EPR investigation of the methyl radical,the hydrogen atom and carbon oxide radicals in Maxixe-type beryl     

Lars Olov Andersson 《Physics and Chemistry of Minerals》2008,35(9):505-520

The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1 signal typical for the CH₃ radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g _// = 2.00263, g _⊥ = 2.00249 and A_// = 2.288 mT, A_⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A ₀ = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g _// = 2.00265, g _⊥ = 2.00625 and A_// = 0.895 mT, A_⊥ = 0.885 mT, could come from a HCO₃ radical. One narrow and easily saturated signal with g _// = 2.00227 and g _⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g _// = 2.0017 and g _⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise from a carbon dioxide radical, which rotates around its symmetry axis.  相似文献   

An assessment of Greenland walrus populations     

Witting  Lars; Born  Erik W. 《ICES Journal of Marine Science》2005,62(2):266-284

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A framework for making qualities of indicators transparent     

Hauge  Kjellrun Hiis; Olsen  Erik; Heldal  Hilde Elise; Skjoldal  Hein Rune 《ICES Journal of Marine Science》2005,62(3):552-557

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Effects on UDP glucuronosyl transferase, glutathione transferase, DT-diaphorase and glutathione reductase activities in rainbow trout liver after long-term exposure to PCB     

Lars Frlin  Sonja Blom  Malin Celander  Joachim Sturve 《Marine environmental research》1996,42(1-4)

In the present study, long-term exposure to PCB resulted in marked induction of the xenobiotic biotransformation enzymes UDP glucuronosyl transferase, glutathione transferase and DT-diaphorase (measured as menadione reductase and DCPIP reductase) in rainbow trout 15 or 20 weeks post-injection during the experimental period. The increase of the phase II enzymes were paralleled by a marked increase of the glutathione reductase activity. These results indicate that prolonged exposure to PCB results in increased production of organo-radicals.  相似文献   

Partial isolation and purification of cadmium-binding proteins from rainbow trout liver     

Carl Haux  Per Erik Olsson  Inger Thorsen  Lars Frlin  ke Larsson 《Marine environmental research》1984,14(1-4)

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Drag force on a circular cylinder in unseparated laminar high Reynolds number nonlinear random oscillatory flow     

Dag Myrhaug  Hanne T. Wist  Lars Erik Holmedal 《Ocean Engineering》2003,30(17):2227-2238

The stochastic properties of the drag force maxima on a circular cylinder subjected to nonlinear random waves are investigated. Unseparated laminar high Reynolds number flow is considered. A simplified approach based on second order Stokes waves is presented, including the sum-frequency effect only. It is demonstrated how a drag force formula valid for regular linear waves can be used to find the cumulative distribution function of individual drag force maxima for nonlinear irregular waves. Here the [Wang, 1968] drag force coefficient is used.  相似文献   

Numerical method for computing the power absorbed by a phase-controlled point absorber     

Lars Chr. Iversen 《Applied Ocean Research》1982,4(3):173-180

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A random walk model for simulating simultaneous currents at several depths     

Richard B. Olsen 《Ocean Engineering》1987,14(6)

Empirical orthogonal function (EOF) analysis is used in conjunction with Markov chains to generate simultaneous current time series at several depths with a random walk model. Duration statistics and probability distributions for EOF modes obtained from real data are used to generate transition probability matrices for the random walk model. New time series of EOF modes are generated, and then combined to produce current time series. The technique has been tested on data from Haltenbanken. Statistical properties of real and simulated time series were compared. Results indicate that the model is acceptable as a tool in simulating current time series to be used in offshore operation models.  相似文献   

Eddy Diffusion Coefficients of Suspended Particulate Matter: Effects of Wind Energy Transfer and Stratification     

Lars Chresten Lund-Hansen  Morten Pejrup  Jens Valeur  Anders Jensen 《Estuarine, Coastal and Shelf Science》1994,38(6)

Gross sedimentation rates (GSR) have been measured using sediment traps placed at nine different levels above the bed (0·3, 0·5, 0·8, 1·0, 2·0, 4·0, 6·0, 8·0 and 10·0 m). The sediment traps were deployed for 1·25 years and recovered 28 times during the study period. Low average GSR values of 5·5 g m^-2 day^-1 were obtained at 10·0 m, and high average GSR values of 114·8 g m^-2 day^-1 were obtained at 0·3 m. An expression for the eddy diffusion coefficient of suspended particulate matter (K_s), based on the measured GSR is given. The expression has been used for modelling of K_s at the different trap levels above the bed. High values (≈42 cm² s^-1) of K_s were obtained at the upper traps, whereas low values (≈2 cm² s^-1) were obtained near the bed. Comparison between level of turbulent energy in terms of shear stress at the boundaries of the water column, i.e. from the wind and the bed flow, showed that wind energy exceeded that of the bed flow by a factor 16. At 5·0 m K_s was positively correlated (r=0·66) to the eddy diffusion coefficient of momentum (K_m) derived from the wind energy transfer to the water, giving an average β of 0·5 for K_s =βK_m. The density difference between surface and bottom waters has been designated a parameter of stratification, and is discussed in relation to variations of K_s and K_m .  相似文献   

Migration and survival of farmed Atlantic salmon (Salmo salar L.) released from two Norwegian fish farms   总被引：1，自引：0，他引：1  

Hansen  Lars P. 《ICES Journal of Marine Science》2006,63(7):1211-1217

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