Evolution of organic matter indicators in response to major environmental changes: The case of a formerly cut-over peat bog (Le Russey, Jura Mountains, France)     

Laure Comont  Fatima Laggoun-Dfarge  Jean-Robert Disnar 《Organic Geochemistry》2006,37(12):1736

To assess whether the biochemical characteristics of peat can provide clues for past ecosystem changes or not, a study was carried out combining elemental analysis, micro-morphological counts and neutral monosaccharide determination of peat organic matter (OM) and the dominant living plants from a formerly cut-over peat bog in the Jura Mountains. Peat profiles (up to 50 cm depth) from two distinctive zones (bare peat, FRA and a regenerating stage, FRC) were compared with the reference profile (FRD) taken from an unexploited area of the bog. The results show contrasting OM composition along the profiles. In the upper sections of the FRD and FRC profiles, high C/N ratios and sugar contents (in the same range as in the source plants) and the large predominance of well preserved plant tissues indicate good preservation of primary biological inputs. In contrast, in peat from the FRA profile and deeper levels of the FRC profile, lower C/N ratios, lower amounts of sugars and a predominance of amorphous OM and mucilage suggest more extensive OM degradation. These features delineate a clear threshold between an uppermost “new” regenerating peat section and an “old” catotelm peat below. Nevertheless, even in the latter, the sugar contents remain relatively high (>80 mg/g) compared with other organic and mineral soils. Analysis of typical peat-forming plants and of bulk peat and fine grained fractions allowed identification of the following source indicators: xylose and arabinose for Cyperaceae; rhamnose, galactose and mannose for mosses; and ribose (and to a lesser extent, hemicellulosic glucose) possibly for microbial synthesis.  相似文献   

Environmental perceptions and practices of livestock keepers on the Namaqualand Commons challenge conventional rangeland management   总被引：1，自引：1，他引：1  

Nicky Allsopp  Catherine Laurent  Laure M.C. Debeaudoin  M. Igshaan Samuels   《Journal of Arid Environments》2007,70(4):740

In South Africa, interventions in communal rangelands proposed by most agriculture-sector institutions are still dominated by the belief that communal herders have little technical skills and by the tenets of “the tragedy of the Commons”, assuming that individual livestock keepers are selfish, norm free, and aiming at maximising short-term offtake and that there is no consistent management of the commons. In this study we show that practices of a diversity of livestock keepers on the Leliefontein Commons of Namaqualand are at odds with this viewpoint: access to rangeland and its use are structured by collective norms and concerns regarding both the sharing of resources and their long-term sustainability. We also show that part of the management of the commons relies on grazing practices which involve tacit and formalised technical knowledge that can be described and modelled. Livestock keepers assess the heterogeneity of the grazing quality of the commons. They are aware of the toxicity and unpalatability of some plants, of the way this differs according to the amount ingested and the availability of other forage, and of the variations of these two factors over seasons of grazing. They classify grazing areas and decide on daily grazing routes according to a complex set of criteria. Carrying capacity of each area is not considered as a fixed parameter but rather as a variable dependant on rainfall. Seasonal movements between areas are designed accordingly. These findings offer a new perspective for research agendas on technical models and extension measures for communal rangeland management particularly in arid and semi-arid areas.  相似文献   

Long-term neutralisation potential of red mud bauxite with brine amendment for the neutralisation of acidic mine tailings     

M. Paradis  J. Duchesne  A. Lamontagne  D. Isabel 《Applied Geochemistry》2007

Acid mine drainage is an environmental problem produced when sulphide in mine tailings dams comes in contact with O₂, bacteria and water. Oxidation occurs and a succession of reactions is responsible for producing acid and metals in the environment. One solution proposed is to use red mud bauxite (RMB) that is very alkaline to neutralise acidic tailings. Previous experiments showed that RMB has a good neutralisation capacity for a short time, but the long-term neutralisation potential is uncertain. So brine was added to RMB to verify if it can improve long-term alkalinity retention of RMB. Some authors have presented results where seawater or other natural or artificial Ca- and Mg-rich brines were used with RMB to convert the basicity (mainly NaOH) and other soluble alkalinity into low solubility hydroxide, carbonate and hydroxycarbonate minerals. Results showed that neutral pH conditions were maintained over the entire test for RMB and a mixture of RMB with brine. Addition of brine to RMB slightly lowered the pH compared to RMB alone. RMB alone lost a lot of dissolved alkalinity at the beginning of the test. Most of the alkalinity was lost in water after a few flushes for RMB samples. The addition of brine helped to keep neutralisation potential over more cycles of leaching.  相似文献   

