Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry     

Daniel P. Glavin  Jason P. Dworkin  Andrew Aubrey  Oliver Botta  James H. Doty  Zita Martins  Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.  相似文献   

    

A. S. Belyakov  V. S. Lavrov  A. V. Nikolaev  L. L. Khudzinskii 《Doklady Earth Sciences》2006,407(2):258

  相似文献   

Colour variability of asteroids in the Sloan Digital Sky Survey Moving Object Catalog     

Gy. M. Szabó  &#;. Ivezi&#; †  M. Juri&#;  R. Lupton  L. L. Kiss 《Monthly notices of the Royal Astronomical Society》2004,348(3):987-998

  相似文献   

The 2dF QSO Redshift Survey – XII. The spectroscopic catalogue and luminosity function     

S. M. Croom  R. J. Smith  B. J. Boyle  T. Shanks  L. Miller  P. J. Outram  N. S. Loaring 《Monthly notices of the Royal Astronomical Society》2004,349(4):1397-1418

  相似文献   

The impact of broad mid-infrared emission bands on extragalactic surveys – a case study: the unidentified 22-μm feature     

Chris P. Pearson  K.-W. Chan  T. Onaka 《Monthly notices of the Royal Astronomical Society》2004,350(2):473-484

  相似文献   

MASS FLUX OF ASTEROIDAL ORIGIN METEOROIDS ON PERIODIC COMET NUCLEI     

R. L. HAWKES  R. A. EATON 《Earth, Moon, and Planets》2004,95(1-4):187-195

We examine the potential contamination of cometary nuclei through impacts from asteroidal origin meteoroids. The paper uses a simple model and has the goal of determining whether asteroidal contamination is potentially significant. We assume a meteoroid power law mass distribution with index values in the range from s=1.83 to s=2.09. We used maximum and minimum models which we believe will bracket the true meteoroid mass distribution. We identify those comets which are expected to be most significantly contaminated, and find values of up to 3.6 kg of asteroidal meteoroid impact per square meter of the cometary surface per orbital revolution. This is less than the expected mass loss per perihelion passage for most comets. Therefore any remnant effects of the contamination will depend on the penetration depth of the meteoroids in the cometary nucleus, and possibly on the distribution of active and inactive areas on cometary nuclei. We present a simple model which suggests that even small meteoroids will embed relatively deeply into a cometary nucleus.  相似文献   

应用ATA的对数周期馈源方案于FAST的可能性探讨     

吴盛殷  熊继衮  吕善伟  张江林  徐祥  南仁东  金乘进 《天文学进展》2004,22(2):179-187

介绍应用于美国凤凰计划的Allen望远镜阵(ATA)的对数周期馈源(LPA)概况，初步给出此种馈源的基本参数及性能，仿真估算了其驻波比和方向图，并结合正在进行中的我国500m孔径球面射电望远镜(FAST)计划，探讨了应用这种宽带馈源的可能性及其限制。  相似文献   

On the Nature of the Object HD 209458b: Conclusions Drawn from Comparison of Experimental and Theoretical Data     

Ksanfomaliti  L. V. 《Solar System Research》2004,38(4):300-308

The experimental data obtained in transit observations of the extrasolar planet HD 209458b and their comparison with theoretical inferences have led to the conclusions that HD 209458b (and other similar hot jupiters) is of a (mainly) hydrogen nature and that these objects probably possess strong magnetic fields. The results of the studies of HD 209458b and prospects for searches for the transits of other extrasolar planets are considered in detail.  相似文献   

Chemical alteration of tephra in the depositional environment: theoretical stability modelling     

A. M. Pollard  S. P. E. Blockley  K. R. Ward 《第四纪科学杂志》2003,18(5):385-394

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Parameters of the intense X-ray and gamma-ray radiation from the solar flare of May 20, 2002, as observed from the Coronas-F spacecraft     

A. V. Bogomolov  A. P. Ignat’ev  K. Kudela  S. N. Kuznetsov  Yu. I. Logachev  O. V. Morozov  I. N. Myagkova  S. N. Oparin  A. A. Pertsov  S. I. Svertilov  B. Yu. Yushkov 《Astronomy Letters》2003,29(3):199-204

We consider temporal, spectral, and polarization parameters of the hard X-ray and gamma-ray radiation observed during the solar flare of May 20, 2002, in the course of experiments with the SONG and SPR-N instruments onboard the Coronas-F spacecraft. This flare is one of the most intense gamma-ray events among all of the bursts of solar hard electromagnetic radiation detected since the beginning of the Coronas-F operation (since July 31, 2001) and one of the few gamma-ray events observed during solar cycle 23. A simultaneous analysis of the Coronas-F and GOES data on solar thermal X-ray radiation suggests that, apart from heating due to currents of matter in the the flare region, impulsive heating due to the injection of energetic electrons took place during the near-limb flare S21E65 of May 20, 2002. These electrons produced intense hard X-ray and gamma-ray radiation. The spectrum of this radiation extends up to energies ≥7 MeV. Intense gamma-ray lines are virtually unobservable against the background of the nonthermal continuum. The polarization of the hard X-ray (20–100 keV) radiation was estimated to be ≤15–20%. No significant increase in the flux of energetic protons from the flare under consideration was found. At the same time, according to ACE data, the fluxes of energetic electrons in interplanetary space increased shortly (～25 min) after the flare.  相似文献