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991.

Relations between Tibetan Plateau precipitation and large-scale climate indices are studied based on the Standardized Precipitation Index (SPI) and the boreal summer season. The focus is on the decadal variability of links between the large-scale circulation and the plateau drought and wetness. Analysis of teleconnectivity of the continental northern hemisphere standardized summer precipitation reveals the Tibetan Plateau as a major SPI teleconnectivity center in south-eastern Asia connecting remote correlation patterns over Eurasia. Employing a moving window approach, changes in covariability and synchronizations between Tibetan Plateau summer SPI and climate indices are analyzed on decadal time scales. Decadal variability in the relationships between Tibetan Plateau summer SPI and the large-scale climate system is characterized by three shifts related to changes in the North Atlantic, the Indian Ocean, and the tropical Pacific. Changes in the North Atlantic variability (North Atlantic Oscillation) result in a stable level of Tibetan Plateau summer SPI variability; the response to changes in tropical Pacific variability is prominent in various indices such as Asian monsoon, Pacific/North America, and East Atlantic/Western Russia pattern.

  相似文献   
992.
EC-Earth is a newly developed global climate system model. Its core components are the Integrated Forecast System (IFS) of the European Centre for Medium Range Weather Forecasts (ECMWF) as the atmosphere component and the Nucleus for European Modelling of the Ocean (NEMO) developed by Institute Pierre Simon Laplace (IPSL) as the ocean component. Both components are used with a horizontal resolution of roughly one degree. In this paper we describe the performance of NEMO in the coupled system by comparing model output with ocean observations. We concentrate on the surface ocean and mass transports. It appears that in general the model has a cold and fresh bias, but a much too warm Southern Ocean. While sea ice concentration and extent have realistic values, the ice tends to be too thick along the Siberian coast. Transports through important straits have realistic values, but generally are at the lower end of the range of observational estimates. Exceptions are very narrow straits (Gibraltar, Bering) which are too wide due to the limited resolution. Consequently the modelled transports through them are too high. The strength of the Atlantic meridional overturning circulation is also at the lower end of observational estimates. The interannual variability of key variables and correlations between them are realistic in size and pattern. This is especially true for the variability of surface temperature in the tropical Pacific (El Ni?o). Overall the ocean component of EC-Earth performs well and helps making EC-Earth a reliable climate model.  相似文献   
993.
We determine the source parameters of three minor earthquakes in the Upper Rhine Graben (URG), a Cenozoic rift, using waveforms from permanent and temporary seismological stations. Two shallow thrust-faulting events (M L = 2.4 and 1.5) occurred on the rift shoulder just south of Heidelberg in March 2005. They indicate a possible movement along the sediment–crystalline interface due to tectonic loading from the near-by Odenwald. In February 2005, an earthquake with a normal-faulting mechanism occurred north of Speyer. This event (M L = 2.8) had an unusual depth of about 22 km and a similar deep normal-faulting event occurred there in 1972 (M L = 3.2). Other lower crustal events without fault plane solutions are known from 1981 and 1983. At such a depth, inside the lower crust, ductile behaviour instead of brittle faulting is commonly assumed and used for geodynamic modelling. Based on the newly available fault plane solutions we can confirm the brittle, extensional regime in the upper and lower crust in the central to northern URG indicated in earlier studies.  相似文献   
994.
