Barium Isotopic Compositions of Geological Reference Materials          下载免费PDF全文

Kirsten van Zuilen  Thomas F. Nägler  Thomas D. Bullen 《Geostandards and Geoanalytical Research》2016,40(4):543-558

The interest in variations of barium (Ba) stable isotope amount ratios in low and high temperature environments has increased over the past several years. Characterisation of Ba isotope ratios of widely available reference materials is now required to validate analytical procedures and to allow comparison of data obtained by different laboratories. We present new Ba isotope amount ratio data for twelve geological reference materials with silicate (AGV‐1, G‐2, BHVO‐1, QLO‐1, BIR‐1, JG‐1a, JB‐1a, JR‐1 and JA‐1), carbonate (IAEA‐CO‐9) and sulfate matrices (IAEA‐SO‐5 and IAEA‐SO‐6) relative to NIST SRM 3104a. In addition, two artificially fractionated in‐house reference materials BaBe12 and BaBe27 (δ^137/134Ba = ?1.161 ± 0.049‰ and ?0.616 ± 0.050‰, respectively) are used as quality control solutions for the negative δ‐range. Accuracy of our data was assessed by interlaboratory comparison between the University of Bern and the United States Geological Survey (USGS). Data were measured by MC‐ICP‐MS (Bern) and TIMS (USGS) using two different double spikes for mass bias correction (¹³⁰Ba–¹³⁵Ba and ¹³²Ba–¹³⁶Ba, respectively). MC‐ICP‐MS measurements were further tested for isobaric and non‐spectral matrix effects by a number of common matrix elements. The results are in excellent agreement and suggest data accuracy.  相似文献   

Nannofossils: the smoking gun for the Canarian hotspot          下载免费PDF全文

Valentin R. Troll  Frances M. Deegan  Steffi Burchardt  Kirsten Zaczek  Juan‐Carlos Carracedo  Fiona C. Meade  Vicente Soler  Mario Cachao  Jorge Ferreira  Abigail K. Barker 《Geology Today》2015,31(4):137-145

The origin of volcanism in the Canary Islands has been a matter of controversy for several decades. Discussions have hinged on whether the Canaries owe their origin to seafloor fractures associated with the Atlas Mountain range or to an underlying plume or hotspot of superheated mantle material. However, the debate has recently come to a conclusion following the discovery of nannofossils preserved in the products of the 2011–2012 submarine eruption at El Hierro, which tell us about the age and growth history of the western‐most island of the archipelago. Light coloured, pumice‐like ‘floating rocks’ were found on the sea surface during the first days of the eruption and have been shown to contain fragments of pre‐island sedimentary strata. These sedimentary rock fragments were picked up by ascending magma and transported to the surface during the eruption, and remarkably retained specimens of pre‐island Upper Cretaceous to Pliocene calcareous nannofossils (e.g. coccolithophores). These marine microorganisms are well known biostratigraphical markers and now provide crucial evidence that the westernmost and youngest island in the Canaries is underlain by the youngest sediment relative to the other islands in the archipelago. This finding supports an age progression for the onset of volcanism at the individual islands of the archipeligo. Importantly, as fracture‐related volcanism is known to produce non‐systematic age‐distributions within volcanic alignments, the now‐confirmed age progression corroberates to the relative motion of the African plate over an underlying mantle plume or hotspot as the cause for the present‐day Canary volcanism.  相似文献   

An intercontinental correlation of the mid-Neoproterozoic Eastern Indian tectonic zone: evidence from the gneissic clasts in Elan Bank conglomerate, Kerguelen Plateau     

Nilanjan Chatterjee  Kirsten Nicolaysen 《Contributions to Mineralogy and Petrology》2012,163(5):789-806

