Distribution and fluxes of metals in the St. Lawrence River from the outflow of Lake Ontario to Québec City     

Ken R. Lum  K. L. E. Kaiser  C. Jaskot 《Aquatic Sciences - Research Across Boundaries》1991,53(1):1-19

Six anchor stations in the St. Lawrence River from the outflow of Lake Ontario to Quebec City, were occupied for ca. 24 hours in June 1987 during low flow conditions. Samples of water and suspended particulate matter were separated by continuous-flow centrifugation, and were collected every two hours.During this sampling period, fluxes of dissolved forms of zinc, copper and nickel increased in Lac St. François and downstream relative to the sum of the fluxes for the two upstream stations at the outflow of Lake Ontario. Increases in the flux of dissolved zinc and copper were pronounced below Montreal and above Lac St. Pierre. For particulate forms of metals, all five metals show that there are significant inputs in the section of the St. Lawrence River between Lac St. François and the station just above the entrance to Lac St. Pierre.The average concentrations of dissolved cadmium, lead, zinc, copper and nickel ranged from 7–23 ng/l; 9–35 ng/l; 0.434–0.939 g/l; 0.15–0.89 g/l and 0.58–1.12 g/l respectively.Regression analysis of the dissolved and particulate metal concentrations suggests that the concentration of dissolved cadmium, lead, zinc and nickel can be predicted from the regression equation and the determination of particulate metal concentration. This prediction appears to be independent of the suspended particulate matter concentration which varies from ca. 1 to 10 mg/l from the outflow of Lake Ontario to Québec City.  相似文献   

Na-rich carbonate inclusions in perovskite and calzirtite from the Guli intrusive Ca-carbonatite,polar Siberia     

L. N. Kogarko  D. A. Plant  C. M. B. Henderson  B. A. Kjarsgaard 《Contributions to Mineralogy and Petrology》1991,109(1):124-129

Carbonate phases, some rich in Na₂O and comparatively rich in SrO and BaO, occur as inclusions in perovskite and calzirtite (Ca₂Zr₅Ti₂O₁₆) in the carbonatite of the Guli complex, Siberia. This is the first record of alkali carbonates, akin to nyerereite [Na₂Ca(CO₃)₂], in plutonic igneous rocks. The inclusion populations suggest that the parental magma of the complex was Ca-rich but developed Na-rich differentiates during the latest stages. This points to the dominant calcic carbonatites of the complex not being derivatives of alkali-rich parental carbonatites. These alkali-rich carbonate inclusions (and rare inclusions of djerfisherite) have been preserved due to the resistance of perovskite and calzirtite to processes of leaching, hydrothermal alteration and weathering.  相似文献   

Geochemical specialization of the tin-bearing granitoid massifs of NW Bohemia   总被引：4，自引：0，他引：4  

K. Breiter  M. Sokolová  A. Sokol 《Mineralium Deposita》1991,26(4):298-306

The geochemistry of Hercynian tin-bearing granitoid massifs of the Krune hory Mts. (Erzgebirge), Slavkovský les Forest (Kaiserwald) and Smriny (eastern Fichtelgebirge) is compared by statistical processing of 270 analyses including a wide spectrum of major and trace elements. Seven different types of granites are distinguished. Out of these, five types represent the successive differentiation of the largest massif of NW Bohemia: the Karlovy Vary (Karlsbad) massif. This comprises strongly differentiated peraluminous granites evolving towards extreme Li-Rb-Cs-F-and Sn-enrichment in the youngest members, which are albite-topaz-zinwaldite lithium granites. The sixth and seventh types are different from the former by their location in the eastern Krune hory and tectonic setting, and they display geochemical features of anorogenic granites: they are metaluminous albite-zinwaldite granites with marked enrichment of Nb, Y, and HREE in addition to Li, Rb, Cs, F and Sn, indicating contamination by sub-crustal material. Sn-W mineralizations, including flat peri-contact greisen bodies, steep greisen veins and tourmalinized phyllites, are all intimately associated with the most strongly differentiated granites — the Li-granite and the Cinovec-granite respectively.  相似文献   

Directions and possibilities of mathematical geology     

L. I. Chetverikov 《Mathematical Geology》1991,23(1):33-40

This paper considers the present state of mathematical geology. Three directions are recognized: applied, theoretical, and mathematical. Applied mathematical geology includes formal use of mathematics to solve problems and computer processing of data. Success is achieved by a correspondence of mathematical methods used to the nature of geological data. This correspondence can be demonstrated by purely mathematical means. Theoretical mathematical geology uses mathematics as a language of geology; however, a number of methodological problems must be solved: formalization of initial geological concepts and creation of a strict conceptual basis, substantiation of initial principles of mathematical simulation, creation of theoretical geological models, problems of elementary and coincidence in geology, and methodological substantiations of possibilities of any mathematical model to approximate geological models. The essense and significance of these problems are considered. The main task of mathematical geology is to prove its correspondence to the nature of the geological objects studied, geological data obtained, and geological problems solvable. Finally, the main problems of mathematical geology are not so much mathematical as geological and methodological.  相似文献   

