Late Quaternary moisture export across Central America and to Greenland: evidence for tropical rainfall variability from Costa Rican stalagmites     

Matthew S. Lachniet  Leah Johnson  Yemane Asmerom  Stephen J. Burns  Victor Polyak  William P. Patterson  Lindsay Burt  April Azouz 《Quaternary Science Reviews》2009,28(27-28):3348-3360

We present a high-resolution terrestrial archive of Central American rainfall over the period 100–24 and 8.1–6.5 ka, based on δ¹⁸O time series from U-series dated stalagmites collected from a cave on the Pacific Coast of Costa Rica. Our results indicate substantial δ¹⁸O variability on millennial to orbital time scales that is interpreted to reflect rainfall variations over the cave site. Correlations with other paleoclimate proxy records suggest that the rainfall variations are forced by sea surface temperatures (SST) in the Atlantic and Pacific Oceans in a fashion analogous to the modern climate cycle. Higher rainfall is associated with periods of a warm tropical North Atlantic Ocean and large SST gradients between the Atlantic and Pacific Oceans. Rainfall variability is likely linked to the intensity and/or latitudinal position of the intertropical convergence zone (ITCZ). Periods of higher rainfall in Costa Rica are also associated with an enhanced sea surface salinity gradient on either side of the isthmus, suggesting greater freshwater export from the Atlantic Basin when the ITCZ is stronger and/or in a more northerly position. Further, wet periods in Central America coincide with high deuterium excess values in Greenland ice, suggesting a direct link between low latitude SSTs, tropical rainfall, and moisture delivery to Greenland. Our results indicate that a stronger tropical hydrological cycle during warm periods and large inter-ocean SST gradients enhanced the delivery of low latitude moisture to Greenland.  相似文献   

Raman spectroscopic study of PbCO3 at high pressures and temperatures     

Robert Minch  Leonid Dubrovinsky  Alexandr Kurnosov  Lars Ehm  Karsten Knorr  Wulf Depmeier 《Physics and Chemistry of Minerals》2010,37(1):45-56

Cerussite (PbCO₃) has been investigated by high-pressure and high-temperature Raman spectroscopy up to pressures of 17.2 GPa and temperatures of 723 K. Two pressure induced phase transitions were observed at about 8.0(2) and 16.0(2) GPa, respectively. The post-aragonite transition (PbCO₃-II) at 8.0(2) GPa is accompanied by softening of the v ₂-out-of-plane mode of the CO ₃ ^2? group and disappearance of the B_1g (v ₄-in-plane band of the CO ₃ ^2? group) mode. Stronger shifts of the carbonate group modes after the phase transition suggest that the new structure is more compressible. The formation of a second high-pressure polymorph begins at about 10 GPa. It is accompanied by the occurrence of three new bands at different pressures and splitting of the v ₁-symmetric C–O stretching mode of the CO ₃ ^2? group. The transitions are reversible on pressure release. A semi-quantitative phase diagram for PbCO₃ as a function of pressure and temperature is proposed.  相似文献   

Strontium and oxygen isotopic systems in waters of mud volcanoes of the Taman Peninsula     

M. I. Bujakaite  V. Yu. Lavrushin  B. G. Pokrovsky  O. E. Kikvadze  B. G. Polyak 《Lithology and Mineral Resources》2014,49(1):47-54

Ten of eleven analyzed water samples from mud volcanoes of the Taman Peninsula are characterized by ⁸⁷Sr/⁸⁶Sr ratio within 0.70734–0.70957, which overlaps the values typical of the Mesozoic and Cenozoic sedimentary carbonates, but sharply differs from the value in the clayey sediments of the Maikop Group (0.7157 ± 0.0022). These data indicate that the strontium isotopic composition is mainly defined by carbonate reservoirs, with relatively little effect of elision solutions, input of which is noticeable only in the water of Gladkovsky Volcano (⁸⁷Sr/⁸⁶Sr = 0.71076). The high δ¹⁸O in mud volcanic waters (up to 14.2‰) can also be attributed to ionic exchange with sedimentary carbonates at temperatures around 150°C.  相似文献   

X-ray single-crystal and Raman study of knorringite,Mg3(Cr1.58Mg0.21Si0.21)Si3O12, synthesized at 16 GPa and 1,600 °C     

Elena A. Bykova  Andrey V. Bobrov  Ekaterina A. Sirotkina  Luca Bindi  Sergey V. Ovsyannikov  Leonid S. Dubrovinsky  Yuriy A. Litvin 《Physics and Chemistry of Minerals》2014,41(4):267-272

The crystal structure of a knorringite-type compound, Mg₃(Cr_1.58Mg_0.21Si_0.21)Si₃O₁₂, synthesized in a multi-anvil press at P = 16 GPa and T = 1,600 °C, was refined from single-crystal X-ray diffraction data up to R = 2.36 % for 314 independent reflections. Garnet was found to be cubic and have space group Ia $\overline{3}$ d, with the unit cell parameters a = 11.5718 (1) Å, V = 1,549.54 (2) Å³. The knorringite crystal studied contains 21 mol% of majorite end-member. The structural characterization of knorringitic garnet is important because the study of its thermodynamic constants provides new constraints on thermobarometry of peridotitic garnet assemblages of the lowermost upper mantle. The Raman spectra of synthetic knorringite have been obtained for the first time.  相似文献   

