Saturn's icy satellites: Thermal and structural models     

Kirk Ellsworth  Gerald Schubert 《Icarus》1983,54(3):490-510

Thermal histories of the small icy Saturnian satellites Mimas, Tethys, Dione, Rhea, and Iapetus are constructed by assuming that they formed as homogeneous ice-silicate mixtures. The models include effects of radiogenic and accretional heating, conductive and subsolidus convective heat transfer, and lithospheric growth. Accretional heating is unlikely to have melted the water ice in the interiors of these bodies and solid state creep of the predominately ice material precludes melting by radiogenic heating. Mimas is so small that its thermal evolution is essentially purely conductive; at present it is a cold, nearly isothermal body. Any subsolidus convection or thermal activity in Mimas would have been confined to a brief period in its early history and would have been due to a warm formation. The four largest satellites are big enough and contain sufficient heat-producing silicates that solid state convection beneath a rigid lithosphere is inevitable independent of initial conditions. Dione and Rhea have convective interiors for most of their thermal histories, while Tethys and Iapetus have mainly conductive thermal histories with early periods of convective 0activity. The thermal histories of the five satellites for the last 4 by are independent of initial conditions; at present they have cold, conductive interiors. The model thermal histories are qualitatively consistent with the appearances of these satellites: Mimas has an ancient heavily cratered surface, Tethys and probably Iapetus have both heavily cratered and more lightly cratered areas, and Dione and Rhea have extensively modified surfaces. Because of their similar sizes and densities, Mimas and Enceladus are expected to have similar surfaces and thermal histories, but instead Enceladus has the most modified surface of all the small icy Saturnian satellites. Our results suggest a heat source for Enceladus, in addition to radiogenic and accretional heating; tidal dissipation is a possibility. Because the water ice in these bodies does not melt, resurfacing must be accomplished by the melting of a low-melting-temperature minor component such as ammonia hydrate.  相似文献   

GSFC optical ozonesonde results during the Gap,France, intercomparisons,June 1981     

Arlin J. Krueger  Peter Simeth  Carol A. Fry  Krishna Tewari 《Planetary and Space Science》1983,31(7):749-759

A GSFC Super Loki optical ozonesonde instrument was flown as part of the ozone sensor intercomparison balloon campaign at Gap, France, in June 1981. A primary objective was to confirm biases between external absorption techniques, such as the GSFC sonde, and in situ techniques, which include ECC, Mast-Brewer, and DASIBI sondes. Ozone distributions were obtained with the GSFC sonde on three of the four ascent-descent legs of the first flight on 19 June. Ozone densities were measured redundantly over altitudes from 22 to 32 km using filters centered at 303 and 300 nm. The three profiles obtained by averaging the data from the two channels are in close agreement with an average S.E. of 1.4%. However, small but consistent differences were found between the ozone densities measured at the two wavelengths. The average difference is 5% using Vigroux cross sections and 4% using preliminary Bass cross sections. The integral ozone amount above the first ceiling altitude of 32.85 km was determined by the Langley plot method to be 45 D.U. The total ozone derived by integrating the optical ozonesonde and ECC profiles is within 2% of the Chiran Dobson Spectrophotometer observation based on a pre-campaign calibration but is 9% greater than the amount derived using a post-campaign calibration.  相似文献   

Processes affecting transfer of sediment and colloids,with associated phosphorus,from intensively farmed grasslands: an overview of key issues     

P. M. Haygarth  G. S. Bilotta  R. Bol  R. E. Brazier  P. J. Butler  J. Freer  L. J. Gimbert  S. J. Granger  T. Krueger  C. J. A. Macleod  P. Naden  G. Old  J. N. Quinton  B. Smith  P. Worsfold 《水文研究》2006,20(20):4407-4413

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SCUBA polarization observations of the magnetic fields in the pre-stellar cores L1498 and L1517B     

