipitation of aluminum hydroxysulfate minerals.Considerable evidence supports the conclusion that the formation of insoluble aluminum hydroxy-sulfate minerals may be the cause of sulfate retention in soils and sediments, as suggested by Adams and Rawajfih (1977), instead of adsorption.  相似文献   

Models of the world ocean     

Kirk Bryan 《Dynamics of Atmospheres and Oceans》1979,3(2-4)

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Viscosity profile of the lower mantle     

Kirk Ellsworth  Gerald Schubert  Charles G. Sammis 《Geophysical Journal International》1985,83(1):199-213

Summary. We determine the variation of effective viscosity η across the lower mantle from models of the Gibb's free energy of activation G * and the adiabatic temperature profile. The variation of G * with depth is calculated using both an elastic strain energy model, in which G * is related to the seismic velocities, and a model which assumes G * is proportional to the melting temperature. The melting temperature is assumed to follow Lindemann's equation. The adiabatic temperature profile is calculated from a model for the density dependence of the Grüneisen parameter. Estimates of η depend on whether the lower mantle is a Newtonian or power law fluid. In the latter case separate estimates of η are obtained for flow with constant stress, constant strain rate, and constant strain energy dissipation rate. For G * based on the melting temperature, increases in η with depth range from a factor of about 100 for Newtonian deformation or power-law flow with constant stress to about 5 for non-Newtonian deformation with constant strain rate. For G * based on elastic defect energy, increases in η with depth range from a factor of about 1500 for Newtonian deformation or power-law flow with constant stress to about 10 for non-Newtonian deformation with constant strain rate. Among these models, only a non-Newtonian lower mantle convecting with constant strain rate or constant strain energy dissipation rate is consistent with recent estimates of mantle viscosity from post-glacial rebound and true polar wander data.  相似文献   

Lacustrine shore platforms at Lake Waikaremoana,North Island,New Zealand     

Jonathan C. Allan  Wayne J. Stephenson  Robert M. Kirk  Anna Taylor 《地球表面变化过程与地形》2002,27(2):207-220

This paper examines the morphology and processes governing the development of shore platforms at Lake Waikaremoana, North Island, New Zealand. Shore platforms at Lake Waikaremoana are recent features, and were formed when a new sequence of shoreline development was initiated, due to lowering of the lake by 5 m in 1946 for hydroelectric power development. Three predominant platform morphologies were identified around the lake. These include gently sloping platforms (c.1·5 to 3·9°), ramp platforms (c.6·8 to 9·2°), and concave ramp platforms (c.7·9 to 12°). Platform widths ranged from 11 to 31 m, with the gently sloping platforms characterized by the widest morphologies. Erosion rates were estimated using perched sandstone boulders and were found to range from 3·4 to 12·5 mm a^?1, with a mean erosion rate of 5·9 mm a^?1. Higher rates of erosion were identified at lower platform elevations, due to a greater frequency of wetting and drying cycles coincident with storm waves, while lower erosion rates were identified at higher elevations. Field evidence suggests that shore platforms at Lake Waikaremoana were likely initiated and continue to develop as a result of subaerial wetting and drying cycles. Waves, coincident with fluctuating lake levels, play an important role by removing the weathered material from the platforms, and appear to control the width of the platforms. A conceptual model of platform development is presented, and analogies are drawn between this model, and the formation of shore platforms in oceanic environments. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Delineating compositional variabilities among crude oils from Central Montana, USA, using light hydrocarbon and biomarker characteristics     

Mark Obermajer  Kirk G Osadetz  Martin G Fowler  James Silliman  William B Hansen  M Clark 《Organic Geochemistry》2002,33(12)

