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101.
102.
The aliphatic, aromatic and polar (NSO) fractions of seabed petroleums and sediment bitumen extracts from the Guaymas Basin hydrothermal system have been analyzed by gas chromatography and gas chromatography-mass spectrometry (free and silylated). The oils were collected from the interiors and exteriors of high temperature hydrothermal vents and represent hydrothermal pyrolyzates that have migrated to the seafloor by hydrothermal fluid circulation. The downcore sediments are representative of both thermally unaltered and thermally altered sediments. The survey has revealed the presence of oxygenated compounds in samples with a high degree of thermal maturity. Phenols are one class of oxygenated compounds found in these samples. A group of methyl-, dimethyl- and trimethyl-isoprenoidyl phenols (C27-C29) is present in all of the seabed NSO fractions, with the methyl- and dimethyl-isoprenoidyl phenols occurring as major components, and a trimethyl-isoprenoidyl phenol as a minor component. A homologous series of n-alkylphenols (C13-C33) has also been found in the seabed petroleums. These phenols are most likely derived from the hydrothermal alteration of sedimentary organic matter. The n-alkylphenols are probably synthesized under hydrothermal conditions, but the isoprenoidyl phenols are probably hydrothermal alteration products of natural product precursors. The suites of phenols do not appear to be useful tracers of high temperature hydrothermal processes.  相似文献   
103.
Four new U/Pb-zircon ages are reported from northern Vestranden, the northernmost part of the Western Gneiss Region of Norway, Scandinavian Caledonides. The age of a basement tonalite (1819±6 Ma), together with earlier datings on granites, indicates that the dominantly granitoid basement in Vestranden began to form more than 1800 Ma years ago. The minimum age of a subsequent Precambrian migmatization event is given by a U/Pb age of 1630±80 Ma found a granite dyke which cuts migmatitic veining in the basement gneisses. While age and lithology suggest general similarity and thereby favour a correlation between the basement granites of the northern part of Vestranden and Svecofennian granites farther to the east, no detailed chronological information is at present available that support such a correlation.No Sveconorwegian-Grenvillian ages have previously been reported from northern Vestranden. Also in the presently studied cases events between c. 1630 Ma and 430 Ma ago did not affect the U-Pb isotope system of zircons. About 430 Ma ago, substantial parts of Vestranden experienced Caledonian high-grade metamorphism and partial anatectic melting. Migmatite neosomes in northern Vestranden, yielded an U/Pb zircon age of 434±22 Ma. Relatively high temperatures persisted throughout much of the Silurian and probably into the Devonian. Large amounts of pegmatite intruded at the end of this period. One of these dykes yielded an U/Pb-zircon age of 404±2 Ma.
Zusammenfassung Vier neue U-Pb-Zirkonalter liegen aus dem nördlichen Vestranden-Bereich des westnorwegischen Gneissgebiets vor. Das Alter einer Tonalitintrusion (1819±6 Ma) bestätigt zusammen mit anderen Altersbestimmungen, daß das präkambrische Fundament der zentralskandinavischen Kaledoniden sich im Vestrandengebiet bereits vor mehr als 1800 Ma zu bilden begann. Das Minimalalter einer darauf folgenden präkambrischen Migmatisierung wird durch ein 1630±20 Ma Alter durchsetzender Granitgänge begrenzt. Zwar deuten die bisher vorliegenden Ergebnisse eine Gleichaltrigkeit der Granitgesteine im nördlichen Vestranden und den Svekofenniden weiter östlich an, ermöglichen aber derzeit noch keine präzise Korrelation des geologischen Geschehens.Sveconorwegische (Grenville) Isotopenalter sind bisher nicht aus dem nördlichen Vestranden bekannt. Auch die neuen Daten weisen keine Störung der U-Pb-Isotopensysteme zwischen etwa 1630 und 430 Ma auf.Beträchtliche Teile des Vestrandenbereiches wurden vor ca. 430 Ma einer kaledonischen, höhergradigen Metamorphose und anatektischer Aufschmelzung unterworfen. Die Neosome eines Migmatites ergaben ein Alter von 434±22 Ma, was erneut die Existenz zweier verschiedener Migmatisierungsetappen im Präkambrium bzw. in Silur bestätigt. Höhere Temperaturen bestanden danach bis in das Devon. Größere Pegmatitmengen wurden am Ende dieser Zeitspanne gebildet. Einer dieser Pegmatitkörper ergab ein U-Pb-Zirkonalter von 404±2 Ma.

