Fine structures of mutually normalized rare-earth patterns of chondrites   总被引：2，自引：0，他引：2  

Akimasa Masuda  Noboru Nakamura  Tsuyoshi Tanaka 《Geochimica et cosmochimica acta》1973,37(2):239-248

REE abundances in ten chondrites (nine falls and one find) were determined very accurately by mass-spectrometric stable isotope dilution techniques. All of the chondrites have different relative and absolute REE patterns. Except for Eu and, rarely, for Ce, the REE abundances in chondrites are smoothly fractionated from sample to sample. Notwithstanding differences in the abundances of common REE, four of five L6 chondrites have very similar absolute Eu abundances; their mutually-normalized REE patterns are not curved, but are composed of two rectilinear segments.The Leedey-normalized REE pattern for St. Séverin (LL6) is composed of two concave curves. Yonozu's (H4,5) pattern shows negligibly concave curvature on both sides of Eu. Kesen's (H4) pattern is unusual in its overall pattern but also in irregularities for particular elements. The irregularity may be connected with the unusually high vapor pressure of metallic Yb. The REE pattern for the Allende bulk sample shows a discontinuity, presumably reflecting its considerable heterogeneity of composition and structure. It is evident that any pattern of ordinary chondrites cannot be produced from the Allende bulk pattern. A comparison is also made with the results on the chondrite composites previously investigated.  相似文献   

Metamorphic P-T conditions and variation of REE between two garnet generations from granulites in the Sør-Rondane mountains,East Antarctica     

Baba  Sotaro  Osanai  Yasuhito  Adachi  Tatsuro  Nakano  Nobuhiko  Hokada  Tomokazu  Toyoshima  Tsuyoshi 《Mineralogy and Petrology》2019,113(6):821-845

Mineralogy and Petrology - In this paper, we describe the metamorphic conditions of Fe-rich granulite and variations in rare earth elements (REE) between peak garnet porphyroblasts and secondary...  相似文献   

Indicator of paleosalinity: Sedimentary sulfur and organic carbon in the Jurassic–Cretaceous Tetori Group,central Japan     

Takashi Hasegawa  Tsuyoshi Hibino  Shunji Hori 《Island Arc》2010,19(4):590-604

A simple geochemical technique using the ratio of total sulfur (TS) to total organic carbon (TOC) was successfully used to reconstruct paleoenvironments in the Jurassic–Cretaceous Tetori Group, central Japan. The TS to TOC ratio is often employed as an effective parameter to separate modern marine or brackish sediments from freshwater deposits. To test the TS/TOC method for paleoenvironmental interpretation of the Tetori Group, we first analyzed TS/TOC for samples for which depositional conditions (i.e. marine, brackish or freshwater) had been recognized paleontologically. The results indicate that the method can effectively separate sedimentary rocks deposited under freshwater from marine and brackish settings. Once we had established the effectiveness of this method, we applied it to three sections of the Tetori Group, central Japan. Stratigraphic fluctuations in TS/TOC values revealed episodic incursions of marine or brackish conditions in the dominantly freshwater depositional sequence in the middle of the Jobu Formation of the Itoshiro Subgroup at the Izumi section, Fukui Prefecture. The same paleoenvironment is also suggested to occur at the top of the Tetori Group in the Tateyama section, Toyama Prefecture. This research provides important information to paleogeographers who currently lack evidence from facies fossils to indicate if the uppermost part of the Tetori Group represents marine or brackish settings. A chemostratigraphy of TS/TOC parameters potentially could provide a correlation among Jurassic–Cretaceous sequences along continental margins over East Asia.  相似文献   

Preliminary health risk assessment for polybrominated diphenyl ethers and polybrominated dibenzo-p-dioxins/furans in seafood from Guangzhou and Zhoushan, China     