Neutron techniques     

Glenn M. Frye Jr.  Philip P. Dunphy  Edward L. Chupp  Paul Evenson 《Solar physics》1988,118(1-2):321-346

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Diurnal photometric conditions at Teide observatory and long-term solar irradiance variations     

B. Andersen  V. Domingo  A. Jiménez  A. Jones  S. Korzennik  P. L. Pallé  F. Pérez Hernández  C. Régulo  T. Roca Cortés  L. L. Tomás 《Solar physics》1988,116(2):391-399

Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively.  相似文献   

Bidimensional spectroscopy of network bright points     

A. Falchi  R. Falciani  L. A. Smaldone  G. P. Tozzi 《Solar physics》1988,114(1):29-45

We develop an automatic, computer controlled procedure to select and to analyze the Network Bright Points (NBPs) on solar images. These have been obtained at the Sac Peak Vacuum Tower Telescope by means of the Universal Birefringent Filter and Zeiss H filters, tuned, respectively, along the profiles of the H, Mg-b1, Na-D2, and H lines.A structure is identified as an NBP if at the wavelength H- 1.5 A its maximum intensity is greater than I + 3 and its area is greater than 1.5 arc sec² at I + 1.5, where I is the mean value and the standard deviation of the intensity distribution on the image. Each detected NBP is then searched and confirmed in all the remaining 31 images at different wavelengths.For each NBP several parameters are measured (position, area, mean and maximum contrast, Dopplergram velocity, compactness, and so on) and some identification constraints are applied.The statistical analysis of the various parameter distributions, for NBPs present within an active region and its surroundings, shows that two types of NBPs can be identified according to the value of their mean contrast C _min the H- 1.5 Å image (C _m 0.1 type I, C _m> 0.1 type II). The type I NBPs (all occurring on the boundaries of the supergranular network) appear to be much more frequent (180/26) than the type II ones.The size A of type I NBPs is less than 1.0 arc sec for H/H wings but of the order of 1.2 arc sec for Na-D2 and Mg-bl. The mean contrast C _m is around the value of 10% along the Na-D2 and Mg-bl profiles and of 20% along the H/H wings.The C _m - A scatter diagrams show, for the photospheric radiation (h < 100 km), a narrow range of variability for C _min correspondence with a wide range for A. For radiation orginated at higher levels (h > 200 km), the C _m- A scatter diagrams seem to indicate, even if with a large variance, that the highest C _m's tend to correspond to the highest A values.The mean Doppler shift is close to zero for Na-D2 and Mg-bl lines but negative (downward motion) for H and H lines.The type II NBPs tends to be preferentially located in the neighbourhood of small, compact sunspots and their detectability is almost constant through all the 4 studied line profiles. No conclusions can be derived on the mean size, contrast and Doppler shift values because their distributions are too dispersed. The only positive information is that its C _m- A scatter diagram, in H and H wings, indicates a wide range of variability for C _m in correspondence with very narrow range of variability for A.  相似文献   

Observations of interstellar HOCO+: abundance enhancements toward the galactic center     

Minh YC  Irvine WM  Ziurys LM 《The Astrophysical journal》1988,334(1):175-181

A survey of the 4(04)-3(03) and 1(01)-0(00) transitions of HOCO+ has been made toward several molecular clouds. The HOCO+ molecule was not observed in any sources except Sgr B2 and Sgr A. The 5(05)-4(04) and 4(14)-3(13) transitions were also detected toward Sgr B2. The results indicate that gas phase CO2 is not a major carbon reservoir in typical molecular clouds. In Sgr B2, the HOCO+ antenna temperature exhibits a peak approximately 2' north of the Sgr B2 central position (Sgr B2[M]) and the 4(04)-3(03) line emission is extended over a approximately 10' x 10' region. The column density of HOCO+ at the northern peak in Sgr B2 is approximately 3 x 10(14) cm-2, and the fractional abundance relative to H2 > or = 3 x 10(-10), which is about 2 orders of magnitude greater than recent predictions of quiescent cloud ion-molecule chemistry.  相似文献   

Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

Heterodyne spectroscopy of the 158 micron C II line in M42     

Boreiko RT  Betz AL  Zmuidzinas J 《The Astrophysical journal》1988,325(2):L47-L51

We have obtained velocity-resolved spectra of the 12C II 157.8 microns 2P3/2-2P1/2 fine structure line in the M42 region of Orion. Observations at 0.8 km s-1 resolution with a laser heterodyne spectrometer show multiple velocity components in some locations, with typical linewidths of 3-5 km s-1. Spectra of theta 1C and BN-KL also show weak emission from the F = 2-1 hyperfine component of the equivalent 13C II line. From the observed 12C II/13C II line intensity ratios, we deduce that the 12C II emission is optically thick with tau approximately 5 at both positions. Excitation temperatures of 128 K and 90 K, together with column densities of approximately 1 x 10(19) cm-2 and approximately 4 x 10(18) cm-2, are derived for theta 1C and BN-KL, respectively.  相似文献