The oxidation state of manganese in marine sediments and ferromanganese nodules     

James W Murray  Laurie S Balistrieri  Barbara Paul 《Geochimica et cosmochimica acta》1984,48(6):1237-1247

Marine sediments and ferromanganese nodules from the Pacific Ocean have been analyzed for the $\text{O}\text{Mn}$ ratio of solid manganese. We tested six chemical methods and concluded that the iodometric and oxalate methods were equivalent and were the best choice in terms of accuracy and precision on natural samples. We choose the iodometric method for most of our analyses because the oxalate procedure is a method of differences.The ferromanganese nodules that we analyzed were all from MANOP site H and had $\text{Mn}\text{Fe}$ ratios that ranged from 5.6 to 70. These nodules were invariably highly oxidized with $\text{O}\text{Mn}$ values ranging from 1.90 to 2.00. Our most precise analyses suggest that less than 1% of the total manganese is present as Mn(II).We also analyzed red clay and hemipelagic sediments from the eastern tropical Pacific (Baja borderland and MANOP site H) and carbonate ooze samples from the equatorial Pacific. These sediments are also highly oxidized ($\text{O}\text{Mn}\text{= 1.90 to 2.00}$) except when Mn(II) appears in the interstitial water. As dissolved Mn(II) increases the value of the $\text{O}\text{Mn}$ ratio in the solid phase decreases. The $\text{O}\text{Mn}$ ratio decreases to values as low as 1.40. This decrease appears to be due to a decrease in oxidized manganese by reduction, however, an increase in reduced manganese in the solid sediments by adsorption or MnCO₃ formation can not be ruled out in all cases.  相似文献   

Disaster Management and Community Planning, and Public Participation: How to Achieve Sustainable Hazard Mitigation   总被引：5，自引：3，他引：5  

Laurie Pearce 《Natural Hazards》2003,28(2-3):211-228

The paper offers first a brief historical overview of disaster management planning. Second, it reviews Australian and American research findings and show that they urge the field of disaster management to shift its focus from response and recovery to sustainable hazard mitigation. It is argued that in order for this shift to occur, it is necessary to integrate disaster management and community planning. Current practice seldom reflects such a synthesis, and this is one of the reasons why hazard awareness is absent from local decision-making processes. Third, it is asserted that if mitigative strategies are to be successfully implemented, then the disaster management process must incorporate public participation at the local decision-making level. The paper concludes with a case study of California's Portola Valley, which demonstrates that when public participation is integrated into disaster management planning and community planning, the result is sustainable hazard mitigation.  相似文献   

The Re-Os Isotopic System: A Review of Analytical Techniques   总被引：4，自引：0，他引：4  

Laurie Reisberg  Thomas Meisel 《Geostandards and Geoanalytical Research》2002,26(3):249-267

Over the past twenty years, successive technological advances have transformed the Re-Os isotopic system into one of the most powerful tools in isotope geochemistry. We present here a brief historical review of these advances and then describe and compare the methods most commonly used today. Our goal is to facilitate the choice of the analytical method best adapted to each specific scientific problem and sample type.  相似文献   

Néotectonique affectant les dépôts marins tyrrhéniens du littoral sud-est tunisien : implications pour les variations du niveau marin     

Samir Bouaziz  Younes Jedoui  Éric Barrier  Jacques Angelier 《Comptes Rendus Geoscience》2003,335(2):247-254

Pleistocene marine deposits of so-called Tyrrhenian age in southeastern Tunisia include two lithostratigraphic units of Last Interglacial (marine isotopic substage 5e). The lower unit culminates at about +3 m above the sea level; the upper unit with Strombus bubonius culminates at +5 m. Brittle deformations affected the upper unit. The analysis of fault-slip data sets reveals a post-Tyrrhenian N020°E trending compression, consistent with joint patterns. This event induced limited vertical movements, showing that at the northeastern edge of the Saharan Platform, the coastal area of the southern Tunisia remained relatively stable since at least the Last Interglacial.  相似文献   

青藏高原西北缘晚新生代的隆升特征——来自西昆仑山前盆地的沉积学证据   总被引：6，自引：0，他引：6  

司家亮  李海兵Laurie BARRIER Jerome VAN DER WOERD孙知明  裴军令潘家伟 《地质通报》2007,26(10):1356-1367

对西昆仑北缘山前盆地新生代沉积特征的研究结果表明,沿西昆仑山前发育的各沉积序列的垂向特征相似:古新世—中新世早期为石膏层、含瓣腮化石的石灰岩和紫红色较细粒的碎屑岩沉积,指示了海相和海陆过渡相较平静的沉积环境;中新世晚期—上新世初期开始出现陆相磨拉石,指示了陆相非平静的沉积环境,砾石的直径由下至上呈增大趋势,可能反映了西昆仑山体不断隆升,其间相对稳定的层段可能是构造运动间歇期或平稳期的沉积,指示了脉动式的隆升模式;磨拉石底部砾石的成分以沉积岩为主,向上火成岩和变质岩砾石逐渐增多,表明剥蚀程度不断加深。根据磨拉石建造的特征,判断剥蚀量和剥蚀强度自西向东有减小和变弱的趋势,可能暗示了西昆仑山晚新生代隆升有自西向东由强变弱的过渡特征。该结论与本区构造地貌学的研究结果一致。  相似文献   

Spatial correlation of shear-wave velocity in the San Francisco Bay Area sediments   总被引：1，自引：0，他引：1  

Eric M. Thompson  Laurie G. Baise  Robert E. Kayen 《Soil Dynamics and Earthquake Engineering》2007,27(2):144-152

