Geostandards and Geoanalytical Research Bibliographic Review 2013     

Klaus Peter Jochum  Uwe Nohl  Beate Schwager  Brigitte Stoll  Philip Suesser  Ulrike Weis 《Geostandards and Geoanalytical Research》2014,38(4):513-515

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Non‐Matrix‐Matched Calibration for the Multi‐Element Analysis of Geological and Environmental Samples Using 200 nm Femtosecond LA‐ICP‐MS: A Comparison with Nanosecond Lasers     

Klaus Peter Jochum  Brigitte Stoll  Ulrike Weis  Dorrit E. Jacob  Regina Mertz‐Kraus  Meinrat O. Andreae 《Geostandards and Geoanalytical Research》2014,38(3):265-292

LA‐ICP‐MS is one of the most promising techniques for in situ analysis of geological and environmental samples. However, there are some limitations with respect to measurement accuracy, in particular for volatile and siderophile/chalcophile elements, when using non‐matrix‐matched calibration. We therefore investigated matrix‐related effects with a new 200 nm femtosecond (fs) laser ablation system (NWRFemto200) using reference materials with different matrices and spot sizes from 10 to 55 μm. We also performed similar experiments with two nanosecond (ns) lasers, a 193 nm excimer (ESI NWR 193) and a 213 nm Nd:YAG (NWR UP‐213) laser. The ion intensity of the 200 nm fs laser ablation was much lower than that of the 213 nm Nd:YAG laser, because the ablation rate was a factor of about 30 lower. Our experiments did not show significant matrix dependency with the 200 nm fs laser. Therefore, a non‐matrix‐matched calibration for the multi‐element analysis of quite different matrices could be performed. This is demonstrated with analytical results from twenty‐two international synthetic silicate glass, geological glass, mineral, phosphate and carbonate reference materials. Calibration was performed with the certified NIST SRM 610 glass, exclusively. Within overall analytical uncertainties, the 200 nm fs LA‐ICP‐MS data agreed with available reference values.  相似文献   

Paleoclimate and growth rates of speleothems in the northwestern Iberian Peninsula over the last two glacial cycles     

Heather M. Stoll  Ana Moreno  Ana Mendez-Vicente  Saul Gonzalez-Lemos  Montserrat Jimenez-Sanchez  Maria Jose Dominguez-Cuesta  R. Lawrence Edwards  Hai Cheng  Xianfeng Wang 《Quaternary Research》2013

Speleothem growth requires humid climates sufficiently warm to stimulate soil CO₂ production by plants. We compile 283 U/Th dates on 21 stalagmites from six cave systems in the NW coast of Spain to evaluate if there are patterns in stalagmite growth that are evidence of climatic forcing. In the oldest stalagmites, from marine oxygen isotope stage (MIS) 7–5, growth persists through the glacial period. Hiatuses and major reductions in growth rate occur during extreme minima in summer insolation. Stalagmites active during the last interglaciation cease growth at the MIS 5–4 boundary (74 ka), when regional sea-surface temperature cooled significantly. During MIS 3, only two stalagmites grew; rates were highest between 50 and 60 ka during the maximum in summer insolation. One stalagmite grew briefly at 41 ka, 36.5 and 28.6 ka, all during warm phases of the Dansgaard–Oeschger cycles. A pronounced Holocene optimum in stalagmite growth occurs from 9 to 6 ka. The cessation of most growth by 4.1 ka, coincident with broad increases in aridity over the Mediterranean and areas influenced by the North African Monsoon, suggest that regions such as NW Spain, with dominant Atlantic moisture sources, also experienced increased aridity at this time.  相似文献   

A dynamical model for the distribution of dark matter and gas in galaxy clusters     

Elena Rasia  Giuseppe Tormen  Lauro Moscardini 《Monthly notices of the Royal Astronomical Society》2004,351(1):237-252

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X-ray and Sunyaev–Zel'dovich scaling relations in galaxy clusters     

