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111.
Structural, petrological and textural studies are combined with phase equilibria modelling of metapelites from different structural levels of the Roc de Frausa Massif in the Eastern Pyrenees. The pre‐Variscan lithological succession is divided into the Upper, Intermediate and Lower series by two orthogneiss sheets and intruded by Variscan igneous rocks. Structural analysis reveals two phases of Variscan deformation. D1 is marked by tight to isoclinal small‐scale folds and an associated flat‐lying foliation (S1) that affects the whole crustal section. D2 structures are characterized by tight upright folds facing to the NW with steep NE–SW axial planes. D2 heterogeneously reworks the D1 fabrics, leading to an almost complete transposition into a sub‐vertical foliation (S2) in the high‐grade metamorphic domain. All structures are affected by late open to tight, steeply inclined south‐verging NW–SE folds (F3) compatible with steep greenschist facies dextral shear zones of probable Alpine age. In the micaschists of the Upper series, andalusite and sillimanite grew during the formation of the S1 foliation indicating heating from 580 to 640 °C associated with an increase in pressure. Subsequent static growth of cordierite points to post‐D1 decompression. In the Intermediate series, a sillimanite–biotite–muscovite‐bearing assemblage that is parallel to the S1 fabric is statically overgrown by cordierite and K‐feldspar. This sequence points to ~1 kbar of post‐D1 decompression at 630–650 °C. The Intermediate series is intruded by a gabbro–diorite stock that has an aureole marked by widespread migmatization. In the aureole, the migmatitic S1 foliation is defined by the assemblage biotite–sillimanite–K‐feldspar–garnet. The microstructural relationships and garnet zoning are compatible with the D1 pressure peak at ~7.5 kbar and ~750 °C. Late‐ to post‐S2 cordierite growth implies that F2 folds and the associated S2 axial planar leucosomes developed during nearly isothermal decompression to <5 kbar. The Lower series migmatites form a composite S1–S2 fabric; the garnet‐bearing assemblage suggests peak P–T conditions of >5 kbar at suprasolidus conditions. Almost complete consumption of garnet and late cordierite growth points to post‐D2 equilibration at <4 kbar and <750 °C. The early metamorphic history associated with the S1 fabric is interpreted as a result of horizontal middle crustal flow associated with progressive heating and possible burial. The upright F2 folding and S2 foliation are associated with a pressure decrease coeval with the intrusion of mafic magma at mid‐crustal levels. The D2 tectono‐metamorphic evolution may be explained by a crustal‐scale doming associated with emplacement of mafic magmas into the core of the dome.  相似文献   
112.
Interpreting how environmental dynamics respond to global climate change and how this has affected human evolution and dispersal is an on-going topic of debate. During the early Middle Pleistocene (~0.6–0.4 Ma), as compared to earlier, environmental conditions were relatively more stable, with longer climatic cycles alternating between open and forested landscapes. During this interval, humans spread successfully providing an important number of fossil sites where fossils or tools are reported. The Atapuerca-Sima de los Huesos (Burgos, northern Spain) site (Atapuerca-SH) is one of the earliest localities with hominin evidence in the European Middle Pleistocene, with the most important accumulation of Homo heidelbergensis so far. We have analyzed the abundant faunal record from Sima de los Huesos, which is mainly comprised of carnivores, in order to approach an interpretation of the palaeoenvironmental circumstances where these hominids inhabited within the Sierra. Other sites from Sierra de Atapuerca referred to the same Faunal Unit (FU 6), are roughly contemporaneous, and include important ungulates, which are here analyzed with Atapuerca-SH. Additional information provided by isotopic analysis helps elucidate the ancient ecology of taxa present in Sima de los Huesos allowing for an accurate portrayal of the setting in which humans lived. The timing of the spread of Homo heidelbergensis is dominated by a relative climatic and environmental stability and points to a landscape dominated by savannah-like open woodland.  相似文献   
113.
In this study, the dispersal of wastes from offshore fish farms was evaluated by analyzing nitrogen stable isotope ratios (δ15N) in macroalgae incubated in the water column at sites located at an increasing distance from the fish cages. Bioassays were performed at three fish farms situated in separate localities with different nutritional conditions (Canary Islands, Murcia and Catalonia) and varying in size, species of fish reared and annual production. Macroalgal bioassays were carried out in two different directions (DI and DII) and they were replicated at each distance in order to evaluate the effect of small-scale variability on the spatial extent of fish farm wastes. The results obtained with δ15N contribute to a better understanding of the application of nitrogen stable isotopes ratios in macroalgae as an effective bioindicator for tracing the dispersion of offshore fish farm wastes, and demonstrate that fish farm wastes can be traced even over distances of some km from the pollution source. In the Canary Islands, the maximum distance obtained for detection of fish farm wastes was between 450 and 700 m. Of the three installations studied, Murcia presented the greatest distance for detection of fish farm waste influence, ranging from between 1550 and 2450 m, whilst in Catalonia this distance was less than 120 m. In Catalonia, the results were masked by the influence of other sources of nitrogen, and thus fish farm wastes were detected at more reduced distances than expected. These results confirm that fish farm wastes can be traced using the nitrogen stable isotope ratios of macroalgae and that this method can also be useful for identifying areas of potential risk to some sensitive ecosystems, and as an early signal that changes in the community structure might occur.  相似文献   
114.
