Deciphering the conditions of tochilinite and cronstedtite formation in CM chondrites from low temperature hydrothermal experiments     

Lionel G. Vacher  Laurent Truche  Franois Faure  Laurent Tissandier  Rgine Mosser‐Ruck  Yves Marrocchi 《Meteoritics & planetary science》2019,54(8):1870-1889

Tochilinite/cronstedtite intergrowths are commonly observed as alteration products in CM chondrite matrices, but the conditions under which they formed are still largely underconstrained due to their scarcity in terrestrial environments. Here, we report low temperature (80 °C) anoxic hydrothermal experiments using starting assemblages similar to the constituents of the matrices of the most pristine CM chondrite and S‐rich and S‐free fluids. Cronstedtite crystals formed only in S‐free experiments under circumneutral conditions with the highest Fe/Si ratios. Fe‐rich tochilinite with chemical and structural characteristics similar to chondritic tochilinite was observed in S‐bearing experiments. We observed a positive correlation between the Mg content in the hydroxide layer of synthetic tochilinite and temperature, suggesting that the composition of tochilinite is a proxy for the alteration temperature in CM chondrites. Using this relation, we estimate the mean precipitation temperatures of tochilinite to be 120–160 °C for CM chondrites. Given the different temperature ranges of tochilinite and cronstedtite in our experiments, we propose that Fe‐rich tochilinite crystals resulted from the alteration of metal beads under S‐bearing alkaline conditions at T = 120–160 °C followed by cronstedtite crystals formed by the reaction of matrix amorphous silicates, metal beads, and water at a low temperature (50–120 °C).  相似文献   

An evaluation of the contribution of soil micromorphology to the study of ancient arable agriculture     

S. P. Carter  D. A. Davidson 《Geoarchaeology》1998,13(6):535-547

This article provides an overview of the development of soil micromorphological studies of ancient agriculture and the current position of research in this field. The stance adopted by the authors is deliberately combative, and it is hoped that the article will stimulate discussion of the current limitations and potentialities of the technique. The findings of this review may be summarized in three proposals: (1) Soil micromorphology cannot be used at present to identify cultivation in ancient soils. Ambiguous or multiple interpretations of soil micromorphological features are unlikely to be resolved, so that the detection of large scale agricultural features in the field (cultivation marks, lynchets) will remain the most secure and direct guides to the presence of a former cultivated soil. Indirect evidence on inferred land use can be provided from pollen and land snail evidence. (2) Micromorphology should retain a key role in the determination of the impact of agriculture on soils, encompassing issues such as erosion, soil structure, fertility, and biological activity. These can be related to agricultural practice: methods of tillage, manuring, soil conservation, and fallowing. (3) Three areas of micromorphological research can be proposed that address the impact of agriculture on soil: (a) the study of well-sealed, buried agricultural soils which have a clearly understood archaeological context; (b) the study of recent soils with known agricultural histories; (c) the establishment of controlled experiments with ancient agricultural techniques. © 1998 John Wiley & Sons, Inc.  相似文献   

Obituary—John R. Booker     

John Carter  Chandra S. Desai  R. Kerry Rowe  Ian M. Smith  W. Wittke 《国际地质力学数值与分析法杂志》1998,22(6):421-423

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Benthic remineralization at the land–ocean interface: A case study of the Rhône River (NW Mediterranean Sea)     

Bruno Lansard  Christophe Rabouille  Lionel Denis  Christian Grenz   《Estuarine, Coastal and Shelf Science》2009,81(4):544-554

Biogeochemical processes in sediments under the influence of the Rhône River plume were studied using both in situ microelectrodes and ex situ sediment core incubations. Organic carbon (OC) and total nitrogen (TN) content as well as stable carbon isotopic composition of OC (δ¹³C_OC) were analysed in 19 surface sediments to determine the distribution and sources of organic matter in the Rhône delta system. Large spatial variations were observed in both the total O₂ uptake (5.2 to 29.3 mmol m⁻² d⁻¹) and NH₄⁺ release (−0.1 to −3.5 mmol m⁻² d⁻¹) rates at the sediment–water interface. The highest fluxes were measured near the Rhône River mouth where sedimentary OC and TN contents reached 1.81% and 0.23% respectively. Values of δ¹³C_OC ranged from −26.83‰ to −23.88‰ with a significant seawards enrichment tracing the dispersal of terrestrial organic matter on the continental shelf. The amount of terrestrial-derived OC reaches 85% in sediments close to the Rhône mouth decreasing down to 25% in continental shelf sediments. On the prodelta, high terrestrial OC accumulation rates support high oxygen uptake rates and thus indicating that a significant fraction of terrestrial OC is remineralized. A particulate organic carbon (POC) mass balance indicates that only 3% of the deposited POC is remineralized in prodelta sediments while 96% is recycled on the continental shelf. It was calculated that a large proportion of the Rhône POC input is either buried (52%) or remineralized (8%), mostly on the prodelta area. The remaining fraction (40%) is either mineralized in the water or exported outside the Rhône delta system in dissolved or particulate forms.  相似文献   