Isotopic Composition of Dissolved Carbonates Meromictic Soda Lake Doroninskoe(Eastern Transbaikalia,Russia)   总被引：1，自引：0，他引：1  

Leonid V. ZAMANA  Svetlana V. BORZENKO 《《地质学报》英文版》2014,88(Z1):395-397

正1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14'42"E112°14'40",  相似文献   

Analysis of a deformable fracture in permeable material     

Lawrence C. Murdoch  Leonid N. Germanovich 《国际地质力学数值与分析法杂志》2006,30(6):529-561

The response of deformable fractures to changes in fluid pressure controls phenomena ranging from the flow of fluids near wells to the propagation of hydraulic fractures. We developed an analysis designed to simulate fluid flows in the vicinity of asperity‐supported fractures at rest, or fully open fractures that might be propagating. Transitions between at‐rest and propagating fractures can also be simulated. This is accomplished by defining contact aperture as the aperture when asperities on a closing fracture first make contact. Locations on a fracture where the aperture is less than the contact aperture are loaded by both fluid pressure and effective stress, whereas locations where the aperture exceeds the contact aperture are loaded only by fluid pressure. Fluid pressure and effective stress on the fracture are determined as functions of time by solving equations of continuity in the fracture and matrix, and by matching the global displacements of the fracture walls to the local deformation of asperities. The resulting analysis is implemented in a numerical code that can simulate well tests or hydraulic fracturing operations. Aperture changes during hydraulic well tests can be measured in the field, and the results predicted using this analysis are similar to field observations. The hydraulic fracturing process can be simulated from the inflation of a pre‐existing crack, to the propagation of a fracture, and the closure of the fracture to rest on asperities or proppant. Two‐dimensional, multi‐phase fluid flow in the matrix is included to provide details that are obscured by simplifications of the leakoff process (Carter‐type assumptions) used in many hydraulic fracture models. Execution times are relatively short, so it is practical to implement this code with parameter estimation algorithms to facilitate interpretation of field data. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

POSSIBLE　HYDROGEOCHEMICAL　PRECONDITIONS　FOR　KASHIN－BECK　DISEASE　IN　TRANSBAIKALIA     

Zamana Leonid Vasilevich 《中国地理科学(英文版)》1995,5(2):185-192

ＰＯＳＳＩＢＬＥＨＹＤＲＯＧＥＯＣＨＥＭＩＣＡＬＰＲＥＣＯＮＤＩＴＩＯＮＳＦＯＲＫＡＳＨＩＮ－ＢＥＣＫＤＩＳＥＡＳＥＩＮＴＲＡＮＳＢＡＩＫＡＬＩＡ￥ＺａｍａｎａＬｅｏｎｉｄＶａｓｉｌｅｖｉｃｈ（ＣｈｉｔａＩｎｓｔｉｔｕｔｅｏｆＮａｔｕｒａｌＲｅｓｏｕ...  相似文献   

On the maximum value of the cosmic abundance of oxygen and the oxygen yield     

Leonid S. Pilyugin  Trinh X. Thuan  José M. Vílchez 《Monthly notices of the Royal Astronomical Society》2007,376(1):353-360

We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centres of the most luminous galaxies, we have constructed the luminosity – central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of H  ii regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities  (−22.3 ≲ M _B ≲−20.3)  , with a constant maximum value of the gas-phase oxygen abundance  12 + log (O/H) ∼ 8.87  . This provides strong evidence that the oxygen abundance in the centres of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas + dust oxygen abundance in spiral galaxies is 12 + log(O/H) ∼ 8.95. This value is a factor of ∼2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.  相似文献   

Two-integral distribution functions for axisymmetric stellar systems with separable densities   总被引：1，自引：0，他引：1  

Zhenglu Jiang  Leonid Ossipkov 《Monthly notices of the Royal Astronomical Society》2007,382(4):1971-1981

We show different expressions of distribution functions (DFs) which depend only on the two classical integrals of the energy and the magnitude of the angular momentum with respect to the axis of symmetry for stellar systems with known axisymmetric densities. The density of the system is required to be a product of functions separable in the potential and the radial coordinates, where the functions of the radial coordinate are powers of a sum of a square of the radial coordinate and its unit scale. The even part of the two-integral DF corresponding to this type of density is in turn a sum or an infinite series of products of functions of the energy and of the magnitude of the angular momentum about the axis of symmetry. A similar expression of its odd part can be also obtained under the assumption of the rotation laws. It can be further shown that these expressions are in fact equivalent to those obtained by using Hunter & Qian's contour integral formulae for the system. This method is generally computationally preferable to the contour integral method. Two examples are given to obtain the even and odd parts of their two-integral DFs. One is for the prolate Jaffe model and the other for the prolate Plummer model.
It can be also found that the Hunter–Qian contour integral formulae of the two-integral even DF for axisymmetric systems can be recovered by use of the Laplace–Mellin integral transformation originally developed by Dejonghe.  相似文献   

The bends in the slopes of radial abundance gradients in the disks of spiral galaxies – do they exist?     

Leonid Pilyugin 《Astrophysics and Space Science》2003,284(2):775-778

Spiral galaxies with a reported bend in the slope of the oxygen abundance O/H_{R 23}, derived with the traditionally used R₂₃-method, are examined. It is shown that the artificial origin of the reported bends can be naturally explained. Two causes of the false bend in the slope of O/H_{R 23} are indicated. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献