Thanks to its simple division into agricultural and forestry land use, the Corbeira catchment (Galicia, Spain) is used as a case study to build a predictive model using hydrogeochemical signatures. Stream data acquired under recessional flow conditions over a one year period were obtained from a sampling station near the downstream end of the catchment, and using principal component analysis, it is shown that some of the analytical parameters are covariant, and some are negatively correlated. These findings support inferences about the pathways of rainfall in the catchment. Specific signatures may be associated with the dominant hydrological source, either surface runoff or subsurface waters: additionally, the dominant land use in that part of the catchment, where the flow originated, can also be predicted. The dominant runoff shows a strong covariance between suspended solids (SS) and particulate phosphorus (PP), with a clear negative correlation with pH. Dissolved organic carbon (DOC) data are associated with this covariant set when these compounds are available in the soils in question. Dissolved phosphorus, total organic nitrogen and dissolved nitrates are also associated with the same covariant set when the runoff flows through areas of extensive agricultural use. The SS ? PP covariance is less significant at lower flows. Typical base flow regimes show a significant covariance between salinity and pH, with a marked negative correlation with SS ? PP set, confirming the dominance of subsurface waters in the baseflow, as expected. Seasonally divergent DOC ? SS behaviour proves to be a useful tracer for rainfall regimes. The DOC trend shows a sinusoidal annual variation in amplitude, determined by the rainfall regime. As a result, flow from the catchment is dominated by surface water whenever there is synchronicity between the peaks of DOC and SS. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
115.
We investigate the influence of mantle flow relative to the lithosphere on subduction dynamics. We use 2D thermo‐mechanical models assuming incompressible non‐Newtonian fluid rheology. Different mantle flow velocities consistent with absolute plate motion models are tested, as well as both directions of flow, either sustaining or opposing slab dip. The effects of different inflow/outflow velocity profiles, slab strengths and upper–lower mantle viscosity contrasts are also evaluated. Slab dip deviations between models with opposite mantle flow directions range from 37° for relatively strong slabs (ηmax = 1025 Pa s) to 50° for weaker slabs (ηmax = 1024 Pa s), accounting for a significant amount of natural slab dip variability. For imposed mantle flow supporting the slab, the initial stage of slab steepening is followed by a stage of continuous slab dip decrease. This slab shallowing eventually leads to mantle wedge closure, subduction cessation and slab break‐off, possibly driving subduction flips.  相似文献   
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118.
This paper focuses on pollen, spores, non‐pollen palynomorphs (NPPs) and certain geochemical elements from the ombrotrophic blanket bog of Zalama (Basque‐Cantabrian Mountains, northern Iberian Peninsula), with the support of a robust chronology based on 17 AMS 14C dates. The main results related to the last 8000 years show that, during the early middle Holocene, pines and deciduous forests were the most extensive tree formations. At the beginning of the succession, pines reach 44%, showing regional presence, whereas after 7600 cal. a BP, deciduous forests were particularly abundant. From c. 6500 cal. a BP the pollen diagram constructed from our samples shows the first anthropogenic evidence, linked with the new economic practices related to the Neolithic of the Basque‐Cantabrian Mountains. From 3300 cal. a BP the expansion of Fagus sylvatica is particularly clear, and has since then become one of the dominant forest species in this region. We also discuss the Holocene evolution of other noteworthy plant communities in southwestern Europe, such as Taxus baccata, Juglans and shrublands.  相似文献   
119.
Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
120.
Phosphorus (P) is one of the major limiting nutrient in many freshwater ecosystems. During the last decade, attention has been focused on the fluxes of suspended sediment and particulate P through freshwater drainage systems because of severe eutrophication effects in aquatic ecosystems. Hence, the analysis and prediction of phosphorus and sediment dynamics constitute an important element for ecological conservation and restoration of freshwater ecosystems. In that sense, the development of a suitable prediction model is justified, and the present work is devoted to the validation and application of a predictive soluble reactive phosphorus (SRP) uptake and sedimentation models, to a real riparian system of the middle Ebro river floodplain. Both models are coupled to a fully distributed two‐dimensional shallow‐water flow numerical model. The SRP uptake model is validated using data from three field experiments. The model predictions show a good accuracy for SRP concentration, where the linear regressions between measured and calculated values of the three experiments were significant (r2 ≥ 0.62; p ≤ 0.05), and a Nash–Sutcliffe coefficient (E) that ranged from 0.54 to 0.62. The sedimentation model is validated using field data collected during two real flooding events within the same river reach. The comparison between calculated and measured sediment depositions showed a significant linear regression (p ≤ 0.05; r2 = 0.97) and an E that ranged from 0.63 to 0.78. Subsequently, the complete model that includes flow dynamics, solute transport, SRP uptake and sedimentation is used to simulate and analyse floodplain sediment deposition, river nutrient contribution and SRP uptake. According to this analysis, the main SRP uptake process appears to be the sediment sorption. The analysis also reveals the presence of a lateral gradient of hydrological connectivity that decreases with distance from the river and controls the river matter contribution to the floodplain. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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