Three compositionally distinctive groups of oils identified in central Montana by biomarker analyses are also recognized by the unique compositions of their light hydrocarbon (gasoline range) fraction. The majority of oils produced from Paleozoic pools (Pennsylvanian Tyler–Amsden interval) group into one broad category based on the distribution of C₂₀–C₄₀ biomarkers. These oils not only have the lowest Paraffin Indices and relative concentrations of normal heptane, but are readily distinguishable from the other compositional groups by using selected “Mango” parameters. However, the biomarker-based subdivision of this group into at least two sub-families is not reflected in the gasoline range fraction, suggesting little effect of source rock host lithology on the distribution of C₅–C₈ hydrocarbons. Oils occurring predominantly in Jurassic–Cretaceous reservoirs display different biomarker and gasoline range characteristics, including Paraffin Indices, K1 parameter and relative concentrations of C₇ compounds, and are classified in two separate compositional categories. In contrast to oils from the Tyler–Amsden interval, the oils produced from the Mesozoic strata are amongst the most mature oils in the study area. The unique biomarker/light hydrocarbon signatures are likely due to different source organic matter. Secondary alteration of oil due to biodegradation and migration, although recognized, appears less significant. The results indicate the overall usefulness of gasoline range compositions in delineating compositional affinities of crude oils in central Montana, clearly suggesting that the oils found in Paleozoic and Mesozoic reservoirs belong to different petroleum systems.  相似文献   

Dynamics of offshore structures by M. H. Patel,butterworths scientific,sevenoaks, Kent, 1989. no. of pages: approx. 400. price: £57.50. ISBN: 0-408-01704-6     

C. L. Kirk 《地震工程与结构动力学》1989,18(7):1087-1087

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Natural and anthropogenic radionuclide distributions in the northwest Atlantic Ocean   总被引：1，自引：0，他引：1  

J. Kirk Cochran  Hugh D. Livingston  David J. Hirschberg  Lolita D. Surprenant 《Earth and Planetary Science Letters》1987,84(2-3)

We have used in-situ pumps which filter large volumes of sea water through a 1 μm cartridge prefilter and two MnO₂-coated cartridges to obtain information on dissolved and particulate radionuclide distributions in the oceans. Two sites in the northwest Atlantic show subsurface maxima of the fallout radionuclides¹³⁷Cs,^239,240Pu and²⁴¹Am. Although the processes of scavenging onto sinking particles and release at depth may contribute to the tracer distributions, comparison of predicted and measured water column inventories suggests that at least 35–50% of the Pu and²⁴¹Am are supplied to the deep water by advection.The depth distributions of the naturally occurring radionuclides²³²Th,²²⁸Th and²³⁰Th reflect their sources to the oceans.²³²Th shows high dissolved concentrations in surface waters, presumably as a result of atmospheric or riverine supply. Activities of²³²Th decrease with depth to values 0.01 dpm/1000 l.²²⁸Th shows high activities in near surface and near bottom water, due to the distribution of its parent,²²⁸Ra. Dissolved²³⁰Th, produced throughout the water column from²³⁴U decay, increases with depth to 3000 m. Values in the deep water (> 3000 m) are nearly constant ( 0.6–0.7 dpm/1000 l), and the distribution of this tracer (and perhaps other long-lived particle-reactive tracers as well) may be affected by the advection inferred from Pu and²⁴¹Am data.The ratio of particulate to dissolved activity for both²³⁰Th and²²⁸Th is 0.15–0.20. This similarity precludes the calculation of sorption rate constants using a simple model of reversible sorption equilibrium. Moreover, in mid-depths²²⁸Th tends to have a higher particulate/dissolved ratio than²³⁰Th, suggesting uptake and release of²³⁰Th and²²⁸Th by different processes. This could occur if²²⁸Th, produced in surface water, were incorporated into biogenic particles formed there and released as those particles dissolved or decomposed during sinking.²³⁰Th, produced throughout the water column, may more closely approach a sorption equilibrium at all depths.²³⁰Th,²⁴¹Am and^239,240Pu are partitioned onto particles in the sequence Th > Am > Pu with 15% of the²³⁰Th on particles compared with 7% for Am and 1% for Pu. Distribution coefficients (K_d) are 1.3–1.6 × 10⁷ for Th, 5–6 × 10⁶ for Am and 7–10 × 10⁵ for Pu. The lower reactivity for Pu is consistent with analyses of Pu oxidation states which show 85% oxidized (V + VI) Pu. However, theK_d value for Pu may be an upper limit because Pu, like²²⁸Th, may be incorporated into particles in surface waters and released at depth only by destruction of the carrier phase.  相似文献