Technosols made with various urban wastes showed contrasted performance for tree development during a 3-year experiment     

Patrice Cannavo  René Guénon  Gilles Galopin  Laure Vidal-Beaudet 《Environmental Earth Sciences》2018,77(18):650

Vegetation in urban areas is generally living in a stress-inducing environment. Sustaining good soil quality is crucial to improve tree development and heath in such (artificial) environment. This study investigates the dynamics of the physico-chemical properties of Technosol, and compares tree development performances in various waste mixtures. A 3-year experiment was conducted with Acer platanoïdes L. grown in three distinct constructed soils, in three replicates, in 0.480-m³ lysimeters in Angers (France). Four combinations of artefacts were studied either as “growing material” (GM) or “structural material” (SM). Three different SMs were used: (1) a mixture of fine mineral material, demolition rubble and green waste (SM-DR/GW), (2) a mixture of fine mineral material, track ballast and sewage sludge (SM-TB/SS), and (3) the SM currently used by Angers city for green space settlements (SM-CT). Waste characteristics and mixing proportions both affected tree development. Physical properties were not a limiting factor for tree development, despite a relatively low soil water reservoir due to high stone content. Moreover, the chemical properties of the materials, more particularly low water pH and CEC, led to poor tree development in SM-CT, whereas the other two SMs did not affect tree development. SM-TB/SS was the most suitable constructed soil after 3 years because it exhibited satisfactory soil nutrient contents that promoted the best tree crown quality. Waste mixtures can sustain soil functions for tree development. As for urban street tree pits that are 2–8 m³ in volume, soil water, and nutrient autonomy should satisfactorily sustain tree development.  相似文献   

Sustained Ability of a Natural Microbial Community to Remove Nitrate from Groundwater     

Charles J. Paradis  John I. Miller  Ji-Won Moon  Sarah J. Spencer  Lauren M. Lui  Joy D. Van Nostrand  Daliang Ning  Andrew D. Steen  Larry D. McKay  Adam P. Arkin  Jizhong Zhou  Eric J. Alm  Terry C. Hazen 《Ground water》2022,60(1):99-111

Microbial-mediated nitrate removal from groundwater is widely recognized as the predominant mechanism for nitrate attenuation in contaminated aquifers and is largely dependent on the presence of a carbon-bearing electron donor. The repeated exposure of a natural microbial community to an electron donor can result in the sustained ability of the community to remove nitrate; this phenomenon has been clearly demonstrated at the laboratory scale. However, in situ demonstrations of this ability are lacking. For this study, ethanol (electron donor) was repeatedly injected into a groundwater well (treatment) for six consecutive weeks to establish the sustained ability of a microbial community to remove nitrate. A second well (control) located upgradient was not injected with ethanol during this time. The treatment well demonstrated strong evidence of sustained ability as evident by ethanol, nitrate, and subsequent sulfate removal up to 21, 64, and 68%, respectively, as compared to the conservative tracer (bromide) upon consecutive exposures. Both wells were then monitored for six additional weeks under natural (no injection) conditions. During the final week, ethanol was injected into both treatment and control wells. The treatment well demonstrated sustained ability as evident by ethanol and nitrate removal up to 20 and 21%, respectively, as compared to bromide, whereas the control did not show strong evidence of nitrate removal (5% removal). Surprisingly, the treatment well did not indicate a sustained and selective enrichment of a microbial community. These results suggested that the predominant mechanism(s) of sustained ability likely exist at the enzymatic- and/or genetic-levels. The results of this study demonstrated the in situ ability of a microbial community to remove nitrate can be sustained in the prolonged absence of an electron donor.  相似文献   

Single-Well Injection-Drift Test to Estimate Groundwater Velocity     

Charles Paradis  Nathan Van Ee  Kendyl Hoss  Cullen Meurer  Aaron Tigar  Paul Reimus  Raymond Johnson 《Ground water》2022,60(4):565-570

