Reduction of nitrogen compounds in oceanic basement and its implications for HCN formation and abiotic organic synthesis     

Nils G Holm  Anna Neubeck 《Geochemical transactions》2009,10(1):9-11

Hydrogen cyanide is an excellent organic reagent and is central to most of the reaction pathways leading to abiotic formation of simple organic compounds containing nitrogen, such as amino acids, purines and pyrimidines. Reduced carbon and nitrogen precursor compounds for the synthesis of HCN may be formed under off-axis hydrothermal conditions in oceanic lithosphere in the presence of native Fe and Ni and are adsorbed on authigenic layer silicates and zeolites. The native metals as well as the molecular hydrogen reducing CO₂ to CO/CH₄ and NO₃ ^-/NO₂ ^- to NH₃/NH₄ ⁺ are a result of serpentinization of mafic rocks. Oceanic plates are conveyor belts of reduced carbon and nitrogen compounds from the off-axis hydrothermal environments to the subduction zones, where compaction, dehydration, desiccation and diagenetic reactions affect the organic precursors. CO/CH₄ and NH₃/NH₄ ⁺ in fluids distilled out of layer silicates and zeolites in the subducting plate at an early stage of subduction will react upon heating and form HCN, which is then available for further organic reactions to, for instance, carbohydrates, nucleosides or even nucleotides, under alkaline conditions in hydrated mantle rocks of the overriding plate. Convergent margins in the initial phase of subduction must, therefore, be considered the most potent sites for prebiotic reactions on Earth. This means that origin of life processes are, perhaps, only possible on planets where some kind of plate tectonics occur.  相似文献   

Petrological inferences on the evolution of magmas erupted in the Andagua Valley,Peru (Central Volcanic Zone)     

E.V. Sørensen  P.M. Holm 《Journal of Volcanology and Geothermal Research》2008

Major and trace element and Sr and Nd isotope data is presented from the Andagua valley scoria cone and lava field (15°32′ S 72°19′ W), Southern Peru in the northernmost part of the Central Volcanic Zone (CVZ). The rocks are all quite evolved in composition (SiO₂ = 55–64 wt.%) and classify as benmoreites, latites and few mugearites and trachytes. Samples are characterized by high Na₂O (4.2–5.2 wt.%), Sr (600–1300 ppm), Ba (800–1600 ppm). The main difference between the benmoreites and latites is in the Na₂O content that reach the highest so far reported from CVZ for these SiO₂ concentrations. The rocks are generally nearly aphyric but latites and trachytes are more porphyritic. Amphibole microphenocrysts generally are only present in latites and trachytes. The difference between benmoreite and latite samples is reflected in lower P₂O₅ and Zr content of the latite samples documenting the existence of two compositional different parental magma types. The investigated volcanic activity spans the Pleistocene to Recent with the historic activity concentrated in the area just south of Andagua. Combined relative stratigraphy, petrography and geochemistry define volcanic units and demonstrate that rocks from Chilcayoc Grande, Chilcayoc Chico 2, Jenchana, Sucna 1 and Chilcayoc Chico 1 represent the most recent volcanic activity. The main trend samples, each form a co-magmatic group resulting in sub-parallel trends in many variations diagrams. It is furthermore shown that these trends point towards calculated mixing lines relating the individual units through a binary mixing process, thus indicating a two stage evolution. In the case of Jenchana, Sucna 1 and Chilcayoc Chico 1, the samples define positive correlation trends in the Sr vs. Rb diagram that can be extrapolated back towards origo indicating nearly perfect incompatibility of Sr and Rb. This together with generally high Sr/Y (50–105) and low Y content (< 16 ppm) suggest lack of plagioclase fractionation and residual garnet in the source and is taken as evidence for relatively high pressure (lower crustal) origin of the mixing event. The amphibole bearing samples form individual co-magmatic groups that cannot be related to each other. This means that the amphibole bearing samples originates from different magmas. The lavas of the Ninamama group are comparable in age to the main trend samples but different in petrography and composition, why the two compositional different magmas must have existed within a small confined area within a limited time span.  相似文献   

