铝硅酸盐矿物和玻璃中Al的配位与局部结构   总被引：3，自引：2，他引：1  

彭明生  李迪恩 《矿物学报》1998,18(4):425-430

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。  相似文献   

西北地区晚第四纪沉积地层一元正脂肪酸酰胺分布特征及古气候意义     

蒲阳  张虎才  雷国良  常凤琴  杨明生  庞有智 《地球科学进展》2010,25(5):533-542

利用气相色谱质谱联用仪在中国西北地区晚第四纪沉积地层中检测出一类特殊的类脂物分子--一元正脂肪酸酰胺.根据其碳数分布特征及前人的研究成果,认为一元正脂肪酸酰胺来源于各种生物体,产生于生物的某些生理活动过程,而不是来源于石油残余物及各种可能的污染.通过对比3个不同区域相近时期古湖相及黄土沉积地层中的脂肪酸酰胺分布特征,认为柴达木盆地可能不是黄土沉积的主要物源区,而额济纳盆地及邻近区域对黄土堆积有着重要的贡献或具有相同的物源.典型黄土沉积地层中UFAA值(不饱和与饱和脂肪酸酰胺相对含量的比值)与粒度、磁化率等指标具有很好的可对比性,特别是在相对暖湿阶段UFAA值呈现了明显的低值.这一现象表明脂肪酸酰胺在沉积地层中的变化受控于气候变化所导致的成岩作用强度的变化,从而记录了气候变化信息.通过研究,认为生物生理活动过程中所产生的一元正脂肪酸酰胺与构成细胞膜的类脂物分子一样,可记录古气候变化.  相似文献   

Intra-seasonal variability of the abyssal currents in COMRA’s contract area in the Clarion-Clipperton Zone     

Fangfang Kuang  Jing Cha  Junpeng Zhang  Aijun Pan  Hangyu Chen  Xiwu Zhou  Chunsheng Jing  Xiaogang Guo 《海洋学报(英文版)》2022,41(11):1-11

In this paper, the intra-seasonal variability of the abyssal currents in the China Ocean Mineral Resources Association (COMRA) polymetallic nodule contact area, located in the western part of the Clarion and Clipperton Fraction Zone in the tropical East Pacific, is investigated using direct observations from subsurface mooring instruments as well as sea-surface height data and reanalysis products. Mooring observations were conducted from September 13, 2017 to August 15, 2018 in the COMRA contact area (10°N, 154°W). The results were as follows: (1) At depths below 200 m, the kinetic energy of intra-seasonal variability (20?100 d) accounts for more than 40% of the overall low-frequency variability, while the ratio reaches more than 50% below 2 000 m. (2) At depths below 200 m, currents show a synchronous oscillation with a characteristic time scale of 30 d, lasting from October to the following January; the energy of the 30-d oscillation increases with depth until the layer of approximately 4 616 m, and the maximum velocity is approximately 10 cm/s. (3) The 30-d oscillation of deep currents is correlated with the tropical instability waves in the upper ocean.  相似文献   

基于数据挖掘探讨中药治疗肝豆状核变性的用药规律          下载免费PDF全文

余家明  张娟  方名胜 《应用海洋学学报》2022,38(5):19

目的：基于数据挖掘探讨中药治疗肝豆状核变性的用药规律。方法：计算机检索1990年1月至2020年1月中国知网（CNKI）、万方数据（WANFANG DATA）、维普中文科技期刊数据库（VIP）中中药治疗肝豆状核变性的相关文献,利用Microsoft Excel 2010 进行频次分析,通过 SPSS Modeler 18.0、SPSS Statistics 23.0 对处方药物进行关联规则、复杂网络、系统聚类分析。结果：最终纳入文献161篇,筛选出处方151首,中药70味。中药频次排前5位的依次是泽泻、姜黄、大黄、黄连、丹参;功效排前5位的依次是利水渗湿、活血化瘀、清热、补虚、泻下药。二项关联多为利水渗湿、活血化瘀、清热、泻下药的组合,三项关联多为活血化瘀、清热、利水渗湿药的组合。聚类分析得到新方聚类的中药组合3类。结论：中医药治疗肝豆状核变性以清热化湿、活血化瘀为主,常用利水渗湿、活血化瘀、清热药,可配伍补虚及泻下药等。  相似文献   

环境规制视角下城市绿色创新时空演变及溢出效应     

彭文斌  苏欣怡  杨胜苏  邝劲松  曹笑天 《地理科学》2023,43(1):41-49

基于2005—2019年中国266个地级及以上城市的面板数据,采用SBM-DEA模型评价城市绿色创新水平,刻画城市绿色创新的空间演变格局,最后构建空间杜宾模型实证分析不同类型的环境规制视角下城市绿色创新的溢出效应。研究结果显示：(1)时序发展上,研究期内城市绿色创新呈现东部地区、中部地区、西部地区、东北地区依次减弱的态势,总体上表现为“双M”型波动上升趋势,未来具有较大的增长潜力;(2)空间演化上,城市绿色创新在空间分布格局上存在明显的区域异质性,整体表现为东部地区主导发展的特征;(3)城市绿色创新在正式环境规制视角下存在正向溢出效应,在非正式环境规制视角下未产生显著溢出效应。  相似文献   

Erratum to: Purification and characterization of iron-cofactored superoxide dismutase from Enteromorpha linza     

