Benthic nutrient fluxes in the intertidal flat within the Changjiang （Yangtze River） Estuary   总被引：1，自引：0，他引：1  

GAO Lei    LI Daoji  WANG Yanming  YU Lihua  KONG Dingjiang  LI Mei  LI Yun  and FANG Tao State Key Laboratory of Marine Geology  Tongji University  Shanghai  China State Key Laboratory of Estuarine  Coastal Research  East China Normal University  Shanghai  China 《中国地球化学学报》2008,27(1):58-71

In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang （Yangtze River） Estuary. Except for NH4^＋, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water （Dw） in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 （n=18）. These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification.  相似文献   

Geochemistry and environmental effect of cadmium in the super-large Jinding Pb-Zn deposit,Yunnan Province,China     

Hang Li  Dahua Li  Tangfu Xiao  Libin He  Zengping Ning  Jialong Sun  Changsheng Zhu  Yan Shuang 《中国地球化学学报》2008,27(1):21-27

The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment.  相似文献   

Changes in nutrient uptake of phytoplankton under the interaction between sunlight and phosphate in the Changjiang （Yangtze） River Estuary     

FANG Tao LI Daoji YU Lihua LI Yun 《中国地球化学学报》2008,27(2):161-170

We conducted ship-board incubation experiments to investigate changes in nutrient uptake of phytoplankton under different phosphate concentrations and irradiances in the Changjiang River Estuary and its adjacent waters in China. Under 100% natural irradiance the uptake rates of phosphate, silicate, and nitrate were accelerated at high phosphate levels （1.84 μM）, while under low irradiance （about 50% natural irradiance） their uptake rates were restrained at the high but stimulated greatly at the intermediate phosphate concentrations （1.26 μM）, as the growth of phytoplankton, changes in nitrite and ammonium uptake didn＇t follow an obvious pattern. Our results also showed that there were linear relationships between nitrate, silicate and phosphate uptake at different phosphate concentrations under low and high irradiances, and the growth period of phytoplankton was prolonged both at the high phosphate concentrations under high irradiance and at the intermediate concentrations under low irradiance, suggesting that the limitation of phytoplankton growth mainly reflected changes in its growth period, and because no such environment （low irradiance and low phosphate concentrations） actually existed in a high turbidity zone, phytoplankton blooms hardly occurred there. In the absence of irradiance, denitrification occurred readily and phytoplankton was kept decreasing, which resulted in phosphate regeneration.  相似文献   

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Playa——A Coupled Model of Reactive olute Transport and Chemical Equilibrium in a Multi-component Underground Brine System     

LI Wenpeng  LIU Zhenying 《《地质学报》英文版》2008,82(5)

Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea oftransport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory.Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/Magnesium in the mining of salt deposits in Qarhan Salt Lake.  相似文献   

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Piaya——A Coupled Model of Reactive Solute Transport and Chemical Equilibrium in a Multi-component Underground Brine System     

LI Wenpeng 《《地质学报》英文版》2008,(5)

Firstly,the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory.The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented,which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake.And secondly,with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference,a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile,the model was applied to model potassium/magnesium transport in Qarban Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarban Salt Lake.  相似文献   

δ13c-δ18O Covariance:An Effective Indicator of Hydrological Closure for Lakes?     

CHEN Jing''''an  WANG Fushun  WAN Guojiang  TANG Degui  David Dian ZHANG  HUNAG Ronggui  LI Jian  XIAO Tangfu 《《地质学报》英文版》2008,82(5)