Abiotic synthesis of organic compounds under the conditions of submarine hydrothermal systems: a perspective     

Holm NG  Andersson EM 《Planetary and Space Science》1995,43(1-2):153-159

Deep-sea hydrothermal systems have been proposed to be likely environments for chemical evolution and the origin of life on Earth. Recently, experiments have, therefore, been carried out in order to test the hypothesis that amino acids can be synthesized under conditions representing hydrothermally altered oceanic crust. The variety of amino acids that have been detected in such experiments corresponds roughly to that reported previously for electric sparking in reducing gas mixtures. The relative yields of the protein amino acids detected are significantly higher than in electric spark discharge experiments, and the overall yields are about an order of magnitude higher. The amino acids are all racemic.  相似文献   

Pulsars: Observational parameters and a discussion on dispersion measures     

Yervant Terzian  Kris Davidson 《Astrophysics and Space Science》1976,44(2):479-500

The relevant data for the known 147 pulsars are presented in graphical and tabular forms. Various data correlations are discussed, and a detailed analysis of pulsar dispersion measures and distances is given. The range of the electron densities in the diffuse interstellar medium is found to be 0.01 cm^–3n _e0.1 cm^–3, and n _e0.03 cm^–3. The dispersion scale height for pulsars is found to be 5.9±0.7 pc cm^–3 implying a linear scale height of 200 pc, which is much smaller than the electron scale height of our Galaxy.Astrophysics and Space Science Review Paper.  相似文献   

A test of independence for stratigraphic sequences with respect to embedded Markov chains     

Sture Holm  Irene Isaksson  Rodney Stevens 《Mathematical Geology》1986,18(6):551-561

Identification of cyclic sequences gives valuable insight into depositional associations of stratigraphic facies. An embedded Markov chain is a reasonable general model for facies transitions. But a model with independent random occurrences of facies is not an appropriate null hypothesis to be tested to show the presence of cycles because of definitional restriction in transition observations to only those between different facies. This is a common stratigraphic situation and the problem has been raised recently by several authors. We present here a test statistic for null hypothesis derived from the concept of partial independence and inherent to the model of embedded Markov processes.  相似文献   

Spatio-Temporal Complex Markov Chain (SCMC) Model Using Directed Graphs: Earthquake Sequencing     

Michael Cavers  Kris Vasudevan 《Pure and Applied Geophysics》2015,172(2):225-241

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Lateglacial vegetation development in Denmark – New evidence based on macrofossils and pollen from Slotseng,a small-scale site in southern Jutland     

Morten Fischer Mortensen  Hilary H. Birks  Charlie Christensen  Jørgen Holm  Nanna Noe-Nygaard  Bent Vad Odgaard  Jesper Olsen  Kaare Lund Rasmussen 《Quaternary Science Reviews》2011,30(19-20):2534-2550

This paper presents the first unambiguous terrestrial palaeoecological record for the late glacial “Bølling warming” in Denmark. Pollen and macrofossil stratigraphies from pre-Bølling to 10,800 cal yr BP are presented from a small kettle hole in Southwest Denmark, during which the lake basin developed from an immature stage after the deglaciation to complete infilling in the early Holocene. Results show that the recently deglaciated landscape bore a discontinuous vegetation of pioneer plants. After the Bølling warming, an open Dryas octopetala-Betula nana community developed with Helianthemum oelandicum. Subarctic species were dominant and local successions were probably delayed by relatively unstable and infertile soils. There is no indication of a climate cooling during the period corresponding to the Older Dryas, but the occurrence of several drought tolerant and steppe species indicates that the period was relatively dry. In the Allerød period the Dryas-B. nana vegetation was initially replaced by an open Salix and grass dominated vegetation and some 400 years later, the first tree birches were documented presumably occupying moist and sheltered soils while drier land remained open. In the Younger Dryas period trees disappeared and the vegetation became open again and dominated by subarctic species. Following climate warming at the Younger Dryas–Holocene transition a shrub community of Empetrum and Juniperus developed. After approximately 200 years it was replaced by birch forest. Overall, the late-glacial vegetation cover had a more open and patchy character than inferred from previous pollen studies as assessment of the vegetation succession based on macrofossil evidence is essential. The inferred general vegetation development corresponds well with results of other studies in the region. Canonical ordinations (RDA) indicate that vegetation changes at the landscape scale during the Lateglacial period were driven by changes in climate, soils and competition for light.  相似文献   