Résumé Cette note fait état de 4 nouvelles déterminations d'âge (méthode U/Pb sur zircon) dans le Vestranden septentrional, qui forme la partie nord de la région gneissique occidentale de la Norvège (Calédonides). L'âge d'une tonalite (1819±6 Ma), joint à des datations antérieures effectuées sur des granites, indique que la formation du socle granitoîde dans le Vestranden a commencé il y a plus de 1800 Ma. L'âge maximal d'une migmatitisation précambrienne ultérieure est donné par la mesure de 1630±80 Ma effectuée sur un dyke de granite qui recoupe le rubanement migmatitique. L'âge et la lithologie indiquent une similitude d'ensemble et, partant, suggèrent une corrélation entre les granites du nord du Vestranden et ceux des Svécofennides situés plus à l'est; toutefois, on ne dispose aujourd'hui d'aucune donnée chronologique à l'appui d'une telle corrélation.Jusqu'à présent, aucun âge svéconorvégien-grenvillien n'a été enregisré dans le Vestranden septentrional. De même, dans les cas étudiés ici, aucun événement n'a affecté le système isotopique U-Pb entre 1630 et 430 Ma. A environ 430 Ma, des parties importantes du Vestranden ont enregistré un métamorphisme calédonien de degré élevé et une fusion anatectique partielle. Les néosomes d'une migmatite ont fourni un âge U/Pb sur zircon de 434±22 Ma. Des températures relativement élevées se sont maintenues pendant la plus grande partie du Silurien et jusqu'au cours du Dévonien. De grandes quantités de pegmatite ont été intrudées à la fin de cette période; un de ces dykes a donné un âge U/Pb sur zircon de 404±2 Ma.

- - . 1819±6 . , , - 1800 . . , , 1630±80 . , . , .- - 1630-430 . . . 434=22 . . , , , ; , , -, 404=2 . .
  相似文献   
104.
The C3H radical, a linear carbon chain with a 2 pi electronic ground state, has been identified in the millimeter-wave spectra of two astronomical sources, IRC +10216 and TMC-1, and conclusively confirmed (accompanying Letter) in a laboratory glow discharge. In IRC +10216 four rotational transitions have been observed, three in the lower fine-structure ladder (2 pi 1/2) and one in the upper (2 pi 3/2), each a resolved or partially resolved lambda-doublet. In TMC-1, both lambda components of the lowest lying 3/2 --> 1/2 transition of the 2 pi 1/2 ladder have been observed, each with well-resolved hfs. In IRC +10216 the excitation of C3H is similar to that of SiCC: the rotational temperature Trot within the 2 pi 1/2 ladder is low (8.5 K), owing to rapid radiative decay, while Trot across the ladders is high (approximately 52 K) because interconnecting far-IR radiative transitions are only weakly permitted. The column density of C3H in IRC +10216 averaged over the estimated source diameter of 84" is 2.8 x 10(13) cm-2, an order of magnitude less than that of C2H and C4H. A determination of the spectroscopic constraints of C3H that permitted the entire radio spectrum of this molecule to be calculated to high accuracy has been derived from analysis of the combined astronomical and laboratory data presented in the accompanying Letter.  相似文献   
105.
The Söndrum stone quarry (Halmstad, SW Sweden) exposes a transition from migmatized granitic gneissic country rock into a foliated clinopyroxene‐free granitic gneiss, and then a central pegmatoid dyke dominated by clinopyroxene megacrysts. This transition zone represents a fracture‐controlled, fluid‐alteration zone that developed under conditions of 650–700 °C and 790 MPa. Mineral chemical trends in F, Cl, Fe, Ti, Mn and Y are interpreted as documenting a fluid infiltration event associated with the formation of the pegmatoid dyke. Fluid inclusions from the pegmatoid dyke are CO2 dominant, whereas in the surrounding country rock they are dominated by H2O‐NaCl‐CaCl2. Fluid inclusions from the intermediate foliated clinopyroxene‐free granitic gneiss are a mixture of the two types. The pegmatoid dyke appears to have originated from a high Ca activity, Fe‐Mg enriched, fluid‐rich granitic melt with a CO2 component, which was emplaced along a tectonic fracture in a regionally migmatized granitic gneiss in the lower crust. This was accompanied by limited partial melting of the surrounding granitic gneiss. The Ca activity of the melt was high enough to allow for the formation of clinopyroxene megacrysts as opposed to orthopyroxene. H2O‐enriched fluids expelled from the crystallizing pegmatoid dyke, which retained the majority of the CO2 helping to stabilize the clinopyroxene. The expelled fluids coarsened and chemically affected the surrounding country rock resulting in trends in the mineral and fluid inclusion chemistry seen today in the foliated and regional granitic gneiss.  相似文献   
106.