The correlation between the Δ13c and 18O in primary carbonates is affected by several factors such as hydrological balance, total CO2 concentrations, climatic condition and lake productivity.The influence of these factors on the Δ13c-δ18 correlation may be different on different time scales. In this paper, two different-type lakes in southwestern China, Lake Erhal and Lake Chenghai, are selected to investigate the influence of climatic pattern on the Δ13c-Δ18o correlation and to evaluate the reliability of the Δ13c-Δ18o covariance as an indicator of hydrological closure. The results show that there exists good correlation between the Δ13c and Δ18o in Lake Erhai (overflowing open lake) and inLake Chenghal (closed lake). This suggests that the Δ13c-Δ18o covariance may be not an effective indicator of hydrological closure for lakes, especially on short time scales. On the one hand, a hydrologically open lake may display covariant Δ13c and δ18 as a result of climatic influence. The particular alternate warm-dry and cold-wet climatic pattern in southwestern China may be the principal cause of the Δ13c-δ18 covariance in Lake Erhai and Lake Chenghal. On the other hand, a hydrologically closed lake unnecessarily displays covariant trends between Δ13c and δ18 because of the buffering effect of high CO2 concentration on the Δ13c shift in hyper-alkaline lakes. We should be the buffering feeect of high CO2 concentration on the 13Cshift in hyper-alkaline lakes.We should be prudent when we use the covariance between 13C and 18O to judge the hydrological closure of lake.  相似文献   

The Role of Fracture Structure in Leachate Pollution at Landfills： A Case Study of a Landfill in Chongqing City     

LUO Yunju  LIU Dongyan  LI Xiulan  ZHU Zhengwei 《《地质学报》英文版》2008,82(5)

This paper studies a landfill where there are three faults running through.As serious pollution has occurred to the geological environment,the landfill is to be closed up and renovated.The paper aims to explore the role of fracture structure in leachate pollution at the landfill.The research was carried out in several stages.First,mathematical models of the pre-renovation landfill with three faults running through and the landfill after renovation were established.And then,the boundary conditions and parameters of the two mathematical models were determined.The groundwater level of the landfills was simulated in order to modify the two mathematical models.As a result,a feasible mathematical model was achieved.Based on this model,a comparison was made of the COD concentration variations in the inside leachate and outside leachate between the two landfills. Accordingly,the impacts of the fracture structure on the pollution of leachate at the landfills could be identified.The study results show that while faults contribute to the migration of leachate,they also serve as a confluence of leachate,thus further deteriorating the environment.The COD concentrations of the inside leachate and the outside leacbate of the pre-renovation landfill are respectively 800 mg/L and 220 mg/L higher than those of the post.renovation landfill.Therefore,measures must be taken to handle the leachate seepage in areas where there are faults as well as the neighboring areas so as to get the environmental pollution under control.  相似文献   

Yangshan Gold Deposit: The Largest Carlin and Carlin-like Type Gold Deposit in China     

YAN Fengzeng  LI Qiangzhi 《《地质学报》英文版》2008,82(4)

Gold Headquarter of the CAPF has discovered the Yangshan super large-scale gold depositin Gansu Province, which is a great breakthrough of gold exploration and prospecting in WesternQiniing Mountains of China. The gold resources of this deposit achieved 308 tons with increasingpotentials. Preliminary geological investigations indicate that the Yangshan gold deposit is located inthe intra-continental collision orogenic belt; and the deposit was formed during the continent-continentcollision orogenic processes. The geological characteristics of the deposit are similar to that of thetypical Carlin-type gold deposits, while differences still exist. The ore-forming background is notablydifferent from the Carlin gold deposit province in the United States; and the ore-forming fluids aresimilar with that of the orogenic-type gold deposit. Accordingly, the Yangshan gold deposit is atransitional type between the Carlin-type and the orogenic type gold deposits. At present, the Yangshangold deposit is the largest Carlin and Carlin-like type gold deposit that is ever discovered in China.Researches on metaliogeny, metaliogenic model and ore-enrichment regularities of the Yangshan golddeposit are crucial to meet the pressing needs of the current geological investigation and oreexploration of the deposit.  相似文献   

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China     

Xin Li  Dongliang Wang  Baoquan Liu  Chunling Ren  Jianying Guo  Xuefeng Su  Jian Wang 《中国地球化学学报》2008,27(4):412-419

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.  相似文献   

Geochemical characteristics and genetic types of crude oils from the Tertiary system in the southern part of western Qaidam Basin, Northwes     

LI Hongbo ZHANG Min ZHANG Chunming PENG Dehua 《中国地球化学学报》2008,27(3)

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