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11.
12.
Mineralogical and petrographic studies of a wide variety of refractory objects from the Murchison C2 chondrite have revealed for the first time melilite-rich and feldspathoid-bearing inclusions in this meteorite, but none of these is identical to any inclusion yet found in Allende. Blue spinel-hibonite spherules have textures indicating that they were once molten, and thus their SiO2-poor bulk composition requires that they were exposed to higher temperatures (>1550°C) than those deduced so far from any Allende inclusion. Melilite-rich inclusions are similar to Allende compact Type A's, but are more Al-, Ti-rich. One inclusion (MUCH-1) consists of a delicate radial aggregate of hibonite crystals surrounded by alteration products, and probably originated by direct condensation of hibonite from the solar nebular vapor. The sinuous, nodular and layered structures of another group of inclusions, spinel-pyroxene aggregates, suggest that these also originated by direct condensation from the solar nebular gas. Each type of inclusion is characterized by a different suite of alteration products and/or rim layers from all the other types, indicating modification of the inclusions in a wide range of different physico-chemical environments after their primary crystallization. All of these inclusions contain some iron-free rim phases. These could not have formed by reaction of the inclusions with fluids in the Murchison parent body because the latter would presumably have been very rich in oxidized iron. Other rim phases and alteration products could have formed at relatively low temperatures in the parent body, but some inclusions were not in the locations in which they were discovered when this took place. Some of these inclusions are too fragile to have been transported from one region to another in the parent body, indicating that low temperature alteration of these may have occurred in the solar nebula.  相似文献   
13.
From the mathematical analysis of the rare-earth data on some of the Apollo 12 samples studied by Hubbard et al. (1971), the possible europium-normal primitive rare-earth pattern, in which europium is normal with respect to the adjacent rare-earth elements, has been estimated. A fact that the igneous rocks (Japanese geosynclinal basalts) appearing to reflect the analogous effect occur locally on the earth enhances our interests in the pattern resulting from the above estimation.  相似文献   
14.
Two foliated metagabbros from the Mid-Atlantic Ridge near 30° N were analyzed for rare earth elements. The chondrite-normalized rare earth pattern for one of them is quite similar to those for abyssal tholeiites. The pattern for another sample, however, is somewhat different from the above one. A new set of bulk partition coefficients for rare earth elements has been estimated correspondingly. This set throws a new light on the interpretation that many alkali olivine basalts were produced by a zone melting or partial melting of primary-liquid-type material. Also the same partition coefficients lead us to an inference that the high-temperature peridotite intrusion in the Lizard area, Cornwall, England, is a secondary-solid-type material which was once in equilibrium with a primary-solid-type material, whereas the pyroxenite, Canyon Mountain, Oregon, is a primary-solid-type material.Both of the metagabbros studied show positive europium anomaly.  相似文献   
15.
The southern Irumide Belt (SIB) is an ENE–WSW-trending,late Mesoproterozoic orogenic belt located between the Congo–Tanzania–Bangweulu(CTB) and Kalahari cratons in central southern Africa. It isseparated from the late Mesoproterozoic Irumide Belt (IB) tothe north by Permo-Triassic graben, raising the possibilitythat the younger rifts reactivated a suture between the twobelts that has been rendered cryptic as a result of youngerKaroo cover. Both belts are dominated by calc-alkaline gneisses,but in addition the SIB contains abundant metavolcanic and metasedimentaryrocks. In this study we present detailed geochemical, isotopicand geochronological data for volcanic and plutonic lithologiesfrom the southernmost part of the SIB, the Chewore–RufunsaTerrane. This terrane comprises a wide variety of supracrustalto mid-crustal rocks that have major- and trace-element compositionssimilar to magmas formed in present-day subduction zones. Chondrite-normalizedrare earth element (REE) profiles and whole-rock Sm–Ndisotope compositions indicate that the parental supra-subductionmelts interacted with, and were contaminated by sialic continentalcrust, implying a continental-margin-arc setting. Secondaryionization mass spectrometry dating of magmatic zircon has yieldedcrystallization ages between c. 1095 and 1040 Ma, similar toelsewhere in the SIB. U–Pb dating and in situ Lu–Hfisotopic analyses of abundant xenocrystic zircon extracted fromthe late Mesoproterozoic granitoids indicate that the contaminantcontinental basement was principally Palaeoproterozoic in ageand had a juvenile isotopic signature at the time of its formation.These data are in contrast to those for the IB, which is characterizedby younger, c. 1020 Ma, calc-alkaline gneisses that formed bythe direct recycling of Archaean crust without significant additionof any juvenile material. We suggest that the SIB developedby the subduction of oceanic crust under the margin of an unnamedcontinental mass until ocean closure at c. 1040 Ma. Subsequentcollision between the SIB and the CTB margin led to the cessationof magmatism in the SIB and the initiation of compression andcrustal melting in the IB. KEY WORDS: geochemistry; Mesoproterozoic; SHRIMP zircon U–Pb dating; Sm–Nd isotopes; Southern Irumide Belt  相似文献   
16.