Ground motions recorded within sedimentary basins are variable over short distances. One important cause of the variability is that local soil properties are variable at all scales. Regional hazard maps developed for predicting site effects are generally derived from maps of surficial geology; however, recent studies have shown that mapped geologic units do not correlate well with the average shear-wave velocity of the upper 30 m, V_s(30). We model the horizontal variability of near-surface soil shear-wave velocity in the San Francisco Bay Area to estimate values in unsampled locations in order to account for site effects in a continuous manner. Previous geostatistical studies of soil properties have shown horizontal correlations at the scale of meters to tens of meters while the vertical correlations are on the order of centimeters. In this paper we analyze shear-wave velocity data over regional distances and find that surface shear-wave velocity is correlated at horizontal distances up to 4 km based on data from seismic cone penetration tests and the spectral analysis of surface waves. We propose a method to map site effects by using geostatistical methods based on the shear-wave velocity correlation structure within a sedimentary basin. If used in conjunction with densely spaced shear-wave velocity profiles in regions of high seismic risk, geostatistical methods can produce reliable continuous maps of site effects.  相似文献   

The politics of publishing and print     

N. Laurie 《Geoforum》2004,35(2):141-142

  相似文献   

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset III: Hydro-geochemical monitoring of the Mule Hole catchment,south India     

Jean Riotte  Laurent Ruiz  Stéphane Audry  Benjamin Baud  Jean-Pierre Bedimo Bedimo  Laurie Boithias  Jean-Jacques Braun  Bernard Dupré  Jean-Louis Duprey  Mikael Faucheux  Christelle Lagane  Jean-Christophe Marechal  Hemanth Moger  Mandalagiri Subbarayappa Mohan Kumar  Harshad Parate  Olivier Ribolzi  Emma Rochelle-Newall  Buvaneshwari Sriramulu  Murari Varma  Muddu Sekhar 《水文研究》2021,35(5):e14196

Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km²), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.  相似文献   

Oxygen isotope and 26Al‐26Mg systematics of aluminum‐rich chondrules from unequilibrated enstatite chondrites     

Yunbin Guan  Gary R. Huss  Laurie A. Leshin  Glenn J. MacPherson  Kevin D. McKeegan 《Meteoritics & planetary science》2006,41(1):33-47

Abstract— Correlated in situ analyses of the oxygen and magnesium isotopic compositions of aluminum‐rich chondrules from unequilibrated enstatite chondrites were obtained using an ion microprobe. Among eleven aluminum‐rich chondrules and two plagioclase fragments measured for ²⁶Al‐²⁶Mg systematics, only one aluminum‐rich chondrule contains excess ²⁶Mg from the in situ decay of ²⁶Al; the inferred initial ratio (²⁶Al/²⁷Al)_o = (6.8 ± 2.4) × 10^?6 is consistent with ratios observed in chondrules from carbonaceous chondrites and unequilibrated ordinary chondrites. The oxygen isotopic compositions of five aluminum‐rich chondrules and one plagioclase fragment define a line of slope ?0.6 ± 0.1 on a three‐oxygen‐isotope diagram, overlapping the field defined by ferromagnesian chondrules in enstatite chondrites but extending to more ¹⁶O‐rich compositions with a range in δ¹⁸O of about ?12‰. Based on their oxygen isotopic compositions, aluminum‐rich chondrules in unequilibrated enstatite chondrites are probably genetically related to ferromagnesian chondrules and are not simple mixtures of materials from ferromagnesian chondrules and calcium‐aluminum‐rich inclusions (CAIs). Relative to their counterparts from unequilibrated ordinary chondrites, aluminum‐rich chondrules from unequilibrated enstatite chondrites show a narrower oxygen isotopic range and much less resolvable excess ²⁶Mg from the in situ decay of ²⁶Al, probably resulting from higher degrees of equilibration and isotopic exchange during post‐crystallization metamorphism. However, the presence of ²⁶Al‐bearing chondrules within the primitive ordinary, carbonaceous, and now enstatite chondrites suggests that ²⁶Al was at least approximately homogeneously distributed across the chondrite‐forming region.  相似文献   

Conceptual model of leachate migration in a granular aquifer derived from the integration of multi-source characterization data (St-Lambert,Canada)     

Laurie Tremblay  René Lefebvre  Daniel Paradis  Erwan Gloaguen 《Hydrogeology Journal》2014,22(3):587-608

Numerical models encompassing source zones and receptors, based on representative conceptual models and accounting for aquifer heterogeneity, are needed to understand contaminant migration and fate; however, aquifer characterization seldom provides the necessary data. This study aimed to develop a workflow for field characterization and data integration, which could: (1) be adapted to the definition of subwatershed-scale aquifer heterogeneity (over 10 km²) and (2) adequately support mass transport model development. The study involved the field investigation of a shallow granular aquifer in a 12-km² subwatershed in Saint-Lambert-de-Lauzon, Canada, in which a decommissioned landfill is emitting a leachate plume managed by natural attenuation. Using proven field methods, the characterization sequence was designed to optimize each method in terms of location, scale of acquisition, density and quality. The emphasis was on the acquisition of detailed indirect geophysical data that were integrated with direct hydraulic and geochemical data. This report focuses on the first qualitative and geostatistical data integration steps of the workflow leading to the development of a hydrogeological conceptual model. This is a prerequisite for further integration steps: prediction of hydrofacies and hydraulic conductivity (K), geostatistical simulations of K, studies of geochemical processes and numerical modeling.  相似文献