J. M. Kirk  D. Ward-Thompson  R. M. Crutcher 《Monthly notices of the Royal Astronomical Society》2006,369(3):1445-1450

We have mapped linearly polarized dust emission from the pre-stellar cores L1498 and L1517B with the James Clerk Maxwell Telescope (JCMT) using the Submillimetre Common User Bolometer Array (SCUBA) and its polarimeter (SCUBAPOL) at a wavelength of 850 μm. We use these measurements to determine the plane-of-sky magnetic field orientation in the cores. In L1498, we see a magnetic field across the peak of the core that lies at an offset of ∼19°± 12° to the short axis of the core. This is similar to the offsets seen in previous observations of pre-stellar cores. To the south-east of the peak, in the filamentary tail of the core, we see that the magnetic field has rotated to lie almost parallel to the long axis of the filament. We hypothesize that the field in the core may have decoupled from the field in the filament that connects the core to the rest of the cloud. We use the Chandrasekhar–Fermi (CF) method to measure the plane-of-sky field strength in the core of L1498 to be ∼10 ± 7 μG.
In L1517B, we see a more gradual turn in the field direction from the northern part of the core to the south. This appears to follow a twist in the filament in which the core is buried, with the field staying at a roughly constant ∼25°± 6° offset to the short axis of the filament, consistent with previous observations of pre-stellar cores. Hence these two clouds in an apparently similar evolutionary state, that exhibit similar masses, morphologies and densities, have very different magnetic field configurations. We again use the CF method and calculate the magnetic field strength in L1517B to be ∼30 ± 10 μG. Both cores appear to be roughly virialized. Comparison with our previous work on somewhat denser cores shows that, for the denser cores, thermal and non-thermal (including magnetic) support are approximately equal, while for the lower density cores studied here, thermal support dominates.  相似文献   

International viewpoint and news     

Elisabeth Helen Krueger  Georg Teutsch 《Environmental Earth Sciences》2013,69(2):729-735

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Nature and Estimated Human Toxicity of Polar Metabolite Mixtures in Groundwater Quantified as TPHd/DRO at Biodegrading Fuel Release Sites     

Dawn A. Zemo  Kirk T. O'Reilly  Rachel E. Mohler  Asheesh K. Tiwary  Renae I. Magaw  Karen A. Synowiec 《Ground Water Monitoring & Remediation》2013,33(4):44-56

Polar metabolites resulting from petroleum biodegradation are measured in groundwater samples as TPHd unless a silica gel cleanup (SGC) is used on the sample extract to isolate hydrocarbons. Even though the metabolites can be the vast majority of the dissolved organics present in groundwater, SGC has been inconsistently applied because of regulatory concern about the nature and toxicity of the metabolites. A two‐step approach was used to identify polar compounds that were measured as TPHd in groundwater extracts at five sites with biodegrading fuel sources. First, gas chromatography with mass spectrometry (GC‐MS) was used to identify and quantify 57 individual target polar metabolites. Only one of these compounds—dodecanoic acid, which has low potential human toxicity—was detected. Second, nontargeted analysis was used to identify as many polar metabolites as possible using both GC‐MS and GC×GC‐MS. The nontargeted analysis revealed that the mixture of polar metabolites identified in groundwater source areas at these five sites is composed of approximately equal average percentages of organic acids, alcohols and ketones, with few phenols and aldehydes. The mixture identified in downgradient areas at these five sites is dominated by acids, with fewer alcohols, far fewer ketones, and very few aldehydes and phenols. A ranking system consistent with systems used by USEPA and the United Nations was developed for evaluating the potential chronic oral toxicity to humans of the different classes of identified polar metabolites. The vast majority of the identified polar metabolites have a “Low” toxicity profile, and the mixture of identified polar metabolites present in groundwater extracts at these five sites is unlikely to present a significant risk to human health.  相似文献   

Solute and geothermal flux monitoring using electrical conductivity in the Madison,Firehole, and Gibbon Rivers,Yellowstone National Park     

R. Blaine McCleskey  Laura E. Clor  Jacob B. Lowenstern  William C. Evans  D. Kirk Nordstrom  Henry Heasler  Mark A. Huebner 《Applied Geochemistry》2012