Yuichi Miyake  Qinting Jiang  Wang Yuan  Nobuyasu Hanari  Tsuyoshi Okazawa  Barbara Wyrzykowska  Man Ka So  Paul K.S. Lam  Nobuyoshi Yamashita   《Marine pollution bulletin》2008,57(6-12):357

Dietary intake is one of the important routes of human exposure to brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs). The use of PBDEs may also result in exposure to polybrominated dibenzo-p-dioxins and dibenzofurans (PBDDs/DFs), as these compounds are impurities in technical mixtures of BFRs and can also be formed unintentionally by the same processes that generate chlorinated dioxins. This study determined the concentrations of polybrominated compounds in common seafood in Guangzhou and Zhoushan, and assessed the health risks of these chemicals via consumption of contaminated seafood. Seafood samples (fish, bivalves, shrimp, crab, and cephalopods) purchased from local markets in 2003 and 2004 were analyzed for PBDEs and PBDDs/DFs. The highest concentration of total PBDEs (46.3 ng g⁻¹ lipid wt.) was detected in fish from Guangzhou, in which BDEs 47 and 209 were the two predominant congeners. The total daily intakes of PBDEs, PBDDs, and PBDFs were, 946, 6.39, and 6.54 pg kg⁻¹ body weight (bw) in Guangzhou, and 489, 4.99, and 7.65 pg kg⁻¹ bw in Zhoushan, respectively. The hazard ratios for PBDDs and PBDFs were both greater than unity, indicating that these compounds may pose some health risks to the local population.  相似文献   

Chemostratigraphy of the Ediacaran basinal setting on the Yangtze platform,South China: Oceanographic and diagenetic aspects of the carbon isotopic depth gradient          下载免费PDF全文

Seishiro Furuyama  Akihiro Kano  Yoko Kunimitsu  Tsuyoshi Ishikawa  Wei Wang  Xin‐chun Liu 《Island Arc》2017,26(5)

The Ediacaran Yangtze platform in South China, which represents depositional settings ranging from coastal to basinal, provides valuable information for understanding climate changes and animal evolution during the Ediacaran Period. Although the shallower settings have been investigated, research on the basinal sections has been limited. This has hampered efforts to establish stratigraphic correlations and understand the oceanographic setting of the Yangtze platform. In this paper, the chemostratigraphy of a basinal section at Fengtan, Hunan Province, is reported based on analyses of stable carbon isotope profiles in carbonates (δ¹³C_carb), organic matter (δ¹³C_org), total organic carbon, ⁸⁷Sr/⁸⁶Sr ratios, and Mn, Rb, and Sr concentrations. The basinal section of the Doushantuo Formation, which is represented at Fengtan, provides data supporting regional correlations and oceanography. Three intervals in the Doushantuo Formation are correlated with the Three Gorges: (i) a negative δ¹³C_carb anomaly with stable δ¹³C_org values and altered ⁸⁷Sr/⁸⁶Sr ratios in the lower section can be correlated to the boundary between Doushantuo Members 2 and 3 (Interval A); (ii) a relatively high δ¹³C_carb anomaly with unaltered ⁸⁷Sr/⁸⁶Sr ratios (up to 0.7086) in the middle section corresponding to the lower part of Doushantuo Member 3 (Interval B); and (iii) a negative δ¹³C_carb anomaly with lowered δ values in the upper section can be correlated to the long interval of negative δ¹³C_carb (Interval C). The Gaskiers glaciation is likely represented in Interval A, and Interval C corresponds to the Shuram excursion reported for other Ediacaran localities. Our correlations confirm the depth gradient of δ¹³C_carb in the Yangtze platform and imply that reductive conditions prevailed in the basinal section from the Early to Middle Ediacaran. Under such conditions, anaerobic degradation of organic carbon or methane perturbed the inorganic carbon isotopic compositions and was at least partly responsible for the depth gradient of δ¹³C_carb.  相似文献   

Detectability analysis of interplate fault slips in the Nankai subduction thrust using seafloor observation instruments     

