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121.
122.
Some recent developments made during the European Union 6th Framework Integrated Project FUNMIG in the understanding and prediction of behaviour in ternary systems of radionuclides, humic substances and mineral surfaces are described. These developments are placed in the context of the existing literature. The aim is to describe the current understanding of humic substance mediated radionuclide transport as it may be applied to calculations in support of Radiological Performance Assessment. Some improvements in experimental techniques that provide the raw data to calibrate metal ion binding models are explained. The various metal ion binding models that are available are described and contrasted, before the recent development of ternary system models, in particular the Ligand Charge Distribution model that can predict metal ion and humic substance behaviour in ternary systems. The kinetic effects in ternary systems are described along with the models that are used to describe them. Finally, the remaining challenges in making predictions of radionuclide transport for the Radiological Performance Assessment of radioactive waste repositories are discussed.  相似文献   
123.
The age of the Ashburton Province, comprising an older divergent‐margin megasequence and a younger convergent‐margin megasequence, is poorly constrained. The Boolaloo Granodiorite, which intruded the divergent‐margin megasequence on the western margin of the Ashburton Province, has given a SHRIMP zircon U–Pb age of 1786 ± 5 Ma, and therefore post‐dates convergent‐margin, backarc basin sequences, with established conventional zircon U7sbnd;Pb ages of ca 1843–1828 Ma. However, it pre‐dated deformation of convergent‐margin, remnant‐ocean sequences. Similarly aged (ca 1797–1791 Ma) granitoids are present in the adjacent Gascoyne Province, thereby identifying a magmatic fold‐thrust belt that abutted a remnant ocean in the Ashburton Province.  相似文献   
124.
The Middle Shoalhaven Plain is a large, tray‐like depression bounded in the west by the Mulwaree fault and in the east by cliffed Permian sediments. The plain is probably Mesozoic in origin and was partially alluviated during the Early to mid‐Eocene. Much of the plain and sediments were covered by basalts during the Late Eocene. This was followed by an episode of deep weathering, which culminated in the formation of widespread bauxitic and lateritic crusts and manganocrete and silcrete during the mid‐Tertiary. A second minor weathering event is recorded during the latest Tertiary to Early Pleistocene. Two new basalt dates are consistent with earlier ones at about 43 Ma. Palaeomagnetism shows bauxites and ferricretes to be mid‐Tertiary.  相似文献   
125.
Abstract

The Devonian subsurface Adavale Basin occupies a central position in the Paleozoic central Thomson Orogen of eastern Australia and records its tectonic setting during this time interval. Here, we have focussed on the basal volcanics of the Gumbardo Formation to clarify the tectonic setting of the basin. The approach has been to undertake stratigraphic logging, LA-ICP-MS U–Pb zircon geochronology and whole-rock geochemical analysis. The data indicate that basin initiation was rapid occurring at ca 401?Ma. The volcanic rocks are dominated by K-feldspar phyric rhyodacitic ignimbrites. The whole-rock geochemical data indicate little evidence for extensive fractional crystallisation, with the volcanic suite resembling the composition of the upper continental crust and exhibiting transitional I- to A-type tectonomagmatic affinities. One new U–Pb zircon age revealed an Early Ordovician emplacement age for a volcanic rock previously interpreted to be part of the Early Devonian Gumbardo Formation, and older basement age is consistent with seismic interpretations of uplifted basement in this region of the western Adavale Basin. Five ignimbrites dated from different stratigraphic levels within the formation yield similar emplacement ages with a pooled weighted age of 398.2?±?1.9?Ma (mean square weighted deviation?=?0.94, n?=?93). Significant zircon inheritance in the volcanic rocks records reworking of Ordovician and Silurian silicic igneous basement from the Thomson Orogen and provides insight into the crustal make-up of the Thomson Orogen. Collectively, the new data presented here suggest the Adavale Basin is a cover-type basin that developed on a stabilised Thomson Orogen after the major Bindian deformation event in the late Silurian.  相似文献   
126.
