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21.
Recent analyses of the carbonate globules present in the Martian meteorite ALH84001 have detected polycyclic aromatic hydrocarbons (PAHs) at the ppm level (McKay et al., 1996). The distribution of PAHs observed in ALH84001 was interpreted as being inconsistent with a terrestrial origin and were claimed to be indigenous to the meteorite, perhaps derived from an ancient martian biota. We have examined PAHs in the Antarctic shergottite EETA79001, which is also considered to be from Mars, as well as several Antarctic carbonaceous chondrites. We have found that many of the same PAHs detected in the ALH84001 carbonate globules are present in Antarctic carbonaceous chondrites and in both the matrix and carbonate (druse) component of EETA79001. We also investigated PAHs in polar ice and found that carbonate is an effective scavenger of PAHs in ice meltwater. Moreover, the distribution of PAHs in the carbonate extract of Antarctic Allan Hills ice is remarkably similar to that found in both EETA79001 and ALH84001. The reported presence of L-amino acids of apparent terrestrial origin in the EETA79001 druse material (McDonald and Bada, 1995) suggests that this meteorite is contaminated with terrestrial organics probably derived from Antarctic ice meltwater that had percolated through the meteorite. Our data suggests that the PAHs observed in both ALH84001 and EETA79001 are derived from either the exogenous delivery of organics to Mars or extraterrestrial and terrestrial PAHs present in the ice meltwater or, more likely, from a mixture of these sources. It would appear that PAHs are not useful biomarkers in the search for extinct or extant life on Mars. 相似文献
22.
Ricard A Cernogora G Fitaire M Hochard L Kouassi N Speller C Vacher JR 《Planetary and Space Science》1995,43(1-2):41-46
The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K. 相似文献
23.
Domy C. Adriano Hyo T. Chon Sally L. Brown Rosanna Ginocchio 《中国地球化学学报》2006,25(B08):45-46
Metals, including heavy metals and metalloids, are a common group of environmental contaminants. Their sources in the environment are geogenic or anthropogenic. The growing trend in global industrialization ensures that more metals could be dispersed even in pristine ecosystems. To fuel industrialization, more metal ore mines have to be discovered and explored. These explorations often result in landscape disturbance, soil degradation and environmental contamination by unwanted mining constituents. Mine tailings brought up to the ground surface often serve as the main source of contaminants when these pyrite-rich materials oxidize. The oxidation of mine tailings results in proton generation, coupled with the dissolution of metals and other cations Unwanted anionic constituents are also produced. The so-called "acid mine drainage" may affect the productivity of farmlands and stability of receiving streams and other bodies of water-acidifying the waters and enriching the ecosystem with metals, i.e., high total dissolved solids. The acidified overburden materials become inhospitable to plant and microbial life as they are typically low in organic matter content and infertile. This exposes the landscape to runoff and erosion. 相似文献
24.
YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
25.
Philip L. Verplanck D. Kirk Nordstrom Geoff S. Plumlee Richard B. Wanty Dana J. Bove Jonathan S. Caine 《中国地球化学学报》2006,25(B08):231-231
In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors: mineralogy and hydrology. Parameters that potentially affect water chemistry include: host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations (for example: Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L). With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides. 相似文献
26.
根据Dobson和TOMS资料分析北京和昆明大气臭氧总量变化特征 总被引:11,自引:0,他引:11
用约20年 Dobson和TOMS资料来分析北京(39.93°N,116.40°E)和昆明 (25.02°N,102.68°)两地大气臭氧总量的变化特征,结果表明:(1)在1979-2000年间北京大气臭氧长期变化趋势是-0.642 DU/年,而昆明在1980-2000年间的趋势是-0.009 DU/年;(2)北京和昆明两地大气臭氧都有很强的季节内变化(尤其冬季更强),与季节性变化强度相当;(3)在北京和昆明,由记录较短的大气臭氧资料分析得到的长期变化趋势,与较长记录得到的结果有显著差异;(4)在北京(中纬度)和昆明(低纬度)大气臭氧都有显著的准两年振荡信号;(5)两个站点大气臭氧的年际变化主要由长期趋势项和准两年振荡信号组成;(6)Dobson仪测量得到的臭氧总量与TOMS资料非常一致。 相似文献
27.
28.
海底天然气渗漏形成水合物量的线性动力学模型:以墨西哥湾GC185区块Bush高地为例 总被引:7,自引:1,他引:7
世界许多地区如墨西哥湾,存在着大量天然气渗漏并形成水合物的现象,出于科学,生态,气候和安全的需要。人类有必要弄清存在于海底以水合成形式存在的天然气的比例。因此,构建了水合物形成量的线性动力学模型,以分析墨西哥湾GC185块区Bush高地海底渗漏天然气的地质过程和行为。Bush高地渗漏的天然气来源于附近的Jolliet气藏,结果表明,渗漏天然气中约有9%的海底形成了水合物。 相似文献
29.
渤海湾老狼坨子海岸带^14C,^137Cs、^210Pb测年与现代沉积速率的加速趋势 总被引:10,自引:5,他引:10
通过对渤海湾西岸L剖面中同一关键层的碳酸钙和原生腹足类壳债权的^14C测年对比研究,确定了晚全新世的2800cal BP的层位及沉积速率0.045cm/a;8个样柱的^137Cs和^210Pbex强度、蓄积量揭示了距今约120年来堤后盐沼的平均沉积速率约为0.35cm/a,而面向开放海湾的潮坪上部则达到约2-3cm/a。研究区近1个世纪以来沉积速率的加速趋势,是渤海湾西岸泥质海岸带的特征之一。 相似文献
30.
在蒙古南戈壁的Bayan—Khoshuu Ruins剖面原归入到志留系Mandalovoo组尕屋(Gavuu)段的地层中发现了牙形刺Caudicriodus woschimidti woschmidti,这是泥盆纪最早期牙形刺带化石在蒙古的首次发现。尕屋(Gavuu)段的下部属志留系,但其上部,即采集牙形刺样品M-9~M-12的层位肯定属下泥盆统(下洛霍考夫阶),而不是下志留统。Mandalovoo组应当改为Mandalovoo群,它的三个段应提升为三个组。 相似文献