The Jurassic (approximately 145 Ma) Nambija oxidized gold skarns are hosted by the Triassic volcanosedimentary Piuntza unit in the sub-Andean zone of southeastern Ecuador. The skarns consist dominantly of granditic garnet (Ad20–98) with subordinate pyroxene (Di46–92Hd17–42Jo0–19) and epidote and are spatially associated with porphyritic quartz-diorite to granodiorite intrusions. Endoskarn is developed at the intrusion margins and grades inwards into a potassic alteration zone. Exoskarn has an outer K- and Na-enriched zone in the volcanosedimentary unit. Gold mineralization is associated with the weakly developed retrograde alteration of the exoskarn and occurs mainly in sulfide-poor vugs and milky quartz veins and veinlets in association with hematite. Fluid inclusion data for the main part of the prograde stage indicate the coexistence of high-temperature (500°C to >600°C), high-salinity (up to 65 wt.% eq. NaCl), and moderate- to low-salinity aqueous-carbonic fluids interpreted to have been trapped at pressures around 100–120 MPa, corresponding to about 4-km depth. Lower-temperature (510–300°C) and moderate- to low-salinity (23–2 wt.% eq. NaCl) aqueous fluids are recorded in garnet and epidote of the end of the prograde stage. The microthermometric data (Th from 513°C to 318°C and salinity from 1.0 to 23 wt.% eq. NaCl) and δ18O values between 6.2‰ and 11.5‰ for gold-bearing milky quartz from the retrograde stage suggest that the ore-forming fluid was dominantly magmatic. Pressures during the early retrograde stage were in the range of 50–100 MPa, in line with the evidence for CO2 effervescence and probable local boiling. The dominance of magmatic low-saline to moderately saline oxidizing fluids during the retrograde stage is consistent with the depth of the skarn system, which could have delayed the ingression of external fluids until relatively low temperatures were reached. The resulting low water-to-rock ratios explain the weak retrograde alteration and the compositional variability of chlorite, essentially controlled by host rock compositions. Gold was precipitated at this stage as a result of cooling and pH increase related to CO2 effervescence, which both result in destabilization of gold-bearing chloride complexes. Significant ingression of external fluids took place after gold deposition only, as recorded by δ18O values of 0.4‰ to 6.2‰ for fluids depositing quartz (below 350°C) in sulfide-rich barren veins. Low-temperature (<300°C) meteoric fluids (δ18Owater between −10.0‰ and −2.0‰) are responsible for the precipitation of late comb quartz and calcite in cavities and veins and indicate mixing with cooler fluids of higher salinities (about 100°C and 25 wt.% eq. NaCl). The latter are similar to low-temperature fluids (202–74.5°C) with δ18O values of −0.5‰ to 3.1‰ and salinities in the range of 21.1 to 17.3 wt.% eq. CaCl2, trapped in calcite of late veins and interpreted as basinal brines. Nambija represents a deep equivalent of the oxidized gold skarn class, the presence of CO2 in the fluids being partly a consequence of the relatively deep setting at about 4-km depth. As in other Au-bearing skarn deposits, not only the prograde stage but also the gold-precipitating retrograde stage is dominated by fluids of magmatic origin.  相似文献   
995.
Fe isotopes are a potential tool for tracing the biogeochemical redox cycle of Fe in the ocean. Specifically, it is hypothesized that Fe isotopes could enable estimation of the contributions from multiple Fe sources to the dissolved Fe budget, an issue that has received much attention in recent years. The first priority however, is to understand any Fe isotope fractionation processes that may occur as Fe enters the ocean, resulting in modification of original source compositions. In this study, we have investigated the Fe inputs from a basalt-hosted, deep-sea hydrothermal system and the fractionation processes that occur as the hot, chemically reduced and acidic vent fluids mix with cold, oxygen-rich seawater.The samples collected were both end-member vent fluids taken from hydrothermal chimneys, and rising buoyant plume samples collected directly above the same vents at 5°S, Mid-Atlantic Ridge. Our analyzes of these samples reveal that, for the particulate Fe species within the buoyant plume, 25% of the Fe is precipitated as Fe-sulfides. The isotope fractionation caused by the formation of these Fe-sulfides is δFe(II)–FeS = +0.60 ± 0.12‰.The source isotope composition for the buoyant plume samples collected above the Red Lion vents is calculated to be −0.29 ± 0.05‰. This is identical to the value measured in end-member vent fluids collected from the underlying “Tannenbaum” chimney. The resulting isotope compositions of the Fe-sulfide and Fe-oxyhydroxide species in this buoyant plume are −0.89 ± 0.11‰ and −0.19 ± 0.09‰, respectively. From mass balance calculations, we have been able to calculate the isotope composition of the dissolved Fe fraction, and hypothesize that the isotope composition of any stabilised dissolved Fe species exported to the surrounding ocean may be heavier than the original vent fluid. Such species would be expected to travel some distance from areas of hydrothermal venting and, hence, contribute to not only the dissolved Fe budget of the deep-ocean but also it’s dissolved Fe isotope signature.  相似文献   
996.
