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91.
Secular Amazon discharge oscillations were investigated comparing information from ancient cartography, satellite images, palaeovegetation, sediments, anthropology and climate, focusing on the evolution of Marajó Island in the Amazon estuary. Four phases were identified. (1) 800–1200 a.d.: Amazon discharge increased gradually and eastern Marajó was a vegetation-free tidal plain with energy oscillations. (2) 1200–1350 a.d. was a dry period with lower river discharges, lower energy, increasing water salinities and maximum mangrove extension, coinciding with the extinction of chiefdoms in Marajó. (3) 1350–1540 a.d.: Amazon discharge increased rapidly, inducing a dominance of freshwater vegetation, inundation of east Marajó and likely a regional rise of relative sea-level (RSL). (4) 1540–1750 a.d.: RSL decreased, coinciding with an El Niño-related intense drought ca. 1600 a.d. Emergence of eastern Marajó was rapid and completed in the eighteenth century, under RSL stabilization to current values. The approach used provided evidence of intermittent large changes in Amazon climate, and can facilitate the prediction of future regional dynamics.  相似文献   
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93.
Experimental studies were carried out in laboratory in order to investigate the effects of fracture on compressional (P) wave and shear (S) wave velocity propagation and therefore the relations between seismic properties and rock mass parameters. The discontinuity index, Id, fracture density parameter C, linear fracture parameter Γ and the rock quality designation (RQD) were used to describe the rock mass parameters. These parameters are analyzed and then related to the seismic properties. Four vertical aligned fractures were created on an intact calcarenite block, 0.6 m long, 0.4 m thick and 0.4 m width, by sawing. The measures were carried out in four different blocks of cacarenite, having the same physical properties, and in four different phases: in first block the fractures were filled with air; in the second block the fractures were filled with “terra rossa”; in third block the fractures were filled with wet “terra rossa” and in the fourth block the fractures were filled with clay. The test results were statistically analysed using the method of least squares regression and polynomial relationships with high correlation coefficient were found between the fractured rock parameters and P-wave, S-wave velocities and Vp/Vs ratio. The investigations suggest that the P-wave and S-wave velocities decrease with increasing the fracture parameters, while the Vp/Vs ratio increases with decreasing the fracture parameters.

Furthermore the results of the experimental studies were applied on the seismic refraction tomography data acquired in a great measurements campaign undertaken in the Adriatic salentina coast (south Italy) in order to monitor the coastal erosion.

The geophysical results, using the polynomial relationships between the fractured rock parameters and P-wave velocity, are in good agreement with the geomorphological and geological results.  相似文献   

94.
Natural analogue investigations aim to understand key phenomena and processes in natural systems related to those expected to occur in radioactive waste repositories. One of the key applications of natural analogue studies has been the possibility to test the geochemical models to be used to describe the migration of radionuclides in a future radioactive waste repository system. To this end, several geochemical modelling testing exercises (commonly denoted as blind predictive modelling, BPM) have formed an integral part of these studies over the last decade.

We have reviewed, discussed and compared the results obtained from geochemical modelling BPM exercises carried out within six natural analogue studies: Poços de Caldas, Cigar Lake, Maqarin, El Berrocal, Oklo and Palmottu. To make this comparison meaningful, we present the main geochemical characteristics of each site in order to highlight the most relevant mineralogical and hydrochemical differences. The elements selected for discussion are: Sr, Ba, Sn, Pb, Se, Ni, Zn, REEs, Th and U. We have based our discussion on the results obtained from the calculated aqueous speciation as well as by comparing solubility calculations with the actually observed concentrations.

Results can be differentiated into two categories of elemental behaviour:

1. those elements like Th and U under reducing conditions that can be fairly well described by assuming solubility control exerted by pure solid phases as their oxyhydroxides;

2. elements such as Sr, Zn, REEs and U under oxidising conditions for which the association to major geochemical components of the system must be considered in order to explain their concentrations in groundwaters.

Additionally, we discuss the main improvements made to the thermodynamic databases and the geochemical calculation methodologies due to the BPM exercises. Furthermore, the most important characterisation geochemical data needed to complete predictive solubility and speciation calculations are identified.  相似文献   