Cellular energy allocation in the Arctic sea ice amphipod Gammarus wilkitzkii exposed to the water soluble fractions of oil     

Olsen GH  Carroll J  Sva E  Camus L 《Marine environmental research》2008,66(1):213-214

Increasing offshore oil and gas activities in the European Arctic has raised concerns of the potential anthropogenic impact of oil-related compounds on the polar marine ecosystem. We measured cellular energy allocation (CEA) in the sea ice amphipod Gammarus wilkitzkii after exposure for one month to the water soluble fraction (WSF) of oil. The CEA biomarker measures the energy budget of organisms by biochemically assessing changes in carbohydrates, protein and lipid content as well as the electron transport system activity. A significantly higher protein content was observed in the medium dose compared to controls, while the total energy budget was not affected in G. wilkitzkii. This indicates that parts of the energy budget of G. wilkitzkii, which is a key species in the Arctic ecosystem, is affected by a WSF of oil.  相似文献   

Doppler imaging and surface differential rotation of young open cluster stars – I. HD 307938 (R58) in IC 2602     

S. C. Marsden  I. A. Waite  B. D. Carter  J.-F. Donati 《Monthly notices of the Royal Astronomical Society》2005,359(2):711-724

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An assessment of the bearing capacity of calcareous and silica sands     

S. K. Yeung  J. P. Carter 《国际地质力学数值与分析法杂志》1989,13(1):19-36

A spherical cavity expansion model has been used to study the bearing capacity of foundations on calcareous and silica sands. Two constitutive models have been used to represent each sand: an elastoplastic, collapse-softening model, and a computationally simpler, elastic/perfectly plastic material. The predictions of the limit pressures for spherical cavity expansion are compared with laboratory data on the bearing capacities obtained from model footing tests. It is shown that the numerical predictions of the limit pressures correlate well with the experimental values of bearing capacity, particularly at higher effective overburden pressures.  相似文献   

Meteoritic and other constraints on the internal structure and impact history of small asteroids     

Edward R.D. Scott  Lionel Wilson 《Icarus》2005,174(1):46-53

Studies of the internal structure of asteroids, which are crucial for understanding their impact history and for hazard mitigation, appear to be in conflict for the S-type asteroids, Eros, Gaspra, and Ida. Spacecraft images and geophysical data show that they are fractured, coherent bodies, whereas models of catastrophic asteroidal impacts, family and satellite formation, and studies of asteroid spin rates, and other diverse properties of asteroids and planetary craters suggest that such asteroids are gravitationally bound aggregates of rubble. These conflicting views may be reconciled if 10-50 km S-type asteroids formed as rubble piles, but were later consolidated into coherent bodies. Many meteorites are breccias that testify to a long history of impact fragmentation and consolidation by alteration, metamorphism, igneous and impact processes. Ordinary chondrites, which are the best analogs for S asteroids, are commonly breccias. Some may have formed in cratering events, but many appear to have formed during disruption and reaccretion of their parent asteroids. Some breccias were lithified during metamorphism, and a few were lithified by injected impact melt, but most are regolith and fragmental breccias that were lithified by mild or moderate shock, like their lunar analogs. Shock experiments show that porous chondritic powders can be consolidated during mild shock by small amounts of silicate melt that glues grains together, and by friction and pressure welding of silicate and metallic Fe,Ni grains. We suggest that the same processes that converted impact debris into meteorite breccias also consolidated asteroidal rubble. Internal voids would be partly filled with regolith by impact-induced seismic shaking. Consolidation of this material beneath large craters would lithify asteroidal rubble to form a more coherent body. Fractures on Ida that were created by antipodal impacts and are concentrated in and near large craters, and small positive gravity anomalies associated with the Psyche and Himeros craters on Eros, are consistent with this concept. Spin data suggest that smaller asteroids 0.6-6 km in size are unconsolidated rubble piles. C-type asteroids, which are more porous than S-types, and their analogs, the volatile-rich carbonaceous chondrites, were probably not lithified by shock.  相似文献   

Arbitrary Lagrangian–Eulerian method for large‐strain consolidation problems     

Majidreza Nazem  Daichao Sheng  John P. Carter  Scott W. Sloan 《国际地质力学数值与分析法杂志》2008,32(9):1023-1050

In this paper, an arbitrary Lagrangian–Eulerian (ALE) method is generalized to solve consolidation problems involving large deformation. Special issues such as pore‐water pressure convection, permeability and void ratio updates due to rotation and convection, mesh refinement and equilibrium checks are discussed. A simple and effective mesh refinement scheme is presented for the ALE method. The ALE method as well as an updated‐Lagrangian method is then used to solve some classical consolidation problems involving large deformations with different constitutive laws. The results clearly show the advantage and efficiency of the ALE method for these examples. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

In Situ measurement of transverse isotropy in shallow-water marine sediments     

Patricia A. Berge  Subhashis Mallick  Gerard J. Fryer  Noël Barstow  Jerry A. Carter  George H. Sutton  John I. Ewing 《Geophysical Journal International》1991,104(2):241-254

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