Andrea Morandi  Stefano Ettori  Lauro Moscardini 《Monthly notices of the Royal Astronomical Society》2007,379(2):518-534

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Giant cluster arcs as a constraint on the scattering cross-section of dark matter     

Massimo Meneghetti  Naoki Yoshida  Matthias Bartelmann  Lauro Moscardini  Volker Springel  Giuseppe Tormen  Simon D. M. White 《Monthly notices of the Royal Astronomical Society》2001,325(1):435-442

We carry out ray tracing through five high-resolution simulations of a galaxy cluster, to study how its ability to produce giant gravitationally lensed arcs is influenced by the collision cross-section of its dark matter. In three cases typical dark matter particles in the cluster core undergo between 1 and 100 collisions per Hubble time; two more explore the long ('collisionless') and short ('fluid') mean free path limits. We study the size and shape distributions of arcs and compute the cross-section for producing 'extreme' arcs of various sizes. Even a few collisions per particle modifies the core structure enough to destroy the ability of the cluster to produce long, thin arcs. For larger collision frequencies the cluster must be scaled up to unrealistically large masses before it regains the ability to produce giant arcs. None of our models with self-interacting dark matter (except the 'fluid' limit) is able to produce radial arcs; even the case with the smallest scattering cross-section must be scaled to the upper limit of observed cluster masses before it produces radial arcs. Apparently the elastic collision cross-section of dark matter in clusters must be very small, below 0.1 cm² g⁻¹, to be compatible with the observed ability of clusters to produce both radial arcs and giant arcs.  相似文献   

Pre-processing algorithms and landslide modelling on remotely sensed DEMs     

Monia Santini  Salvatore Grimaldi  Fernando Nardi  Andrea Petroselli  Maria Cristina Rulli 《Geomorphology》2009,113(1-2):110

Terrain analysis applications using remotely sensed Digital Elevation Models (DEMs), nowadays easily available, permit to quantify several river basin morphologic and hydrologic properties (e.g. slope, aspect, curvature, flow path lengths) and indirect hydrogeomorphic indices (e.g. specific upslope area, topographic wetness index) able to characterize the physical processes governing the landscape evolution (e.g. surface saturation, runoff, erosion, deposition). Such DEMs often contain artifacts and the automated hydrogeomorphic characterization of the watershed is influenced by terrain analysis procedures consisting in artificial depression (pit) and flat area treatment approaches combined with flow direction methods.In shallow landslide deterministic models, when applied using topographic dataset at medium scale (e.g. 30 m of resolution), the choice of the most suitable DEM-processing procedure is not trivial and can influence model results. This also affects the selection of most critical areas for further finer resolution studies or for the implementation of countermeasures aiming to landslide risk mitigation.In this paper such issue is investigated using as topographic input the ASTER DEMs and comparing two different combinations of DEM correction and flow routing schemes. The study areas comprise ten catchments in Italy for which hydrogeomorphic processes are significant. Aims of this paper are: 1) to introduce a parameter estimation procedure for the physically-based DEM correction method PEM4PIT (Physical Erosion Model for PIT removal); 2) to investigate the influence of different terrain analysis procedures on results of the slope stability model SHALSTAB (SHAllow Landsliding STABility) using remotely-sensed ASTER DEMs; 3) trying to assess which of terrain analysis methods is more appropriate for describing terrain instability.  相似文献   

Stability analysis and morphometric characterization of palaeo-lakes of the Benjamin Matienzo basin, Las Cuevas River, Argentina     

Stella Moreiras  Carolina Lauro  Leandro Mastrantonio 《Natural Hazards》2012,62(2):593-611