The depleted mantle and the continental crust are generally thought to balance the budget of refractory and lithophile elements of the Bulk Silicate Earth (BSE), resulting in complementary trace element patterns. However, the two high field strength elements (HFSE) niobium and tantalum appear to contradict this mass balance. All reservoirs of the silicate Earth exhibit subchondritic Nb/Ta ratios, possibly as a result of Nb depletion.In this study a series of nineteen orogenic MORB-type eclogites from different localities was analyzed to determine their HFSE concentrations and to contribute to the question of whether subducted oceanic crust could form a hidden reservoir to account for the mass imbalance of Nb/Ta between BSE and the chondritic reservoir. Concentrations of HFSE were analyzed with isotope dilution (ID) techniques. Additionally, LA-ICPMS analyses of clinopyroxene, garnet and rutile have been performed. Rutile is by far the major host for Nb and Ta in all analyzed eclogites. However, many rutiles revealed zoning in Nb/Ta ratios, with cores being higher than rims. Accordingly, in situ analyses of rutiles have to be evaluated carefully and rutile cores do not necessarily reflect a bulk rock Nb and Ta composition, although over 90% of these elements reside in rutile.The HFSE concentration data in bulk rocks show that the orogenic eclogites have subchondritic Nb/Ta ratios and near chondritic Zr/Hf ratios. The investigated eclogites show neither enrichment of Nb compared to similarly incompatible elements (e.g. La), nor fractionation of Nb/Ta ratios relative to MOR-basalts, the likely precursor of these rocks. This indicates that during the conversion of the oceanic crust to eclogites in most cases, (1) HFSE and REE have similar mobility on average, possibly because both element groups remain in the down going slab, and (2) no significant fractionation of Nb/Ta occurs in subducted oceanic crust. With an average Nb/Ta ratio of 14.2 ± 1.4 (2s.e.), the investigated eclogites cannot balance the differences between BSE and chondrite. Additionally, as their average Nb/Ta is indistinguishable from the Nb/Ta of MORB, they are also an unlikely candidate to balance the potentially small differences in Nb/Ta between the continental crust and the mantle.  相似文献   
997.
Atmospheric radiocarbon variations over the Younger Dryas interval, from 13,000 to 11,600 cal yr BP, are of immense scientific interest because they reveal crucial information about the linkages between climate, ocean circulation and the carbon cycle. However, no direct and reliable atmospheric 14C records based on tree rings for the entire Younger Dryas have been available. In this paper, we present (1) high-precision 14C measurements on the extension of absolute tree-ring chronology from 12,400 to 12,560 cal yr BP and (2) high-precision, high-resolution atmospheric 14C record derived from a 617-yr-long tree-ring chronology of Huon pine from Tasmania, Australia, spanning the early Younger Dryas. The new tree-ring 14C records bridge the current gap in European tree-ring radiocarbon chronologies during the early Younger Dryas, linking the floating Lateglacial Pine record to the absolute tree-ring timescale. A continuous and reliable atmospheric 14C record for the past 14,000 cal yr BP including the Younger Dryas is now available. The new records indicate that the abrupt rise in atmospheric Δ14C associated with the Younger Dryas onset occurs at 12,760 cal yr BP, 240 yrs later than that recorded in Cariaco varves, with a smaller magnitude of 40‰ followed by several centennial Δ14C variations of 20–25‰. Comparing the tree-ring Δ14C to marine-derived Δ14C and modelled Δ14C based on ice-core 10Be fluxes, we conclude that changes in ocean circulation were mainly responsible for the Younger Dryas onset, while a combination of changes in ocean circulation and 14C production rate were responsible for atmospheric Δ14C variations for the remainder of the Younger Dryas.  相似文献   
998.
999.
1000.
地球化学与环境样品分析标准物质和GeoReM数据库   总被引:7,自引:5,他引:2  
在地球化学和环境样品分析中,标准物质发挥着越来越重要的作用。尽管通常要求分析者必须提供量值溯源的测量过程的信息;但大多数论著都未给出标准物质的数据。文章强调标准物质在地球化学分析工作中的重要性,同时将地球化学与环境样品分析标准物质数据库GeoReM介绍给中国的地质分析工作者。GeoReM数据库收录了1880个地球化学和环境样品分析标准物质的定值数据、汇编数据、分析数据及其他相关信息,其中包括156个由中国制备的标准物质的数据。GeoReM数据库还给出了所收录标准物质推荐使用的首选值及其不确定度。尽管这些首选值大多都不是按照国际标准化组织的有关规定而确定的,但是它们的置信度高,因而被广泛应用于仪器校准和分析数据的质量监控。文章还指出要将中国研制的、发表在中文期刊上的标准物质也收录到GeoReM数据库中,这对于促进中国的相关研究,增加国际认可度具有重要意义。  相似文献   
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