Enrichissement en uranium authigène dans les sédiments glaciaires de l'océan AustralEnrichments in authigenic uranium in glacial sediments of the Southern Ocean     

Laurent Dezileau  Gilles Bareille  Jean-Louis Reyss 《Comptes Rendus Geoscience》2002,334(14):1039-1046

Four sediment cores from the Polar frontal zone and the Antarctic zone in the Indian sector of the Southern Ocean present an increase of authigenic uranium during glacial periods. We show that this increase in uranium is due to a combination of (i) an increase in the lateral transport of organic matter, (ii) a decrease in the oxygen in deep waters, and (iii) a process of diagenesis. It appears that uranium concentration cannot be used as a proxy of palaeoproductivity in the Southern Ocean, as previously suggested by Kumar et al. in 1995. To cite this article: L. Dezileau et al., C. R. Geoscience 334 (2002) 1039–1046.  相似文献   

Provenance analysis and tectonic setting of the Ordovician clastic deposits in the southern Puna Basin, NW Argentina   总被引：9，自引：0，他引：9  

Udo Zimmermann  Heinrich Bahlburg† 《Sedimentology》2003,50(6):1079-1104

Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Q_t89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Q_t33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Q_t24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The ε_{Nd(t = sed)} values scatter around −11 to −9. The calculated Nd-T_DM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average ε_{Nd(t = sed)} values are less negative at −5·1, and Nd-T_DM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (ε_{Nd(t = sed)} = −3 to −1; T_DM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.  相似文献   

Foliation fields and 3D cartography in geology: Principles of a method based on potential interpolation   总被引：4，自引：0，他引：4  

Christian Lajaunie  Gabriel Courrioux  Laurent Manuel 《Mathematical Geology》1997,29(4):571-584

A modeling method that takes into account known points on a geological interface and plane orientation data such as stratification or foliation planes is described and tested. The orientations data do not necessarily belong to one of the interfaces but are assumed to sample the main anisotropy of a geological formation as in current geological situations. The problem is to determine the surfaces which pass through the known points on interfaces and which are compatible with the orientation data. The method is based on the interpolation of a scalar field defined in the space the gradient in which is orthogonal to the orientations, given that some points have the same but unknown scalar value (points of the same interface), and that scalar gradient is known on the other points (foliations). The modeled interfaces are represented as isovalues of the interpolated field. Preliminary two-dimensional tests carried-out with different covariance models demonstrate the validity of the method, which is easily transposable in three dimensions.  相似文献   

Occurence of abundant diradicaloid moieties in the insoluble organic matter from the Orgueil and Murchison meteorites: a fingerprint of its extraterrestrial origin?     

Laurent Binet  Didier Gourier  François Robert 《Geochimica et cosmochimica acta》2004,68(4):881-891

The highly aromatic structure of the macromolecular organic matter (OM) of the Murchison and Orgueil meteorites was recently shown to contain free organic radicals which are concentrated in micro-regions in contrast with terrestrial samples which always show an homogeneous distribution of radicals. An additional signature is revealed, in the present study, by the evolution of the radical concentration with temperature. Whereas in terrestrial samples, this concentration is independent of temperature (Curie magnetism), a significant increase is observed above 150 K in the two meteorites. Based on the electronic structure of organic radicals, calculated by Extended Hückel and Density Functional methods, this behavior was assigned to the occurrence of diradicaloid moieties hosted by aromatic structures of 10 to 15 rings and having a quinoidal structure. They represent 40 and 25% of the total radicals in Orgueil and Murchison, respectively. The search for the cosmochemical interpretation of this unique observation should open a new field of experimental investigations.  相似文献   

Magma flow in the East Greenland dyke swarm inferred from study of anisotropy of magnetic susceptibility: magmatic growth of a volcanic margin   总被引：2，自引：0，他引：2  

Jean-Paul Callot  Laurent Geoffroy 《Geophysical Journal International》2004,159(2):816-830

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Influence of the Neotethys rifting on the development of the Dampier Sub-basin (North West Shelf of Australia), highlighted by subsidence modelling     

Laurent Langhi  Gilles D. Borel 《Tectonophysics》2005,397(1-2):93

During the Late Palaeozoic and the Mesozoic, the development and evolution of the North West Shelf of Australia have been mostly driven by rifting phases associated with the break-up of Gondwana. These extensional episodes, which culminated in the opening of the Neotethys Ocean during the Permo-Carboniferous and a series of abyssal plains during the Jurassic-Cretaceous, are characterised by different stress regimes and modes of extension, and therefore had distinctive effects on the margin, and particularly on the Northern Carnarvon Basin.Interpretation of 3D and 2D seismic data enables a structural and stratigraphic analysis of the Late Palaeozoic sediments deposited in the proximal part of the Dampier Sub-basin (Mermaid Nose). Based on their seismic characters, stratigraphic relationship, internal patterns, lateral continuity, and architecture, these units are associated here with the Pennsylvanian?–Early Sakmarian glaciogenic Lyons Group and the Sakmarian–Artinskian Callytharra Formation. The former were deposited in a half-graben whose development is associated with the onset of the Neotethys rifting, and the latter is characterised by restricted deposition, inversion of prograding patterns, and uplift.The integration of seismo-stratigraphic characterisation of the Late Palaeozoic sequences and Mesozoic data from one exploration well (Roebuck-1) enables the construction of subsidence curves for the Mermaid Nose and the interpretation of its geohistory.The tectonic subsidence curves show a striking Permo-Carboniferous rifting phase related to the Neotethys rifting and a discrete Late Jurassic–Early Cretaceous event coeval with the opening and the spreading of the Argo Abyssal Plain.This result points out the predominance of the effects of the Permo-Carboniferous Neotethys episode, whereas the extension related to the Argo Abyssal Plain rifting that occurred later and closer to the studied area, had only limited effects on the subsidence of the proximal Dampier Sub-basin. Therefore, it supports a tectonic model with two distinct modes of extension for the Late Palaeozoic (widespread) and the Mesozoic (localised) rifting phases.  相似文献   