The Mikabu and Sorachi–Yezo belts comprise Jurassic ophiolitic complexes in Japan, where abundant basaltic to picritic rocks occur as lavas and hyaloclastite blocks. In the studied northern Hamamatsu and Dodaira areas of the Mikabu belt, these rocks are divided into two geochemical types, namely depleted (D-) and enriched (E-) types. In addition, highly enriched (HE-) type has been reported from other areas in literature. The D-type picrites contain highly magnesian relic olivine phenocrysts up to Fo93.5, and their Fo–NiO trend indicates fractional crystallization from a high-MgO primary magma. The MgO content is calculated as high as 25 wt%, indicating mantle melting at unusually high potential temperature (T p) up to 1,650 °C. The E-type rocks represent the enrichment in Fe and LREE and the depletion in Mg, Al and HREE relative to the D-type rocks. These chemical characteristics are in good accordance with those of melts from garnet pyroxenite melting. Volcanics in the Sorachi–Yezo belts can be divided into the same types as the Mikabu belt, and the D-type picrites with magnesian olivines also show lines of evidence for production from high T p mantle. Evidence for the high T p mantle and geochemical similarities with high-Mg picrites and komatiites from oceanic and continental large igneous provinces (LIPs) indicate that the Mikabu and Sorachi–Yezo belts are accreted oceanic LIPs that were formed from hot large mantle plumes in the Late Jurassic Pacific Ocean. The E- and D-type rocks were formed as magmas generated by garnet pyroxenite melting at an early stage of LIP magmatism and by depleted peridotite melting at the later stage, respectively. The Mikabu belt characteristically bears abundant ultramafic cumulates, which could have been formed by crystal accumulation from a primary magma generated from Fe-rich peridotite mantle source, and the HE-type magma were produced by low degrees partial melting of garnet pyroxenite source. They should have been formed later and in lower temperatures than the E- and D-type rocks. The Mikabu and Sorachi Plateaus were formed in a low-latitude region of the Late Jurassic Pacific Ocean possibly near a subduction zone, partially experienced high P/T metamorphism during subduction, and then uplifted in association with (or without, in case of Mikabu) the supra-subduction zone ophiolite. The Mikabu and Sorachi Plateaus may be the Late Jurassic oceanic LIPs that could have been formed in brotherhood with the Shatsky Rise.  相似文献   
17.
18.
<正>The podiform chromitites in the Luobusa ophiolite,Southern Tibet,have received much attention because of the presence of ultrahigh-pressure minerals,such as microdiamonds(Bai et al.,1993;Yang et al.,2007;Xu et al.,2009),coesite(Yang et al.,2007)and highly reduced metal phases(Bai et al.,2000;Robinson et al.,2004).The  相似文献   
19.
Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations.  相似文献   
20.
Exposure of the ca. 6 Ma Taitao ophiolite, Chile, located 50 km south of the Chile Triple Junction, allows detailed chemical and isotopic study of rocks that were recently extracted from the depleted mantle source of mid-ocean ridge basalts (DMM). Ultramafic and mafic rocks are examined for isotopic (Os, Sr, Nd, and O), and major and trace element compositions, including the highly siderophile elements (HSE). Taitao peridotites have compositions indicative of variable extents of partial melting and melt extraction. Low δ18O values for most whole rock samples suggest some open-system, high-temperature water–rock interaction, most likely during serpentinization, but relict olivine grains have δ18O values consistent with primary mantle values. Most of the peridotites analyzed for Nd–Sr isotopes have compositions consistent with estimates for the modern DMM, although several samples are characterized by 87Sr/86Sr and 143Nd/144Nd indicative of crustal contamination, most likely via interactions with seawater. The peridotites have initial 187Os/188Os ratios that range widely from 0.1168 to 0.1288 (γOs = −8.0 to +1.1), averaging 0.1239 (γOs = −2.4), which is comparable to the average for modern abyssal peridotites. A negative correlation between the Mg# of relict olivine grains and Os isotopic compositions of whole rock peridotites suggests that the Os isotopic compositions reflect primary mantle Re/Os fractionation produced by variable extents of partial melting at approximately 1.6 Ga. Recent re-melting at or near the spatially associated Chile Ridge further modified these rocks, and Re, and minor Pt and Pd were subsequently added back into some rocks by late-stage melt–rock or fluid–rock interactions.In contrast to the peridotites, approximately half of the mafic rocks examined have whole rock δ18O values within the range of mantle compositions, and their Nd and Sr isotopic compositions are all generally within the range of modern DMM. These rocks have initial 187Os/188Os ratios, calculated for 6 Ma, that range from 0.126 (γOs = −1) to as high as 0.561 (γOs = +342). The Os isotopic systematics of each of these rocks may reflect derivation from mixed lithologies that include the peridotites, but may also include pyroxenites with considerably more radiogenic Os than the peridotites. This observation supports the view that suprachondritic Os present in MORB derives from mixed mantle source lithologies, accounting for some of the worldwide dichotomy in 187Os/188Os between MORB and abyssal peridotites.The collective results of this study suggest that this >500 km3 block of the mantle underwent at least two stages of melting. The first stage occurred at 1.6 Ga, after which the block remained isolated and unmixed within the DMM. A final stage of melting recently occurred at or near the Chile Ridge, resulting in the production of at least some of the mafic rocks. Convective stirring of this mantle domain during a >1 Ga period was remarkably inefficient, at least with regard to Os isotopes.  相似文献   
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