The thermal output from the Yellowstone magma chamber can be estimated from the Cl flux in the major rivers in Yellowstone National Park; and by utilizing continuous discharge and electrical conductivity measurements the Cl flux can be calculated. The relationship between electrical conductivity and concentrations of Cl and other geothermal solutes (Na, SO₄, F, HCO₃, SiO₂, K, Li, B, and As) was quantified at monitoring sites along the Madison, Gibbon, and Firehole Rivers, which receive discharge from some of the largest and most active geothermal areas in Yellowstone. Except for some trace elements, most solutes behave conservatively and the ratios between geothermal solute concentrations are constant in the Madison, Gibbon, and Firehole Rivers. Hence, dissolved concentrations of Cl, Na, SO₄, F, HCO₃, SiO₂, K, Li, Ca, B and As correlate well with conductivity (R² > 0.9 for most solutes) and most exhibit linear trends. The 2011 flux for Cl, SO₄, F and HCO₃ determined using automated conductivity sensors and discharge data from nearby USGS gaging stations is in good agreement with those of previous years (1983–1994 and 1997–2008) at each of the monitoring sites. Continuous conductivity monitoring provides a cost- and labor-effective alternative to existing protocols whereby flux is estimated through manual collection of numerous water samples and subsequent chemical analysis. Electrical conductivity data also yield insights into a variety of topics of research interest at Yellowstone and elsewhere: (1) Geyser eruptions are easily identified and the solute flux quantified with conductivity data. (2) Short-term heavy rain events can produce conductivity anomalies due to dissolution of efflorescent salts that are temporarily trapped in and around geyser basins during low-flow periods. During a major rain event in October 2010, 180,000 kg of additional solute was measured in the Madison River. (3) The output of thermal water from the Gibbon River appears to have increased by about 0.2%/a in recent years, while the output of thermal water for the Firehole River shows a decrease of about 10% from 1983 to 2011. Confirmation of these trends will require continuing Cl flux monitoring over the coming decades.  相似文献   

SCUBA and Spitzer observations of the Taurus molecular cloud – pulling the bull's tail     

D. Nutter  J. M. Kirk  D. Stamatellos  D. Ward-Thompson 《Monthly notices of the Royal Astronomical Society》2008,384(2):755-763

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Broad‐Scale Evidence That pH Influences the Balance Between Microbial Iron and Sulfate Reduction          下载免费PDF全文

Matthew F. Kirk  Qusheng Jin  Ben R. Haller 《Ground water》2016,54(3):406-413

Understanding basic controls on aquifer microbiology is essential to managing water resources and predicting impacts of future environmental change. Previous theoretical and laboratory studies indicate that pH can influence interactions between microorganisms that reduce ferric iron and sulfate. In this study, we test the environmental relevance of this relationship by examining broad‐scale geochemical data from anoxic zones of aquifers. We isolated data from the U.S. Geological Survey National Water Information System for 19 principal aquifer systems. We then removed samples with chemical compositions inconsistent with iron‐ and sulfate‐reducing environments and evaluated the relationships between pH and other geochemical parameters using Spearman's rho rank correlation tests. Overall, iron concentration and the iron‐sulfide concentration ratio of groundwater share a statistically significant negative correlation with pH (P < 0.0001). These relationships indicate that the significance of iron reduction relative to sulfate reduction tends to increase with decreasing pH. Moreover, thermodynamic calculations show that, as the pH of groundwater decreases, iron reduction becomes increasingly favorable relative to sulfate reduction. Hence, the relative significance of each microbial reaction may vary in response to thermodynamic controls on microbial activity. Our findings demonstrate that trends in groundwater geochemistry across different regional aquifer systems are consistent with pH as a control on interactions between microbial iron and sulfate reduction. Environmental changes that perturb groundwater pH can affect water quality by altering the balance between these microbial reactions.  相似文献   

Forecast of Natural Aquifer Discharge Using a Data‐Driven,Statistical Approach     

Kevin G. Boggs  Rob Van Kirk  Gary S. Johnson  Jerry P. Fairley 《Ground water》2014,52(6):853-863

In the Western United States, demand for water is often out of balance with limited water supplies. This has led to extensive water rights conflict and litigation. A tool that can reliably forecast natural aquifer discharge months ahead of peak water demand could help water practitioners and managers by providing advanced knowledge of potential water‐right mitigation requirements. The timing and magnitude of natural aquifer discharge from the Eastern Snake Plain Aquifer (ESPA) in southern Idaho is accurately forecast 4 months ahead of the peak water demand, which occurs annually in July. An ARIMA time‐series model with exogenous predictors (ARIMAX model) was used to develop the forecast. The ARIMAX model fit to a set of training data was assessed using Akaike's information criterion to select the optimal model that forecasts aquifer discharge, given the previous year's discharge and values of the predictor variables. Model performance was assessed by application of the model to a validation subset of data. The Nash‐Sutcliffe efficiency for model predictions made on the validation set was 0.57. The predictor variables used in our forecast represent the major recharge and discharge components of the ESPA water budget, including variables that reflect overall water supply and important aspects of water administration and management. Coefficients of variation on the regression coefficients for streamflow and irrigation diversions were all much less than 0.5, indicating that these variables are strong predictors. The model with the highest AIC weight included streamflow, two irrigation diversion variables, and storage.  相似文献