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96.
The concentration and distribution of dissolved nitrogenous compounds was studied in the Greenland Sea in June 1991. Dissolved organic (DON) and inorganic nitrogen (DIN) were determined in seawater of different origin and depth. Dissolved organic matter was isolated on XAD-2 resin and fractionated into its non-humic hydrophilic (H1), and so-called humic components (hydrophobic acid, HbA, and hydrophobic neutral, HbN). From all fractions the DON content was subsequently determined. Total DON concentrations were about 5 μmol Ni−1 in the surface and 3 μmol NI−1 below depths of 150–200 m. DIN varied between 1.5 and 1.6 μmol NI−1. There was a highly significant inverse correlation (r = −0.75) between DON and DIN suggesting a close coupling in the uptake and release of the different forms of nitrogen. The mean DON concentrations of the XAD-fractions were for HI = 2.3 μmol Ni−1, for HbA = 0.8 μmol NI and for HbN = 1.0 μmol NI−1. The average percentage contributions were, respectively, 56%, 19% and 25%. This means that about 56% of the total DON does not belong to the ‘humic fraction’. The HbN fraction was evenly distributed in the water column, without any obvious relationship with water masses, depth, or nutrient status. In contrast, the HbA fraction showed a significant correlation with total DON.  相似文献   
97.
98.
Understanding the distribution and abundance of organisms can be exceedingly difficult for pelagic fish species that live in estuarine environments. This is particularly so for fish that cannot be readily marked and released or otherwise tracked, such as the diminutive delta smelt, Hypomesus transpacificus, endemic to the San Francisco Estuary. The environmental factors that influence their distribution operate at multiple scales, from daily tidal cycles and local perceptual fields to seasonal and annual changes in dominant environmental gradients spanning the entire San Francisco Estuary. To quantify scale-specific patterns and factors shaping the spatiotemporal abundance dynamics of adult delta smelt, we fit a suite of models to an extensive, spatially resolved, catch survey time series from 13 annual cohorts. The best model included cohort-specific abundance indicators and daily mortality rates, a regional spatial adjustment, and haul-specific environmental conditions. The regional adjustment identified several density hot spots that were persistent across cohorts. While this model did include local environmental conditions, the gain in explained variation was relatively slight compared to that explained by the regional adjustment. Total abundance estimates were derived by multiplying habitat volume by catch density (design-based) and modeled density (model-based), with both showing severe declines in the population over the time period studied. The design-based approaches had lower uncertainty but potentially higher bias. We discuss the implications of our results for advancing the science and improving management of delta smelt, and future data collection needs.  相似文献   
99.
Maderas volcano is a small, andesitic stratovolcano located on the island of Ometepe in Lake Nicaragua, Nicaragua, with no record of historic activity. Twenty-one samples were collected in 2010 from lava flows of Maderas. The selected samples were analyzed for whole-rock geochemistry using ICP-AES and/or were dated using the 40Ar/39Ar method. The results of these analyses were combined with previously collected data from Maderas as well as field observations to determine the eruptive history of the volcano and create a geologic map. The results of the geochemical analyses indicate that Maderas has higher concentrations of alkalies than most Nicaraguan and Costa Rican volcanoes including its nearest neighbor, Concepción volcano. It is also different from Concepción in that it displays higher incompatible elements. Determined age dates range from 179.2?±?16.4?ka to 70.5?±?6.1?ka. Based on these ages and the geomorphology of the volcano which is characterized by a bisecting graben, it is proposed that Maderas experienced two generations of development: initial build-up of the older cone including pre-graben lava flows, followed by post-graben lava flows. The ages also indicate that Maderas is markedly older than Concepción which is historically active. Volcanic hazards were also assessed. The 40Ar/39Ar ages indicate that Maderas has likely been inactive for tens of thousands of years and future volcanic eruptions are not considered an immediate hazard. However, earthquake and lahar hazards exist for the communities around the volcano. The steep slopes of the eroded older cone are the most likely sources of lahar hazards.  相似文献   
100.
High-voltage transmission networks represent a large electrical circuit just above the ground subjected to a number of transient overcharges of various kinds, some of which may lead to failures. Some failures might be related to anomalies of the geophysical environment. We have analyzed one unprecedented long series of transmission grid failures (9?years) on high-voltage networks located in S?o Paulo state, southeastern Brazil, from 1998 to 2006, which includes an important fraction of the past solar activity cycle 23. Ninety-five distinct failure causes were given by the power line operator to explain the transmission grid shut downs. Most failures were attributed to atmospheric discharges, corresponding to 1,957 failures out of a total of 4,572 for the whole period at 138?kV, and 170 out of 763 at 440?kV, respectively. They correspond to less than one ten thousandth of the actual number of atmospheric discharges recorded in the same area, demonstrating the grid’s high resilience to breakdowns due to lightning. A clear concentration of failures in the region’s thunderstorm season has been found. A significant 67 and 77?% reduction in the number of failure rates per year has been found for the 138 and 440?kV grids, respectively, for the period studied, in good correspondence with the decay in the sunspot numbers. No obvious correlation was found between power failures and the planetary index of geomagnetic activity or major geomagnetic storms in the period, either on short or on long time scales. Assuming that the dependence of the electrosphere/ionosphere-ground coupling on the external geophysical environment plays a major role in explaining the reduction in power failures as the solar cycle wanes, it is suggested that the increase in atmosphere conductivity caused by the larger cosmic ray flux then reduces the threshold voltage required to produce lightning strokes, so reducing their effectiveness in disrupting high-voltage power lines.  相似文献   
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