Proliferation of fast-growing ephemeral macroalgae in shallow-water embayments constitutes a large-scale environmental change of coastal marine ecosystems. Since inorganic nutrients essential for the initiation and maintenance of macroalgal growth may be supplied from the underlying sediment, we investigated the coupling between benthic inorganic nutrient (mainly N and P) fluxes and sediment properties in 6 bays representing a wide gradient of sediment characteristics (grain size, organic matter content, solid phase C and N). The initial characterization of bays was made in June and also included measurements of oxygen flux and microphytobenthic and macrofaunal biomass. In September, still within the growth season of the macroalgae, complementary experiments with sediment-water incubations for benthic flux measurements of oxygen and nutrients focused on trophic status (balance between auto- and heterotrophy) as a controlling factor for rates of measured benthic nutrient fluxes. Generally, sediments rendered autotrophic by microphytobenthic photosynthesis removed nutrients from the overlying water, while heterotrophic sediments supplied nutrients to the overlying bottom water. Estimations of the green-algal nutrient demand suggested that late in the growth season, net heterotrophic sediments could cover 20% of the N-demand and 70% of the P demand. As the benthic trophic status is a functional variable more closely coupled to nutrient fluxes than the comparably conservative structural parameter organic matter content, we suggest that the trophic status is a more viable parameter to classify sediments and predict benthic nutrient fluxes in shallow-water environments.  相似文献   
107.
The Hattian landslide, which was triggered by the 2005 Kashmir earthquake, formed one of largest landslide dams in the world and it has posed a serious threat of flooding to people living in the lower reach of the Jhelum River. In order to understand deformation occurring in the body of the dam, physical measurements using a Differential Global Positioning System (DGPS) were conducted. Gradual deformation and slowly developing backward erosion initially were observed, leading eventually to a sudden creation of a deep hollow on the downstream slope of the landslide dam. The dimensions of this eroded gully were determined by laser scanning, and the results showed a significant loss of soil volume and a large change in the body of the dam. A breach formation model was used to predict the outflow hydrograph generated by constant downcutting of dam during a breaching event. A run-off analysis of the outflow hydrograph was conducted to evaluate inundation levels of flood waves in case the dam is breached. Hazardous downstream locations were identified near the junction of the Karli and Jhelum Rivers, suggesting a need for early warning system in order to avoid loss of lives.  相似文献   
108.
Using the 20-m Onsala Observatory telescope (Sweden), we performed observations of the CH3C2H(6-5) line toward several regions of massive star formation to estimate the kinetic temperature of the gas and study its variations over the sources. Intense lines were detected in five objects. For these, we estimated the kinetic temperature of the gas near the CS and N2H+ molecular emission peaks by the method of population diagrams. A significant temperature difference between these peaks is noticeable only in W3 and, to a lesser degree, in DR 21. In the remaining cases, it is insignificant. This indicates that the chemical differentiation of the molecules in these regions cannot be associated with temperature variations. The kinetic temperature determined from methyl acetylene observations is usually slightly higher than the temperature estimated from ammonia observations. This is probably because the methyl acetylene emission originates in denser, i.e., deeper and hotter layers of the cloud.  相似文献   
109.
Svalbard is located in the north-west corner of the Barents Sea shelf and the Eurasian Plate, in a key area for interpreting Caledonian and older orogens in the Arctic region. Recent U–Pb dating in the Nordaustlandet Terrane of eastern Svalbard shows this terrane to consist of a Grenville-age basement, overlain by Neoproterozoic to early Palaeozoic platformal sediments, and intruded by Caledonian anatectic granites. Deformation, metamorphism and crustal anatectic magmatism occurred both during the Grenvillian (960–940 Ma) and Caledonian (450–410 Ma) orogenies. This evolution shows great similarities with that of eastern Greenland. In the classical model, eastern Svalbard is placed outboard of central east Greenland in pre-Caledonian time. Alternatively, it may have been located north-east of Greenland and transferred west and rotated anticlockwise during Caledonian continent–continent collision. In the Neoproterozoic, easternmost Svalbard may have been part of a wider area of Grenville-age crust, now fragmented and dispersed around the Arctic.  相似文献   
110.
Fine-grained glaciomarine and glacial deposits on the outer Mid Norwegian continental shelf show complex variations in shear strength and degree of consolidation. At the Smørbukk Sør field (approx. 65°N, 7°E) about 80 m of variably overconsolidated clayey till is found on top of normally- or possibly underconsolidated glaciomarine and marine sediments. A high gas content is found below 60 m, and the porewater in the rather soft sediments in the lower part of the borehole may have been partly trapped by gas hydrates when the overlying hard till was deposited. The variations in geotechnical properties of the 80 m thick till section are suggested to result mainly from compaction below grounded ice during the last glaciation, and we interpret the strength variations in the till to reflect shifts between freeze of sediment porewater onto the base of the ice causing highly overconsolidated intervals, and thermal equilibrium or melting at the ice sole resulting in intervals of softer till.A large ridge northwest of Smørbukk (Skjoldryggen) is probably partly formed by ice push during ice flow oscillations at the same time as the described till at Smørbukk was deposited. This ridge retarded the ice flow and hence the frictional heating at the end of surges, creating pulses of net freezing base ice and consolidation of the substratum. The described process has possibly affected a wide area up-ice of Skjoldryggen, and may be common in areas with a complex glacial history and a fine-grained substratum.  相似文献   
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