The Kerguelen Plateau is a submarine, Cretaceous Large Igneous Province in the southern Indian Ocean. Drilling on Elan Bank, a western salient of the Kerguelen Plateau, yielded a ~26 m section of fluvial conglomerate intercalated with basalt. Chemical dating of monazite within garnet and matrix monazite in metapelitic clasts from the conglomerate indicates that high-grade metamorphism of the pelitic protolith occurred between 785 ± 12 and 694 ± 18 Ma. A calculated P–T pseudosection indicates that the observed core-to-inner rim compositional zoning in garnet is consistent with P/T decrease from 10.2 kb/760°C to 6.2 kb/560°C. In an Early Cretaceous paleogeographic reconstruction, the Elan Bank drill site is located on a SSW continuation of the Eastern Indian Tectonic Zone (EITZ), a 876–784 Ma, NNE–SSW metamorphic belt with sinistral shear zones in eastern India. The retrograde P–T path of the Elan Bank metapelitic clast overlaps with that of the EITZ metapelite, and the Elan Bank monazite chemical dates and previously determined 824–675 Ma U–Pb isotope monazite dates by the TIMS method are remarkably similar to the monazite chemical dates from the EITZ metapelites and high-grade metamorphic rocks from the eastern margin of the Eastern Ghats Belt. Based on the demonstrable affinity of metamorphic, geochronologic, and spatial data, this study concludes that the EITZ was likely a continuous, ~1,800–km-long tectono-metamorphic belt in the Rodinia supercontinent stretching from eastern India through the Eastern Ghats to the basement of Elan Bank and probably to the Rayner Complex of East Antarctica.  相似文献   

A regional-scale climate reconstruction of the last 4000 years from lakes in the Nebraska Sand Hills,USA     

J. Schmieder  S.C. Fritz  J.B. Swinehart  A.L.C. Shinneman  A.P. Wolfe  G. Miller  N. Daniels  K.C. Jacobs  E.C. Grimm 《Quaternary Science Reviews》2011,30(13-14):1797-1812

High-resolution paleohydrological reconstructions were carried out in five shallow lakes in the Nebraska Sand Hills across an east–west transect in order to 1) determine whether long-term droughts of the past 4000 years were spatially and temporally coherent across the region, 2) distinguish local variation in climate or hydrology from regional patterns of change, and 3) compare the paleolimnological results with the existing dune-inferred drought records. Diatom-inferred lake-level was reconstructed for all sites and compared with other regional records. Alterations between high and low lake-levels were frequent during the past 4000 years, which suggests that shifts between dry and wet periods were prevalent across the Sand Hills. Extended multi-decadal to centennial-scale droughts were more common prior to 2000 years BP, while the last two millennia were hydrologically more variable and climate conditions alternated on shorter timescales. Despite some discrepancies among the five records, the paleohydrological reconstructions refine the Holocene drought history of the Nebraska Sand Hills, particularly between ～2200 and 4000 cal a BP. Many of the observed drought events are contemporaneous with severe droughts documented at sites in the northern Great Plains and Rocky Mountains, lending support for the severity and regional significance of these events in western North America.  相似文献   

Evaluation of a climate simulation in Europe based on the WRF–NOAH model system: precipitation in Germany     

Kirsten Warrach-Sagi  Thomas Schwitalla  Volker Wulfmeyer  Hans-Stefan Bauer 《Climate Dynamics》2013,41(3-4):755-774

The Weather Research and Forecast (WRF) model with its land surface model NOAH was set up and applied as regional climate model over Europe. It was forced with the latest ERA-interim reanalysis data from 1989 to 2008 and operated with 0.33° and 0.11° resolution. This study focuses on the verification of monthly and seasonal mean precipitation over Germany, where a high quality precipitation dataset of the German Weather Service is available. In particular, the precipitation is studied in the orographic terrain of southwestern Germany and the dry lowlands of northeastern Germany. In both regions precipitation data is very important for end users such as hydrologists and farmers. Both WRF simulations show a systematic positive precipitation bias not apparent in ERA-interim and an overestimation of wet day frequency. The downscaling experiment improved the annual cycle of the precipitation intensity, which is underestimated by ERA-interim. Normalized Taylor diagrams, i.e., those discarding the systematic bias by normalizing the quantities, demonstrate that downscaling with WRF provides a better spatial distribution than the ERA interim precipitation analyses in southwestern Germany and most of the whole of Germany but degrades the results for northeastern Germany. At the applied model resolution of 0.11°, WRF shows typical systematic errors of RCMs in orographic terrain such as the windward–lee effect. A convection permitting case study set up for summer 2007 improved the precipitation simulations with respect to the location of precipitation maxima in the mountainous regions and the spatial correlation of precipitation. This result indicates the high value of regional climate simulations on the convection-permitting scale.  相似文献   