吕明生  蔡阮鸿  王淑军  刘兆普  焦豫良  房耀维  张小昕 《中国海洋湖沼学报》2014,32(1):238-238

<正>Erratum to:Chinese Journal of Oceanology and Limnology Vol.31 No.6,P.1190-1195,2013http://dx.doi.org/10.1007/s00343-013-3049-3The supporting grant information on the footnote of the original version of this article needs to be altered and updated.The new information is given below.  相似文献   

广西沿海超高层建筑进行气象灾害风险评估必要性     

农成万  何如  邝良俊  张幸  李斌喜 《气象研究与应用》2014,(1):71-73,87,I0002

通过列举国内外超高层建筑遭受气象灾害的案例,结合广西气象灾害风险区划资料,分析大风、台风、龙卷风、暴雨、雷电（雷击）、强降温等灾害与沿海超高层建筑的关系,以及可能造成的影响和潜在的风险,论述了超高层建筑进行气象灾害风险评估可实现最大安全与最小投资的统一.以期为广西沿海开展“超高层建筑气象灾害风险评估”工作提供理由和依据.  相似文献   

Fusion of high-resolution DEMs derived from COSMO-SkyMed and TerraSAR-X InSAR datasets   总被引：1，自引：0，他引：1  

Houjun Jiang  Lu Zhang  Yong Wang  Mingsheng Liao 《Journal of Geodesy》2014,88(6):587-599

Voids caused by shadow, layover, and decorrelation usually occur in digital elevation models (DEMs) of mountainous areas that are derived from interferometric synthetic aperture radar (InSAR) datasets. The presence of voids degrades the quality and usability of the DEMs. Thus, void removal is considered as an integral part of the DEM production using InSAR data. The fusion of multiple DEMs has been widely recognized as a promising way for the void removal. Because the vertical accuracy of multiple DEMs can be different, the selection of optimum weights becomes a key problem in the fusion and is studied in this article. As a showcase, two high-resolution InSAR DEMs near Mt. Qilian in northwest China are created and then merged. The two pairs of InSAR data were acquired by TerraSAR-X from an ascending orbit and COSMO-SkyMed from a descending orbit. A maximum likelihood fusion scheme with the weights optimally determined by the height of ambiguity and the variance of phase noise is adopted to syncretize the two DEMs in our study. The fused DEM has a fine spatial resolution of 10 m and depicts the landform of the study area well. The percentage of void cells in the fused DEM is only 0.13 %, while 6.9 and 5.7 % of the cells in the COSMO-SkyMed DEM and the TerraSAR-X DEM are originally voids. Using the ICESat/GLAS elevation data and the Chinese national DEM of scale 1:50,000 as references, we evaluate vertical accuracy levels of the fused DEM as well as the original InSAR DEMs. The results show that substantial improvements could be achieved by DEM fusion after atmospheric phase screen removal. The quality of fused DEM can even meet the high-resolution terrain information (HRTI) standard.  相似文献   

Has climate change driven spatio-temporal changes of cropland in northern China since the 1970s?   总被引：4，自引：0，他引：4  

Wenjiao Shi  Fulu Tao  Jiyuan Liu  Xinliang Xu  Wenhui Kuang  Jinwei Dong  Xiaoli Shi 《Climatic change》2014,124(1-2):163-177

Improving the understanding of cropland change and its driving factors is a current focus for policy decision-makers in China. The datasets of cropland and cropland changes from the 1970s to the 2000s were used to explore whether climate change has produced spatio-temporal changes to cropland in northern China since the 1970s. Two representative indicators of heat and water resources, which are important determinants of crop growth and productivity, were considered to track climate change, including active accumulated temperatures ≥10 °C (AAT10) and the standardized precipitation evapotranspiration index (SPEI). Our results showed that rapid cropland change has occurred in northern China since the 1970s, and the area of cropland reclamation (10.23 million ha) was much greater than that of abandoned cropland (2.94 million ha). In the 2000s, the area of cropland with AAT10 higher than 3,000 °C·d increased, while the area of cropland with an SPEI greater than 0.25 decreased compared to the 1970s, 1980s and 1990s. It appears that climate warming has provided thermal conditions that have aided rapid cropland reclamation in northern China since the 1970s, and drier climatic conditions did not become a limiting factor for cropland reclamation, especially from the 1990s to the 2000s. Approximately 70 % of cropland reclamation areas were located in warmer but drier regions from the 1990s to the 2000s, and approximately 40 % of cropland abandonment occurred in warmer and wetter conditions that were suitable for agriculture during the periods from the 1970s to the 1980s and the 1990s to the 2000s. Our results suggest that climate change can be considered a driving factor of cropland change in the past several decades in northern China, in addition to socioeconomic factors.  相似文献   

机场净空区建筑物的识别与监测     

童矿  宋洋  孔祥芬 《测绘通报》2022,(3):127-131

目前,在建筑物识别与监测方面,基于单幅高分辨率遥感影像的阴影测高法和基于多视角影像的立体像对法将建筑物轮廓或名称识别与高度监测相独立,因此导致其自动化水平较低、数据冗余度与成本较高。基于数字表面模型(DSM)和兴趣点(POI)数据,本文提出了一种机场净空区建筑物识别与监测集成的方法,并以某国际机场为试验区对该方法的可行性进行了验证。试验结果表明:①该方法在建筑物识别与监测方面的准确率只取决于DSM的精度,而对DSM的数据来源没有限制;②以潜在危险建筑物高程变化速率为依据进行不定期的动态监测,在确保监测间隔期间机场净空区安全的同时可以降低数据成本和重复识别与监测所有建筑物造成的数据冗余度。  相似文献