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61.
Analysis of two continuous, high‐resolution palaeo‐flood records from southern Norway reveals that the frequency of extreme flood events has changed significantly during the Holocene. During the early and middle Holocene, flood frequency was low; by contrast, it was high over the last 2300 years when the mean flood frequency was about 2.5–3.0 per century. The present regional discharge regime is dominated by spring/summer snowmelt, and our results indicate that the changing flood frequency cannot be explained by local conditions associated with the respective catchments of the two lakes, but rather long‐term variations of solid winter precipitation and related snowmelt. Applying available instrumental winter precipitation data and associated sea‐level pressure re‐analysis data as a modern analogue, we document that atmospheric circulation anomalies, significantly different from the North Atlantic Oscillation (NAO), have some potential in explaining the variability of the two different palaeo‐flood records. Centennial‐scale patterns in shifting flood frequency might be indicative of shifts in atmospheric circulation and shed light on palaeo‐pressure variations in the North Atlantic region, in areas not influenced by the NAO. Major shifts are found at about 2300, 1200 and 200 years ago (cal. a BP). Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
62.
The activity of FeTiO3 in the binary ilmenitepyrophanite (FeTiO3-MnTiO3) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO3=2 Fe+2 TiO2+O2 in T-O2 space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, W Fe-Mn ilm , of 2.2±0.3 kJ g-atom–1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives W Fe-Mn gt =1.2±0.5 kJ g-atom–1 for the almandine-spessartine (Fe3Al2Si3O12-Mn3Al2Si3O12) solid solution.  相似文献   
63.
The enthalpies of transition at T= 298 K between zinc metasilicate assemblages, measured by molten oxide solution calorimetry, are:
  相似文献   
64.
According to the present state of science and technology, the ultimate disposal of critical substances such as chemotoxic wastes, metal slurries, radioactive substances, etc., as well as houshold waste, necessitates enclosure within a multi-barrier system. The geology of the disposal site plays an important role. The site itself defines the geological barrier which has to fulfill at least two requirements: namely low permeability and retention, respectively retardation qualities. These can be achieved to a certain degree either by clay minerals, zeolites or an artificial product such as active coal. In order to increase the imperviousness and retardation potentials of e.g. clayey geological barriers, technical barriers have to be added. One of them and the most important is the mineralogic barrier. It consists of clay dominated layers and according to the multimineral barrier concept the different layers have to meet different functions.  相似文献   
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67.
NiAl2O4 is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl2O4 quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a0, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).  相似文献   
68.
The equilibrium diffusion technique has become a valuable tool for ecological and biogeochemical studies in aquatic environments. In sediment ecosystems, changes in concentration of microbial metabolites with increasing depth can be determined dependably and reproducibly with this technique. Since the permeation characteristics of the membranes employed are crucial, selecting the proper membrane requires knowledge about its behavior under conditions which prevail in the natural environment. Thirteen polymer sheets were evaluated comparing permeation terms for biogeochemically relevant solutes, biodegradability, and mechanical strength. Cellulose-based dialysis membranes are most satisfactory when employed in low temperature anoxic environments. For this membrane, correction terms were calculated to account for diffusion losses during retrieval and sampling. Optimal incubation times can now be predicted from experimentally determined permeation coefficients for several porewater solutes. Dialysis porewater samplers (DPS) have been successfully applied during more than 100 independent experiments for the collection of interstitial water from surface sediments. DPS were used for water depths as deep as 290 meters.  相似文献   
69.
Mantle fragments of ultramafic composition are widespread in the Scandinavian Caledonides (SC). Lenses and boudins of Alpine-type peridotites in the Scandinavian Caledonides represent parts of dismembered ophiolite sequences and fragments of sub-continental upper mantle. Metaperidotites of nappes in internal positions are generally isofacial with the metamorphic envelope, usually Caledonian metasediments but in places also Precambrian metagranitoids forming the basement cores of the nappes. Caledonian metamorphism strongly modified the texture and mineralogy of the peridotites and resulted in a systematic metamorphic pattern which is consistent with the pattern observed in the envelope.

Metaperidotites of the external massifs display at least a two-stage metamorphic history: an early Caledonian high-pressure high-temperature phase related to early crustal stacking and a late Caledonian regional metamorphic overprint which produced a regular Barrovian-type metamorphic pattern of in-situ metamorphism.

Metaperidotites from nappes in intermediate positions (Iapetus Ocean ophiolites and ultramafic rocks from island arc environments) show strongly diverging histories. Metaperidotites from internal ophiolites (oceanic ophiolites, Köli) lack any evidence of subduction metamorphism, are serpentinized to various degrees, show abundant primary mantle relic mineralogies and the Caledonian metamorphic overprint is low. Metaperidotites from external (island arc) ophiolites and other associations (Seve) often show relic high-pressure metamorphism related to the Finnmarkian phase of the Caledonian orogeny. The Seve metaperidotites are occasionally associated with eclogites and show a weak overprint of late Caledonian regional metamorphism. Alpine-type peridotites are absent in the foreland of the Baltic Shield and in the innermost nappes (Lofoten).

The metamorphic characteristics and evolution recorded by the metaperidotites in the Scandinavian Caledonides allow a general reconstruction of the dynamics of collision belt formation.  相似文献   

70.
Thirteen alicyclic compounds (C5… C7) are examined for their biochemical degradability in a laboratory activating tank and in two respirometers (Warburg, Sapromat). The tests were performed with adapted and nonadapted activated sludge. In addition, the COD was determined by three different methods. With the exception of cycloheptane (BOD < 25% of the BODtheor.), six compounds prove to be easily degradable (BOD > 45% of the BODtheor.) and six compounds prove to be degradable (BOD 45… 25% of the BODtheor.).  相似文献   
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