Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances   总被引：2，自引：2，他引：0  

Alain Cocherie  Michle Robert 《Gondwana Research》2008,14(4):597

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.  相似文献   

Strain-softening behaviour of sand in strain path testing under plane-strain conditions     

D. Wanatowski  J. Chu  R. S.-C. Lo 《Acta Geotechnica》2008,3(2):99-114

Experimental data are presented in this paper to study the strain-softening behaviour of sand under plane-strain conditions. K ₀ consolidated strain path tests were conducted using a new plane-strain apparatus. The stress–strain behaviour of medium dense sand under plane-strain conditions was characterized. The test results show that the occurrence of pre-failure strain softening under plane-strain conditions is affected by the void ratio, the strain increment ratio and the initial effective confining stress. This is consistent with previous findings established under axisymmetric conditions. However, a pre-failure strain-softening behaviour in plane-strain tests conducted under high-confining stresses may consist of three stages, namely, material softening, banding softening, and ultimate state. This observation is different from that in triaxial tests where banding softening does not normally occur.  相似文献   

The geography of the elderly in a modernizing society: the Hong Kong case     

Lo CP 《Singapore journal of tropical geography》1984,5(1):1-20

The characteristics of the elderly population of Hong Kong are first described. Recent changes in the spatial distribution of the elderly are also detailed. The spatial distribution and internal migration patterns of the elderly are shown to be very similar to those of the population as a whole. The problems posed by the fact that many of the elderly are poorly educated and lowly paid are considered.  相似文献   

Petrogenesis of anomalous K-enriched MORB from the Southwest Indian Ridge: 11°53′E to 14°38′E     

Anton P le Roex  Henry J B Dick  Ronald T Watkins 《Contributions to Mineralogy and Petrology》1992,110(2-3):253-268

Glassy pillow basalts with unusual geochemical characteristics for mid-ocean ridge basalt (MORB) have been dredge sampled from the Southwest Indian Ridge between 12 and 15°E during Leg ANT IV/4 of the F.S. POLARSTERN. Lavas from 4 of 6 dredges are moderately nepheline normative, highly K-enriched (0.5–1.77 wt% K₂O) alkali basalts and hawaiites. Mg-numbers indicate that many of the lavas are fairly primitive (Mg No.=63–67), yet show extreme enrichment in incompatible elements; e.g. Nb (24–60 ppm), Ba (170–470 ppm) and Sr (258–460 ppm). Incompatible-element ratios such as Zr/Nb (3–5) and Y/Nb (0.46–1.1) are extremely low even for E-type (enriched) MORB, whereas (La/Yb)_n ratios are particularly high (3.4–7.8). ⁸⁷Sr/⁸⁶Sr (0.70290–0.70368), ¹⁴³Nd/¹⁴⁴Nd (0.51302–0.51284) and ²⁰⁶Pb/²⁰⁴Pb (18.708–19.564) isotopic ratios further indicate the geochemically enriched nature of these lavas, which range from the compositional field for depleted N-type (normal) MORB towards the composition of Bouvet Island lavas. Mutually correlated incompatible-element and Sr-, Nd- and Pb-isotopic ratios allow a fairly well constrained model to be developed for the petrogenesis of these unusually alkalic mid-ocean ridge lavas. The alkalic nature and degree of enrichment in incompatible elements is ascribed to particularly low degrees of partial melting (3–5 wt%), at greater than usual depth, of a source region that has experienced prior geochemical enrichment (by veining) related to the upwelling Bouvet mantle plume. To account for the observed compositional variations, a model is proposed whereby mixing between partial melts derived from these geochemically enriched silicate veins, and an incipient to low percentage (±2%) melt from the surrounding geochemically depleted suboceanic asthenosphere occurs as a consequence of increasing degree of melting with adiabatic upwelling. Eruption of these alkalic lavas in this spreading ridge environment is attributed to a temporary hiatus in tholeiitic volcanism and associated spreading along this section of the Southwest Indian Ridge, related to readjustment of spreading direction to a more stable plate geometry.  相似文献   

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

地震作用下的灰坝液化特征及其动力稳定性分析--以安阳电厂为例   总被引：1，自引：0，他引：1  

李永乐  陈宇  彭成山  刘宪亮 《地质科技情报》2002,21(1):83-86

根据安阳电厂灰坝岩土工程性质及其动力学特性,建立了适合灰坝工程的动力分析模型并采用有限元法进行了动力分析.在此基础上,在不同工况条件下对灰坝进行了抗液化安全评价及抗震稳定性分析.研究表明,在不设碎石桩、无排渗体条件下,粉煤灰子坝的抗液化安全系数Ks＜1.25,将发生液化;在设碎石桩、有排渗体条件下,粉煤灰子坝的抗液化安全系数明显提高,Ks≥1.25,不会发生液化.抗震稳定性分析表明,在上述两种工况条件下灰坝是稳定的.  相似文献   

Magnetic properties of a freshly fallen LL ordinary chondrite: the Bensour meteorite   总被引：1，自引：0，他引：1  

Jrme Gattacceca  Pierre Rochette  Michle Bourot-Denise 《Physics of the Earth and Planetary Interiors》2003,140(4):343-358