A simple algebraic equation is presented here to estimate the magnitude of groundwater velocity based on data from a single-well injection-drift test thereby eliminating the time-consuming and costly extraction phase. A volume of tracer-amended water was injected by forced-gradient into a single well followed by monitoring of the conservative solute tracers under natural-gradient conditions as their upgradient portions drifted back through the well. The breakthrough curve data from the single well during the drift phase was analyzed to determine the mean travel times of the tracers. The estimated mean upgradient travel distance back through the single well and the mean travel times of the tracers were used in a simple algebraic equation to estimate groundwater velocity. The groundwater velocity based on the single-well injection-drift test was estimated to be approximately 0.64 ft per day. Two transects of observation wells were used to monitor the natural-gradient tracer transport downgradient of the injection well. The one-dimensional, or dual-well, transport of the tracer from the injection well to the nearest downgradient observation well indicated that the groundwater velocity was 0.55 ft per day. The two-dimensional, or multi-well, transport of the center of mass of the tracers indicated that the groundwater velocity was 0.60 ft per day; the dual- and multi-well results were in excellent agreement with those from the single-well and validated the simple algebraic equation. The new single-well method presented here is relatively simple, rapid, and does not require an extraction phase.  相似文献   

Apatite Reference Materials for SIMS Microanalysis of Isotopes and Trace Elements     

Allen K. Kennedy  Jörn-Frederik Wotzlaw  James L. Crowley  Mark Schmitz  Urs Schaltegger  Benjamin Wade  Laure Martin  Cristina Talavera  Bryant Ware  Thi Hao Bui 《Geostandards and Geoanalytical Research》2023,47(2):373-402

Twelve apatite samples have been tested as secondary ion mass spectrometry (SIMS) reference materials. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis shows that the SLAP, NUAN and GR40 apatite gems are internally homogeneous, with most trace element mass fractions having 2 standard deviations (2s) ≤ 2.0%. BR2, BR5, OL2, AFG2 and AFB1, which have U > 63 μg g^-1, ²⁰⁶Pb/²⁰⁴Pb > 283, and homogeneous SIMS U-Pb data, have respective isotope dilution thermal ionisation mass spectrometry (ID-TIMS) ages of 2053.83 ± 0.21 Ma, 2040.34 ± 0.09 Ma, 868.87 ± 0.25 Ma, 478.71 ± 0.22 Ma and 473.25 ± 0.09 Ma. Minor U-Pb heterogeneity exists and accurate SIMS results require correction with the 3D Concordia-constrained common Pb composition. Among the studied samples, AFG2 and BR5 are the most homogeneous U-Pb reference materials. The SIMS sulfur isotopic compositions of eight of the apatites shows they are homogeneous, with 2s for both 10³δ³⁴S and 10³δ³³S < 0.55‰. One apatite, BR96, has Δ³³S = -0.36 ± 0.2‰. The apatite samples have ID-TIMS ⁸⁷Sr/⁸⁶Sr between 0.704214 ± 0.000030 and 0.723134 ± 0.000035.  相似文献   

Reworking of intra-oceanic rocks in a deep sea basin: example from the Bou-Maiza complex (Edough massif,eastern Algeria)     

Mehdi Mechati  Dalila Hammor  Delphine Bosch  Olivier Bruguier  Laure Fernandez 《International Geology Review》2018,60(4):464-478

Metagabbros and amphibolites exposed in the Bou-Maïza area of the Edough massif (northeast Algeria) are described in detail. Field and petro-structural observations point to the syn-sedimentary emplacement of gabbros as clasts, blocks and lenses of polymictic gabbroic breccias. Associated amphibolites display fine-scale parallel sedimentary bedding and represent mafic epiclastites, litharenites and mafic greywackes. The mafic beds and lenses are intercalated with aluminous pelitic schists of continental origin, quartzite and marble. It is concluded that all mafic rocks from this locality derive from the erosion of an oceanic plutono-volcanic complex of MORB affinity that was reworked in a block matrix mélange and emplaced as turbidites and debris flows during the Mesozoic. We propose a convergent plate margin setting for these formations connected with the subducted Calabrian branch of the Tethyan slab.  相似文献   

The oxygen isotope composition of Karoo and Etendeka picrites: High δ18O mantle or crustal contamination?     

Chris Harris  Petrus le Roux  Ryan Cochrane  Laure Martin  Andrew R. Duncan  Julian S. Marsh  Anton P. le Roex  Cornelia Class 《Contributions to Mineralogy and Petrology》2015,170(1):1-24

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The world-class Howard’s Pass SEDEX Zn-Pb district,Selwyn Basin,Yukon. Part I: trace element compositions of pyrite record input of hydrothermal,diagenetic, and metamorphic fluids to mineralization     

Michael G. Gadd  Daniel Layton-Matthews  Jan M. Peter  Suzanne J. Paradis 《Mineralium Deposita》2016,51(3):319-342

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