Agata  Ryoichiro  Hori  Takane  Ariyoshi  Keisuke  Ichimura  Tsuyoshi 《Marine Geophysical Researches》2019,40(4):453-466

To help the decision making regarding where to locate new observation instruments on the seafloor, we examined the detectability of interplate earthquakes and slow slips in the Nankai subduction thrust in Japan using seafloor observation instruments. Here, the detectability is defined as the smallest magnitude of the interplate fault slip detected by the assumed observation points based on crustal deformation simulation. In the detectability analyses, we considered the effect of sensor drifts that are particularly associated with seafloor observations. In addition, we introduced high-resolution three-dimensional (3D) finite element modeling of crustal deformation to consider the effect of the topography and 3D heterogeneous crustal structure around the Nankai Trough. The results of the detectability analyses show that introducing new seafloor stations for tilt observation in the Nankai region should increase the detectability of small- or medium-sized interplate earthquakes and slow slips significantly. Based on the obtained results, we also discuss the advantage of both the existing and the new observation instruments in detecting interplate fault slips.

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Nutrient transport from an artificial upwelling of deep sea water     

Nicholas Williamson  Atsuki Komiya  Shigenao Maruyama  Masud Behnia  Steve W. Armfield 《Journal of Oceanography》2009,65(3):349-359

The transport of nutrient-rich, deep sea water from an artificial upwelling pipe has been simulated. A numerical model has been built within a commercial Computational Fluid Dynamics (CFD) package. The model considers the flow of the deep sea water after it is ejected from the pipe outlet in a negatively buoyant plume (densimetric Froude number = −2.6), within a stably stratified ocean environment subject to strong ocean current cross flow. Two cross-flow profiles were tested with momentum flux ratios equal to 0.92 and 3.7. The standard k-ε turbulence model has been employed and a range of turbulent Schmidt and Prandtl numbers tested. In all cases the results show that the rapid diffusion of heat and salinity at the pipe outlet causes the plume to attain neutral buoyancy very rapidly, preventing strong fountain-like behavior. At the higher momentum flux ratio fountain-like behavior is more pronounced close to the pipe outlet. The strong cross-current makes horizontal advection the dominant transport process downstream. The nutrient plume trajectory remains largely within one relatively thin stratified layer, making any ocean cross-flow profile less important. Very little unsteady behavior was observed. The results show that the nutrient is reduced to less than 2% of its inlet concentration 10 meters downstream of the inlet and this result is largely independent of turbulent Prandtl or Schmidt number. Initial results would suggest that if such an artificial upwelling were to be viable for an ocean farming project, a large number of upwelling pipes would be necessary. Further work will have to determine the minimum nutrient concentration required to sustain a viable phytoplankton population and the required spacing between upwelling pipes.  相似文献   

Improved description of global mixed-layer depth using Argo profiling floats     

Shigeki Hosoda  Tsuyoshi Ohira  Kanako Sato  Toshio Suga 《Journal of Oceanography》2010,66(6):773-787

A global data set describing the gridded mixed-layer depth (MLD) in 10-day intervals was produced using high-quality Argo float data from 2001 to 2009. The characteristics and advantages provided by the new MLD data set are described here, including a comparison based on two different thresholds and using data sets of different vertical and temporal resolution. The MLD in the data set was estimated on the basis of a shallower depth of the iso-thermal layer (TLD) or iso-pycnal layer (PLD), calculated using the finite difference method. The MLD data are incorporated into 2° × 2° grid in the global ocean, including marginal seas. Also, two threshold values were used to examine differences in the MLD and its seasonal temporal variability. The characteristics and advantages of using the Argo 10-day intervals to determine the MLD were then confirmed by comparing those data with the station buoy daily means and the Argo monthly means. With respect to vertical and temporal resolutions, the Argo 10-day data has two distinct advantages: (1) improved representation of the MLD vertical change due to high vertical resolution, especially during periods of large MLD variability and (2) more detailed representation of the temporal change in MLD than achieved with the Argo monthly mean data, especially from winter to spring in mid and high latitudes. These advantages were maintained in the case of a larger threshold despite the fact that the MLD is rather deep and the detailed variation in its distribution differs depending on the season and location. This study also investigated the relative influence of TLD and PLD to the MLD calculation for each grid. Generally, the MLD is primarily determined based on the PLD at low and mid latitudes (TLD > PLD), whereas the TLD is more important at high latitudes, especially in winter (TLD < PLD). In the case of a larger threshold, the area of the larger PLD influence spreads polewards because of the greater effect of salinity in winter. Although there are some differences in the effect of temperature and salinity in estimations of the MLD, both are indispensable factors for the MLD estimations even at different thresholds.  相似文献   