Observational Effects of Strong gravity     

Kris Beckwith  Chris Done 《Astrophysics and Space Science》2005,300(1-3):87-96

The current paradigm of high energy spectroscopy tells us that light emitted from a wide variety of objects has its origin close to the black hole event horizon. As such, these photons are subject to general relativistic effects such as light-bending, gravitational lensing and redshift, time-dilation, etc. These gravitational effects are well-understood from a theoretical standpoint and therefore, provide a natural mechanism to test the properties of strong gravitational fields. To this end, we have developed a new (semi-analytic) strong gravity code, capable of describing the contribution of photons that perform multiple orbits of the hole. We apply this code to a simple Keplerian accretion disk in order to understand the role played by the angular emissivity, black hole spin and higher order images in forming the line profile.  相似文献   

Late Cenozoic evolution of the western Barents Sea-Svalbard continental margin     

Jan Inge Faleide  Anders Solheim  Anne Fiedler  Berit O. Hjelstuen  Espen S. Andersen  Kris Vanneste 《Global and Planetary Change》1996,12(1-4)

Seven regionally correlatable reflectors, named R7 (oldest) to R1, have been identified in the Upper Cenozoic sedimentary succession along the western continental margin of Svalbard and the Barents Sea. Regional seismic profiles have been used to correlate between submarine fans that comprise major depocentres in this region. Glacial sediment thicknesses reach up to 3 seconds two-way time, corresponding to 3.5–4 km. Despite limited chronostratigraphic control, ages have been assigned to the major sequence boundaries based on ties both to exploration wells and to shallow boreholes, and by paleoenvironmental interpretations and correlations with other regions. Lateral and vertical variations in seismic facies, between stratified and chaotic with slump structures, have major implications for the interpretation of the depositional regime along the margin. The main phases of erosion and deposition at different segments of the margin are discussed in the paper, which also provides a regional seismic stratigraphic framework for two complementary papers in the present volume. Reflector R7 marks the onset of extensive continental shelf glaciations, but whereas the outer Svalbard shelf has been heavily and frequently glaciated since R7 time, this did not occur, or occurred to a much less extent, until R5 time in the southern Barents Sea. The present study provides the background for a quantification of the late Cenozoic glacial erosion of Svalbard and the Barents Sea. The rates of erosion and deposition exhibit large temporal and spatial variations reflecting the importance of glacial processes in the Late Cenozoic development of this nearly 1000 km long margin.  相似文献   

Preliminary Studies of Soils in North-East Greenland between 74° and 75° Northern Latitude     

Bjarne Holm Jakobsen Ph.D. 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2013,113(1):111-115

Jakobsen, Bjarne Holm: Preliminary Studies of Soils in North- East Greenland between 74° and 75° Northern Latitude. Geografisk Tidsskrift 92:111–115. Copenhagen 1992.

The geography of soils has been studied in north-east Greenland between latitudes 74° and 75° N. The study ranges from the outer coast to the interior of the ice-free land area. Well-drained soils show a characteristic sequence determined by the east-west climatic gradient. Fossil soil characteristics and secondary formed features supply information on the palaeoclimate.  相似文献