A comprehensive rock magnetic, magnetic anisotropy and paleomagnetic study has been undertaken in the brecciated LL6 Bensour ordinary chondrite, a few months only after its fall on Earth. Microscopic observations and electronic microprobe analyses indicate the presence of Ni-rich taenite, tetrataenite and rare Co-rich kamacite. Tetrataenite is the main carrier of remanence. Magnetization and anisotropy measurements were performed on mutually oriented 125 mm³ sub-samples. A very strong coherent susceptibility and remanence anisotropy is evidenced and interpreted as due to the large impact responsible for the post-metamorphic compaction of this brecciated material and disruption of the parent body. We show that the acquisition of remanent magnetization postdates metamorphism on the parent body and predates the entering of the meteorite in Earth’s atmosphere. Three components of magnetization could be isolated. A soft coherent component is closely related to the anisotropy of the meteorite and is interpreted as a shock remanent magnetization acquired during the same large impact on the parent body. Two harder components show random directions at a few mm scale. This randomness is attributed either to the formation mechanism of tetrataenite or to post-metamorphic brecciation. All components are likely acquired in very low (≈μT) to null ambient magnetic field, as demonstrated by comparison with demagnetization behavior of isothermal remanent magnetization. Two other LL6 meteorites, Kilabo and St-Mesmin, have also been studied for comparison with Bensour.  相似文献   

震后预报的某些研究     

吕培苓  孙士宏 《地震》1997,17(1):67-74

通过研究华北北部中强以上地震震后地震活动，地形变、地电阻率、水化学和水位变化特征，给出了各单项方法识别震后效应与新地震异常的标志。为了综合判别震后短临异常变化是震后效应或新异常，研制了一套综合识别计算机程序系统，该系统考虑了已发生的强震序列类型，地震活动背景特征以及强震前后前兆短临异常变化形态，充分利用专家的知识与经验进行推理和判断。通过运行典型事例表明该系统功能较强，使用方便。系统的实现是专家系  相似文献   

Petrogenesis of lavas from the AMAR Valley and Narrowgate region of the FAMOUS Valley, 36°–37°N on the Mid-Atlantic Ridge     

A. P. le Roex  Frederick A. Frey  Stephen H. Richardson 《Contributions to Mineralogy and Petrology》1996,124(2):167-184

Basaltic lavas from the AMAR Valley and the Narrowgate region of the FAMOUS Valley on the Mid-Atlantic Ridge (36° to 37°?N) range in texture from aphyric to highly plagioclase phyric (>25% large plagioclase phenocrysts). Based on ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios, most of these lavas can be subdivided into two distinct, isotopically homogeneous, groups: Group I has lower ⁸⁷Sr/⁸⁶Sr (0.70288±1) and higher ¹⁴³Nd/¹⁴⁴Nd (0.51312±1) ratios; Group II has higher ⁸⁷Sr/⁸⁶Sr (0.70296±1) and lower ¹⁴³Nd/¹⁴⁴Nd (0.51309±2) ratios. Most Group II lavas are aphyric, whereas Group I lavas are primarily plagioclase phyric. Lavas from both groups show a wide range in incompatible element abundance ratios (e.g., Zr/Nb =6–29; (La/Sm)_n=0.6–1.7). Aphyric lavas have relatively constant Sc (40±1.5?ppm) abundances and CaO/Al₂O₃ ratios (0.80±0.02). Group I lavas are confined primarily to the AMAR rift valley floor whereas Group II lavas are found along the east and west marginal highs. We interpret the isotopic differences between the two groups as reflecting a temporal change in the upwelling mantle beneath this region of the Mid-Atlantic Ridge which is south of the Azore Islands. For each group, a petrogenetic model consistent with the geochemical data is multi-stage decompression melting of an initially enriched, homogeneous, mantle source region. If the early derived, incompatible-element enriched, melt increments are not always pooled with subsequent increments, the erupted magma batches may have the major element characteristics of melts derived by 10 to 20% melting, but with incompatible element abundance ratios reflecting the change from an enriched to depleted source during the incremental melting process. In this process an initially homogeneous source can generate primary magmas with the required range in incompatible element abundance ratios shown by each group. The nearly constant CaO/Al₂O₃ ratios and Sc contents of the aphyric lavas with decreasing Mg?? reflects subsequent polybaric fractionation of clinopyroxene, plagioclase and olivine over the pressure interval 8–6?kbar (24–18?km), followed by rapid transport to the surface and eruption. There is no geochemical evidence for a crustal magma chamber beneath this section of the Mid-Atlantic Ridge.  相似文献   

Change of crustal gravitational potential energy in the Taiwan orogen by the Chi-Chi earthquake sequence     

Shu-Kun Hsu  Chung-Liang Lo 《Earth and Planetary Science Letters》2004,222(2):573-581

The active convergence between the northwest corner of the Philippine Sea Plate and the southeast margin of the Eurasian Plate has given rise to the Taiwan mountain-building and produced numerous earthquakes. Among the earthquakes, the 1999 Chi-Chi earthquake is the largest one recorded in the century. In this study, we examine the crustal gravitational potential energy (GPE) change in the Taiwan orogen caused by the Chi-Chi earthquake sequence, which was catalogued by the regional broadband seismometer array for a whole year. As a result, we find that the crust was going up and down randomly during the earthquake sequence, but an overall cumulative gain of the crustal GPE, +1.82×10¹⁶ J, was rapidly achieved in 1 month after the main shock. The crustal GPE was nearly still afterwards and reached +1.90×10¹⁶ J in 1 year. Spatially, although the main surface faulting has occurred in western Taiwan, the crustal GPE gain is mainly distributed in central Taiwan at the area where the existing crustal GPE is high and the existing lithospheric GPE is relatively low. The crustal GPE loss by the Chi-Chi earthquake sequence can also be observed and is generally distributed at both sides of the crustal GPE gain area. The crustal GPE gain mainly found in central Taiwan corroborates that the uplift of the Taiwan orogen is principally taking place in central Taiwan, rather than in the more hazardous western Taiwan.  相似文献