Polycyclic aromatic hydrocarbons in the Jurassic–Cretaceous Tetori Group,central Japan     

Takashi Hasegawa  Tsuyoshi Hibino 《Island Arc》2011,20(1):23-34

Primary data on the organic geochemistry of the Tetori Group provide basic information about depositional environments and thermal maturation of organic matter through two geological sections in the Hokuriku region, central Japan. The thermal maturity of organic matter was evaluated by the methylphenanthrene index‐1. The maturity progressively increases stratigraphically down through the Izumi section in Fukui Prefecture. The estimated vitrinite reflectance equivalent is <1.35% near the top of the section, gradually increasing to >2.0% near the base. The thermal maturation process can account for stratigraphic changes in abundance of PAHs through this section. However, the occasional occurrence of coronene in the middle of the Izumi section is attributed to possible paleo‐wildfires that supplied more coronene to the depositional site. The stratigraphic distribution of PAHs through the Tateyama section, Toyama Prefecture, also can be explained by the same scenario as envisaged for the Izumi section, but weathering and/or other secondary factors may have partly modified primary signals for this section. Polycyclic aromatic sulfur compounds were observed in nearly all samples from both sections, even in samples for which a freshwater paleoenvironment is surmised. Most plausibly, some reduced sulfur was re‐oxidized to elemental sulfur, which persisted in the sediments and may have contributed to the formation of aromatic sulfur compounds. Hence, polycyclic aromatic sulfur compounds do not provide an index to separate marine environments from the freshwater settings for the Tetori Group.  相似文献   

Fluids’ dynamics in transient air sparging of a heterogeneous unconfined aquifer     

Rashid S. Al-Maamari  Akihiko Hirayama  Tsuyoshi Shiga  Mark N. Sueyoshi  Mahfoodh Al-Shuely  Osman A. E. Abdalla  Anvar R. Kacimov 《Environmental Earth Sciences》2011,63(6):1189-1198

Water table dynamics, dissolved oxygen (DO) content, electrical resistivity (ER) in monitoring wells and air pressure in the vadose zone are monitored in air sparging (AS) accompanied by soil vapor extraction (SVE) at a hydrocarbon-contaminated groundwater site in Oman, where a diesel spillover affected a heterogeneous unconfined aquifer. The formation of a groundwater mound at the early stage of air injection and potential lateral migration of contaminants from the mound apex called for an additional hydrodynamic barrier constructed as a pair of pump-and-treat (P&T) wells whose recirculation zone encompassed the AS and SVE wells. In all monitored piezometers the phreatic surface showed a rapid and distinct peak, which is attributed to the time of air breakthrough from the injection point to the vadose zone and a relatively mild recession limb interpreted as a decay of the mound. Tracer tests showed a layer of a relatively low hydraulic conductivity at an intermediate depth of the screened interval of the wells. Increased levels of DO and borehole air pressure that have been observed (as far as 50 m away) are likely mitigated by SVE and P&T. Radius of influence can be indirectly inferred from ER and DO changes in the AS operation zone. Salt tracer tests have shown that groundwater velocity within the AS zone decreases with the increase of air injection rate.  相似文献