Kinetics of selenium release in mine waste from the Meade Peak Phosphatic Shale,Phosphoria Formation,Wooley Valley,Idaho, USA     

Lisa L. Stillings  Michael C. Amacher 《Chemical Geology》2010,269(1-2):113-123

Phosphorite from the Meade Peak Phosphatic Shale member of the Permian Phosphoria Formation has been mined in southeastern Idaho since 1906. Dumps of waste rock from mining operations contain high concentrations of Se which readily leach into nearby streams and wetlands. While the most common mineralogical residence of Se in the phosphatic shale is elemental Se, Se(0), Se is also an integral component of sulfide phases (pyrite, sphalerite and vaesite–pyrite_ss) in the waste rock. It may also be present as adsorbed selenate and/or selenite, and FeSe₂ and organo-selenides.Se release from the waste rock has been observed in field and laboratory experiments. Release rates calculated from waste rock dump and column leachate solutions describe the net, overall Se release from all of the possible sources of Se listed above. In field studies, Se concentration in seepage water (pH 7.4–7.8) from the Wooley Valley Unit 4 dump ranges from 3600 µg/L in May to 10 µg/L by Sept. Surface water flow, Q, from the seep also declines over the summer, from 2 L/s in May to 0.03 L/s in Sept. Se flux ([Se] ? Q) reaches a steady-state of < 150 mg/day in 1–4 months, depending upon the volume of Q. Se release (mg/L) follows a first order reaction with a rate constant, k, = 1.35 – 6.35e?3 h^? 1 (11.8–55.6 yr^? 1).Laboratory experiments were performed with the waste shale in packed bed reactors; residence time varied from 0.09 to 400 h and outlet pH ～ 7.5. Here, Se concentration increased with increasing residence time and release was modeled with a first order reaction with k = 2.19e?3 h^? 1 (19.2 yr^? 1).Rate constants reported here fall within an order of magnitude of reported rate constants for oxidation of Se(0) formed by bacterial precipitation. This similarity among rate constants from both field and laboratory studies combined with the direct observation of Se(0) in waste shales of the Phosphoria Formation suggests that oxidation of Se(0) may control steady-state Se concentration in water draining the Wooley Valley waste dump.  相似文献   

A liminal territory: Gaza,executive discretion,and sanctions turned humanitarian     

Lisa Bhungalia 《GeoJournal》2010,75(4):347-357

In September 2007 Israel’s security cabinet approved a ‘hostile entity’ classification for the Gaza Strip and intensified its economic and diplomatic blockade of this Hamas-controlled region. Taking the ‘hostile entity’ classification as a point of entry, this paper examines the construction of Gaza as an insurgent zone, a liminal space within which Israel’s executive discretion has authorizing force. Central to this process, it argues, is a blurring of lines between the civilian and combatant—the elimination of a purely civilian space. This paper begins with an analysis of the discursive strategies employed to collapse the space between the civilian body and battlefield in Gaza. It then turns to an examination of socio-spatial practices mobilized around the ‘hostile entity’ classification, foremost Israel’s sanctions policy, and argues this counter-insurgency strategy entails regulation and management of the Palestinian body combined with the active subjugation of Palestinian life to the power of death. Centrally, this paper attends to the relationship between geopolitics and violence at the scale of the (Palestinian) body.  相似文献   

October 8, 2005 Pakistan Earthquake： Preliminary observations and report of an international conference     

Mona Lisa A. B. Kausar Azam A. Khwaja M. Qasim Jan 《《幕》》2006,29(3):206-208

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Carolina Bay geoarchaeology and Holocene landscape evolution on the Upper Coastal Plain of South Carolina     

Mark J. Brooks  Barbara E. Taylor  John A. Grant 《Geoarchaeology》1996,11(6):481-504

Surface water on the mainly dry, upland interfluves of the Upper Coastal Plain of South Carolina occurs currently as a sporadic distribution of shallow ponds held within Carolina bays and other small, isolated basins. At seven bays on the U.S. Department of Energy's Savannah River Site on the Upper Coastal Plain of South Carolina, we investigated Holocene changes in bay morphology, ecology, and prehistoric human activity. At Flamingo Bay, we employed archaeological survey and testing, shovel and auger testing, sediment analysis, and ground-penetrating radar to document stratigraphy and chronology of the sand rim on the eastern side of the bay. Artifact assemblage indicate changes in intensity of human use of the bay. Radiocarbon dates from a sediment core establish time scales for depositional processes at the center of the basin. Ground-penetrating radar data from the other bays indicate that the stratigraphy of all seven bays is broadly similar. We conclude that: (1) Significant modification of the bays, including rim development and basin infilling, occurred during the Holocene; (2) ponds on the early Holocene landscape were larger and more permanent than at present; (3) early Holocene climate, as indicated by both depositional processes and human activity, was not characterized by prolonged periods of extremely dry conditions; and (4) fluvial-centric models of terminal Pleistocene—early Holocene human adaptations require revision to include intensive use of isolated upland ponds. © 1996 John Wiley & Sons, Inc.  相似文献   

Dietary niche separation of three Late Pleistocene bear species from Vancouver Island,on the Pacific Northwest Coast of North America     

Cara Kubiak  Vaughan Grimes  Geert Van Biesen  Grant Keddie  Mike Buckley  Reba Macdonald  M. P. Richards 《第四纪科学杂志》2023,38(1):8-20

Competition between taxa related to climate changes has been proposed as a possible factor in Pleistocene megafaunal extinctions, and here we present isotope evidence of the diets of three co-existing bear species [black bear (Ursus americanus), brown bear (Ursus arctos), and the now extinct short-faced bear (Arctodus simus)] from a locale in western North America dating to the Late (Terminal) Pleistocene (~14.5–11.7 ka). The three bear species were found at several sites on Vancouver Island, on the western coast of Canada. To examine the chronological overlap and niche partitioning between these species of bear, we used direct radiocarbon dating, stable isotope analysis and ZooMS proteomic identification methods. Here we present new radiocarbon evidence from Terminal Pleistocene U. americanus, U. arctos and A. simus from several sites on the island, along with both bulk collagen and compound-specific isotope data for these species. Radiocarbon dates confirm the chronological overlap of Arctodus and both Ursus species in the montane regions of the island at the end of the Pleistocene. Stable isotope data reveal niche differentiation between these species, with U. americanus occupying a distinctly lower trophic position than the other two taxa.  相似文献