Decomposition reactions of magnesium sulfate hydrates and phase equilibria in the MgSO₄-H₂O and Na-Mg-Cl-SO₄-H₂O systems with implications for Mars     

Michael Steiger  Kirsten Linnow  Dorothee Ehrhardt  Mandy Rohde 《Geochimica et cosmochimica acta》2011,75(12):3600-3626

We report new measurements of equilibrium relative humidities for stable and metastable hydration-dehydration equilibria involving several magnesium sulfates in the MgSO₄·nH₂O series. We also report a comprehensive thermodynamic treatment of the system including solution properties and experimental data from the published literature, i.e. solubilities, heat capacities and additional decomposition humidities. While for some magnesium sulfate hydrates solubility data in the binary system MgSO₄-H₂O are sparse, there is a reasonable database of solubility measurements of these hydrates in the ternary MgCl₂-MgSO₄-H₂O and the quaternary reciprocal Na⁺-Mg²⁺-Cl⁻-SO₄²⁻-H₂O systems. To make these data suitable for the determination of solubility products, we parameterized a Pitzer ion interaction model for the calculation of activity coefficients and water activities in mixed solutions of these systems and report the ion interaction parameters for the Na⁺-Mg²⁺-Cl⁻-SO₄²⁻-H₂O system. The model predicted solubilities in the reciprocal system are in very good agreement with experimental data. Using all available experimental data and the solution model an updated phase diagram of the MgSO₄-H₂O system covering the whole temperature range from about 170 to 473 K is established. This treatment includes MgSO₄·H₂O (kieserite), MgSO₄·4H₂O (starkeyite), MgSO₄·5H₂O (pentahydrite), MgSO₄·6H₂O (hexahydrite), MgSO₄·7H₂O (epsomite) and MgSO₄·11H₂O (meridianiite). It is shown that only kieserite, hexahydrite, epsomite and meridianiite show fields of stable existence while starkeyite and pentahydrite are always metastable. Due to sluggish kinetics of kieserite formation, however, there is a rather extended field of metastable existence of starkeyite which makes this solid a major product in dehydration reactions. The model predicted behavior of the magnesium sulfates is in excellent agreement with observations reported in the literature under terrestrial temperature and relative humidity conditions. We also discuss the implications of the new phase diagram for sulfates on Mars.  相似文献   

Tectono‐sedimentary Evolution of Early Pennsylvanian Alluvial Systems at the Onset of the Alleghanian Orogeny,Pocahontas Basin,Virginia     

R.P. Grimm  K. Eriksson  J. Carbaugh 《Basin Research》2013,25(4):450-470

Foreland basin strata provide an opportunity to review the depositional response of alluvial systems to unsteady tectonic load variations at convergent plate margins. The lower Breathitt Group of the Pocahontas Basin, a sub‐basin of the Central Appalachian Basin, in Virginia preserves an Early Pennsylvanian record of sedimentation during initial foreland basin subsidence of the Alleghanian orogeny. Utilizing fluvial facies distributions and long‐term stacking patterns within the context of an ancient, marginal‐marine foreland basin provides stratigraphic evidence to disentangle a recurring, low‐frequency residual tectonic signature from high‐frequency glacioeustatic events. Results from basin‐wide facies analysis, corroborated with petrography and detrital zircon geochronology, support a two end‐member depositional system of coexisting transverse and longitudinal alluvial systems infilling the foredeep during eustatic lowstands. Provenance data suggest that sediment was derived from low‐grade metamorphic Grenvillian‐Avalonian terranes and recycling of older Palaeozoic sedimentary rocks uplifted as part of the Alleghanian orogen and Archean‐Superior‐Province. Immature sediments, including lithic sandstone bodies, were deposited within a SE‐NW oriented transverse drainage system. Quartzarenites were deposited within a strike‐parallel NE‐SW oriented axial drainage, forming elongate belts along the western basin margin. These mature quartzarenites were deposited within a braided fluvial system that originated from a northerly cratonic source area. Integrating subsurface and sandstone provenance data indicates significant, repeated palaeogeographical shifts in alluvial facies distribution. Distinct wedges comprising composite sequences are bounded by successive shifts in alluvial facies and define three low‐frequency tectonic accommodation cycles. The proposed tectonic accommodation cycles provide an explanation for the recognized low‐frequency composite sequences, defining short‐term episodes of unsteady westward migration of the flexural Appalachian Basin and constrain the relative timing of deformation events during cratonward progression of the Alleghanian orogenic wedge.  相似文献   