Eocene-Pliocene time scale and stratigraphy of the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB)     

Jean-Pierre Berger  Bettina Reichenbacher  Damien Becker  Matthias Grimm  Kirsten Grimm  Laurent Picot  Andrea Storni  Claudius Pirkenseer  Andreas Schaefer 《International Journal of Earth Sciences》2005,94(4):711-731

We present a general stratigraphic synthesis for the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB) from Eocene to Pliocene times. The stratigraphic data were compiled both from literature and from research carried out by the authors during the past 6 years ; an index of the stratigraphically most important localitites is provided. We distinguish 14 geographical areas from the Helvetic domain in the South to the Hanau Basin in the North. For each geographical area, we give a synthesis of the biostratigraphy, lithofacies, and chronostratigraphic ranges. The relationships between this stratigraphic record and the global sea-level changes are generally disturbed by the geodynamic (e.g., subsidence) evolution of the basins. However, global sea-level changes probably affected the dynamic of transgression–regression in the URG (e.g., Middle Pechelbronn Beds and Serie Grise corresponding with sea-level rise between Ru1/Ru2 and Ru2/Ru3 sequences, respectively) as well as in the Molasse basin (regression of the UMM corresponding with the sea-level drop at the Ch1 sequence). The URGENT-project (Upper Rhine Graben evolution and neotectonics) provided an unique opportunity to carry out and present this synthesis. Discussions with scientists addressing sedimentology, tectonics, geophysics and geochemistry permitted the comparison of the sedimentary history and stratigraphy of the basin with processes controlling its geodynamic evolution. Data presented here back up the palaeogeographic reconstructions presented in a companion paper by the same authors (see Berger et al. in Int J Earth Sci 2005).  相似文献   

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux     

Zakaria Boujamlaoui  Thierry Bariac  Philippe Biron  Laurent Canale  Patricia Richard 《Comptes Rendus Geoscience》2005,337(6):589-598

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).  相似文献   

Nouvelles données pour l’histoire des fluctuations holocènes du niveau du lac de Neuchatel (Suisse): la séquence sédimentaire de Marin-Les Piécettes     

Michel Magny  Matthieu Honegger et Laurent Chalumeau 《Eclogae Geologicae Helvetiae》2005,98(2):249-259

Resume. Les fouilles archéologiques réalisées de 1998 à 2002 sur le site néolithique de Marin-Les Piécettes sur la rive nord-ouest du lac de Neuchatel ont offert l’opportunité d’observer deux séquences sédimentaires intéressantes pour la reconstitution des variations holocènes du niveau du lac, en particulier au cours de la période correspondant au changement de cours de l’Aar en direction du nord-est, vers 5650–5500 cal BP. La géométrie des corps sédimentaires et les changements lithologiques permettent de reconna?tre plusieurs phases majeures de bas niveaux relatifs du plan d’eau vers 6870, 5660, 5060–3990, 3580, 2280, 1640 et 1170 cal BP. Le site néolithique de Marin-Les Piécettes s’est développé vers 5454–5433 cal BP à la faveur d’un court épisode de bas niveau du lac qui a interrompu une importante phase de haut niveau au début du Subboréal. Les événements paléohydrologiques identifiés à Marin-Les Piécettes apparaissent cohérents avec ceux reconstitués sur le site de Montilier au bord du lac de Morat, ainsi qu’avec les variations paléohydrologiques reconstituées à partir des lacs du Jura, du Plateau suisse et des Préalpes du Nord fran?aises. Ceci suggère qu’ils témoignent d’un signal climatique. La séquence sédimentaire de Marin-Les Piécettes met enfin en évidence la formation d’un cordon littoral sur la rive nord-ouest du lac juste après 5660 cal BP. Manuscrit re?u le 22 septembre 2004 Révision acceptée le 11 mars 2005  相似文献   

Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite     

Mariëtte Wolthers  Laurent Charlet  Peter R. van der Linde 《Geochimica et cosmochimica acta》2005,69(14):3483-3492

Arsenate, As(V), sorption onto synthetic iron(II) monosulfide, disordered mackinawite (FeS), is fast. As(V) sorption decreases above the point of zero surface charge of FeS and follows the pH-dependent concentration of positively charged surface species. No redox reaction is observed between the As(V) ions and the mineral surface over the time span of the experiments. This observation shows that As(V) dominantly forms an outer-sphere complex at the surface of mackinawite. Arsenite, As(III), sorption is not strongly pH-dependent and can be expressed by a Freundlich isotherm. Sorption is fast, although slower than that of As(V). As(III) also forms an outer-sphere complex at the surface of mackinawite. In agreement with previous spectroscopic studies, complexation at low As(V) and As(III) concentration occurs preferentially at the mono-coordinated sulfide edge sites. The K_d (L g⁻¹) values obtained from linear fits to the isotherm data are ∼9 for As(V) and ∼2 for As(III). Stronger sorption of As(V) than As(III), and thus a higher As(III) mobility, may be reflected in natural anoxic sulfidic waters when disordered mackinawite controls arsenic mobility.  相似文献