In the western United States, more than 79 000 km2 has been converted to irrigated agriculture and urban areas. These changes have the potential to alter surface temperature by modifying the energy budget at the land–atmosphere interface. This study reports the seasonally varying temperature responses of four regional climate models (RCMs) – RSM, RegCM3, MM5-CLM3, and DRCM – to conversion of potential natural vegetation to modern land-cover and land-use over a 1-year period. Three of the RCMs supplemented soil moisture, producing large decreases in the August mean (− 1.4 to − 3.1 °C) and maximum (− 2.9 to − 6.1 °C) 2-m air temperatures where natural vegetation was converted to irrigated agriculture. Conversion to irrigated agriculture also resulted in large increases in relative humidity (9% to 36% absolute change). Modeled changes in the August minimum 2-m air temperature were not as pronounced or consistent across the models. Converting natural vegetation to urban land-cover produced less pronounced temperature effects in all models, with the magnitude of the effect dependent upon the preexisting vegetation type and urban parameterizations. Overall, the RCM results indicate that the temperature impacts of land-use change are most pronounced during the summer months, when surface heating is strongest and differences in surface soil moisture between irrigated land and natural vegetation are largest.  相似文献   
127.
A small‐scale experiment was done to test the feasibility of thermally marking hatchery‐reared rainbow trout (Oncorhynchus mykiss Walbaum) fry that are released into rivers and impoundments in New South Wales (NSW), Australia. Fry of rainbow trout were exposed to two different 48‐h thermal cycles each of a cold and warm water period. One thermal regime consisted of a cold water period during which the temperature was reduced from 14 to 8°C for 18 h followed by a return to 14°C for 30 h. For the second thermal treatment, water temperature was reduced to 4°C for 10 h followed by a period of 38 h at 14°C. Thermal cycles were repeated 4 and 8 times for each thermal regime, respectively. Following a growth period after treatment, obvious marks were visible on all treated otoliths as distinct from control otoliths. The 10°C differential treatment created the most visible patterns and growth of these fish was not significantly different from control fish. This marking method could be applied to normal hatchery practices to evaluate the effectiveness of large‐scale rainbow trout stockings in NSW.  相似文献   
128.
This paper investigates the behavior of katabatic flow induced by an idealized, thermally inhomogeneous surface; a strip of surface cooling that has a finite width in the along-slope direction and is infinitely long in the cross-slope direction. Numerical simulations using the Boussinesq equations of motion and the thermodynamic energy equation are performed for various slope angles and strip lengths. The underlying dynamical processes in the katabatic jet and the near environment are explored by considering the along-slope momentum balance after a steady state has been achieved. The inhomogeneous nature of the surface forcing also induces a response in the environment that extends very far away from the sloped surface. Nearly horizontal jets close to the vertical heights of both sides of the cold strip are observed in the environment. A horizontal vorticity analysis is performed on these horizontal jets to ascertain their dynamical structure.  相似文献   
129.
The storms usually associated with rill development in nature are seldom prolonged, so development is often interrupted by interstorm disturbances, e.g. weathering or tillage. In laboratory simulated rainfall experiments, active rill development can be prolonged, and under these conditions typically passes through a period of intense incision, channel extension and bifurcation before reaching quasi‐stable conditions in which little form change occurs. This paper presents laboratory experiments with coarse textured soils under simulated rainfall which show how channel adjustment processes contribute to the evolution of quasi‐stability. Newly incised rills were stabilized for detailed study of links between rill configuration and flow energy. On a loamy sand, adjustment towards equilibrium occurred due to channel widening and meandering, whereas on a sandy loam, mobile knickpoints and chutes, pulsations in flow width and flow depth and changes in stream power and sediment discharge occurred as the channel adjusted towards equilibrium. The tendency of rill systems towards quasi‐stability is shown by changes in stream power values which show short‐lived minima. Differences in energy dissipation in stabilized rills indicate that minimization of energy dissipation was reached locally between knickpoints and at the downstream ends of rills. In the absence of energy gradients in knickpoints and chutes, stabilized rill sections tended toward equilibrium by establishing uniform energy expenditure. The study confirmed that energy dissipation increased with flow aspect ratio. In stabilized rills, flow acceleration reduced energy dissipation on the loamy sand but not on the sandy loam. On both soils flow deceleration tended to increase energy dissipation. Understanding how rill systems evolve towards stability is essential in order to predict how interruptions between storms may affect long‐term rill dynamics. This is essential if event‐based physical models are to become effective in predicting sediment transport on rilled hillslopes under changing weather and climatic conditions. Copyright © 2008 John Wiley and Sons, Ltd.  相似文献   
130.
Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (60 wt%) and quartz polymorphs (35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10−16 to 10−17 mol s−1 kg tuff−1 with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10−15 to 10−16 mol s−1 kg tuff−1 for percolation fluxes of 15 mm a−1 and 1 mm a−1, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a−1 or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (50 mg L−1) may inhibit feldspar dissolution.  相似文献   
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