Holocene variability in climate and oceanic conditions in the winter rainfall zone of South Africa—inferred from a high resolution diatom record from Verlorenvlei     

Kelly L. Kirsten  Thomas Kasper  Hayley C. Cawthra  Paul Strobel  Lynne J. Quick  Michael E. Meadows  Torsten Haberzettl 《第四纪科学杂志》2020,35(4):572-581

We present a diatom record from a well-dated 15.25 m composite sedimentary core from Verlorenvlei, a shallow coastal lake on the west coast of South Africa. We show that fluctuations in the diatom record occur in response to changes in sea level, ocean–atmosphere interactions and latitudinal shifts in the wind belts. During the early to mid-Holocene, the system primarily responds to sea level changes. A marine community that favours high nutrients is evident, particularly during 9200–8000, 7420–7000 and 6200–5600 cal a bp , corroborating periods of Benguela upwelling linked to fluctuations in the southeast trade winds. Increases in bioproductivity (%TOC, C/N) and fresher-water diatoms are associated with wetter conditions over the region and the northward migration of the southern westerly wind belt, most notably between 8000 and 7500 cal a bp and over the last 700 years. The latter trends are concomitant with changes in the extent of Antarctic sea ice and availability of moisture in southern South America. During the late Holocene, as sea levels stabilised to modern levels, climate variability is more strongly evident. The body of evidence further reveals the sensitivity of the region to high-latitude atmospheric mechanisms, but also showcases the significance of the southeast trade winds.  相似文献   

A high‐resolution record of Holocene climate and vegetation dynamics from the southern Cape coast of South Africa: pollen and microcharcoal evidence from Eilandvlei          下载免费PDF全文

Lynne J. Quick  Brian M. Chase  Michael Wündsch  Kelly L. Kirsten  Manuel Chevalier  Roland Mäusbacher  Michael E. Meadows  Torsten Haberzettl 《第四纪科学杂志》2018,33(5):487-500

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Additive toxicity of herbicide mixtures and comparative sensitivity of tropical benthic microalgae     

Marie Magnusson  Kirsten Heimann  Andrew P. Negri 《Marine pollution bulletin》2010,60(11):1978-1987

Natural waters often contain complex mixtures of unknown contaminants potentially posing a threat to marine communities through chemical interactions. Here, acute effects of the photosystem II-inhibiting herbicides diuron, tebuthiuron, atrazine, simazine, and hexazinone, herbicide breakdown products (desethyl-atrazine (DEA) and 3,4-dichloroaniline (3,4-DCA)) and binary mixtures, were investigated using three tropical benthic microalgae; Navicula sp. and Cylindrotheca closterium (Ochrophyta) and Nephroselmis pyriformis (Chlorophyta), and one standard test species, Phaeodactylum tricornutum (Ochrophyta), in a high-throughput Maxi-Imaging-PAM bioassay (Maxi-IPAM). The order of toxicity was; diuron > hexazinone > tebuthiuron > atrazine > simazine > DEA > 3,4-DCA for all species. The tropical green alga N. pyriformis was up to 10-fold more sensitive than the diatoms tested here and reported for coral symbionts, and is recommended as a standard tropical test species for future research. All binary mixtures exhibited additive toxicity, and the use of herbicide equivalents (HEq) is therefore recommended in order to incorporate total-maximum-load measures for environmental regulatory purposes.  相似文献