Natural dams are caused by the blockage of streams as a result of the sudden arrival of detritus material during a glacial surge advance or fast slope collapse threatening downstream populations. Nevertheless, origin, morphological characteristics and stability of dammed lakes are frequently ignored. Six impounded palaeo-lakes were geomorphologically studied in the Benjamin Matienzo gully (32°14′ S–70°02′ W), denominated, from north to south: Goyete, Negro, Casa de Piedra, Lagunita, Susanita and Matienzo. We determined the origin, morphometric parameters, stability index and rate of streamflow rupture for these dammed ancient lakes in order to shed light on the potential outburst flood hazard in this Andean mountain region. According to our findings, we concluded that palaeo-lakes would have had a short life as they turned out to be unstable, except for the Goyete Lake, matching with the lack of fine lacustrine sediments in all river blockages. We also estimated the maximum peak discharge of a probable outburst flow generated during a drastic collapse of these dams. Obtained values range between 22 and 151 m³/s being notably higher than the average annual streamflow of Las Cuevas River (6.6 m³/s), but similar to the instantaneous streamflow of this river (157 m³/s, 2-year recurrence time).  相似文献   

Petrology and Sr–Nd–Hf isotope geochemistry of gabbro xenoliths from the Hyblean Plateau: a MARID reservoir beneath SE Sicily?     

Giovanna T. Sapienza  William L. Griffin  Suzanne Y. O’Reilly  Lauro Morten 《Contributions to Mineralogy and Petrology》2009,157(1):1-22

In situ trace-element and isotopic (⁸⁷Sr/⁸⁶Sr) data and whole-rock Sr–Nd–Hf data on 12 gabbro xenoliths from the Hyblean Plateau (south-eastern Sicily) illustrate the complex petrogenetic evolution of this lithospheric segment. The gabbros formed by precipitation of plagioclase + clinopyroxene from a HIMU-type alkaline melt, then were cryptically metasomatized by a low-Rb, high-⁸⁷Sr/⁸⁶Sr fluid, and finally infiltrated by an exotic, late Fe–Ti-rich melt with ⁸⁷Sr/⁸⁶Sr ~ 0.7055, carrying high concentrations of Sr, Rb and HFSE. The geochemical and isotopic features of both the metasomatizing fluid and the Fe–Ti-rich melt are compatible with their common derivation by the progressive melting of an amphibole–phlogopite–ilmenite metasomatic domain (MARID-type?) that probably resided within the subcontinental lithospheric mantle. Therefore, both the astenosphere and the lithosphere underneath the Hyblean Plateau contributed to the petrogenesis of the gabbros. Sm–Nd dating yields an age of 253 ± 60 Ma for the cumulitic pile, roughly coinciding with a hydrothermal event recorded by crustal zircons in the area. We suggest that the Hyblean Plateau suffered a thermal event—probably related to lithospheric thinning and upwelling and melting of the asthenosphere—in Permo-Triassic time (the opening of the Ionian Basin?). The induced perturbation in the lithosphere caused consequent melting of some previously metasomatised portions.  相似文献   

High-Resolution LA-ICP-MS for Accurate Determination of Low Abundances of K, Sc and Other Trace Elements in Geological Samples   总被引：1，自引：0，他引：1  

Julia Regnery  Brigitte Stoll  Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2010,34(1):19-38

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) was used to determine K, Sc, Ti, V, Cr, Mn, Co, Ni and Zn in geological samples. Because the isotopes of these elements and the internal standard element (Ca) often have interferences from molecular ions when determined using quadrupole or sector-field ICP-MS in low mass resolution mode, ion intensities were measured at a high mass resolution of 4000. We investigated dynamic element fractionation, type and abundance of molecular ions using different geological reference materials. Highly resolved mass spectra were especially important for accurate low-abundance measurements. As a result, maximum "critical" concentration limits for each isotope were obtained, where a mass resolution of 4000 was necessary for reliable LA-ICP-MS analysis. To test the LA-ICP-MS technique, different international reference material glasses and powdered rock reference materials were analysed. Rock powders were fused to glass beads using an Ir-strip heater. Nearly all concentration values for the reference materials agreed with the reference values at the 95% confidence level. To demonstrate routine LA-ICP-MS analysis at a mass resolution of 4000, trace element data for Hawaiian basalts are also presented.  相似文献