Computer simulation of Pb and Sr isotope evolution of the Earth's crust and upper mantle     

Richard Lee Armstrong  Steven M Hein 《Geochimica et cosmochimica acta》1973,37(1):1-18

Isotope evolution in a differentiated (crust and upper mantle) and chemically heterogeneous Earth has been computed for a model with isotopic exchange between crust and mantle at an exponentially decreasing rate. To simulate the effects of subduction, cells of crust and mantle are selected at random, their contents mixed and then redistributed into the cells from which they came—to give new chemically heterogeneous but momentarily isotopically homogeneous systems. Daughter isotopes in each cell grow according to equations appropriate for closed chemical systems. Rock age distributions and isotopic data created by the computer calculation mimic nature. Pb isotope data changes through geologic time are illustrated to demonstrate that two-stage interpretations applied to Pb data for rocks with complex histories may be misleading. The intercept of the Pb ore growth curve and regressions fit to Pb data gives minimum values only for the duration of heterogeneous $\text{U}\text{Pb}$ systems, not the time when heterogeneous distribution first occurred. An intercept derived time of about 3 b.y., in the Pb system is shown to be quantitatively compatible with an average $\text{Rb}\text{Sr}$ age of crustal rocks of 1.5 b.y. and with a constant degree of chemical heterogeneity for all of Earth history.  相似文献   

On Automated Geography!     

Marc P. Armstrong 《The Professional geographer》1993,45(4):440-442

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Replacement textures in CAI and implications regarding planetary metamorphism     

G.P Meeker  G.J Wasserburg  J.T Armstrong 《Geochimica et cosmochimica acta》1983,47(4):707-721

Textural and chemical features of five coarse-grained, calcium-aluminum-rich inclusions from the Allende meteorite indicate that some of the melilite in these inclusions was formed by a secondary metamorphic event and not by primary crystallization from a melt or by a sequential nebular condensation process. These inclusions contain embayed pyroxene surrounded by melilite. Physically separated pyroxene crystals are often in optical continuity indicating that they were once part of larger single crystals that have been partly replaced by melilite. Other evidences of metamorphism include reaction textures between melilite and spinel, and metamorphic textures such as kink-band-like features, lobate sutured grain boundaries, and 120° triple-points. This type of metamorphic process requires the addition of Ca which we propose came from calcite or by introduction of a fluid phase. We believe that the most likely environment for this metamorphic process is on a small planetary body, and not in the solar nebula. The results of this study are compatible with oxygen isotopic heterogeneities within CAI, and provide a mechanism for producing lower temperature alteration phases and the rim phases found in these inclusions. We conclude that planetary processes must thus be considered in the formation history of CAI, and that it is necessary to reconsider the classification system of these objects in light of the replacement process proposed here.  相似文献   

Time constraints for Mesoproterozoic upper amphibolite facies metamorphism in NW Namibia: a multi-isotopic approach     

Barbara Seth  Richard A. Armstrong  Annett Büttner  Igor M. Villa   《Earth and Planetary Science Letters》2005,230(3-4):355-378

This study presents the chronological evolution of the upper amphibolite facies Orue Unit in NW Namibia. Metasedimentary and meta-igneous rocks of the Orue Unit were investigated using the Pb–Pb stepwise leaching technique on garnet and rutile, U–Pb multi-grain analysis on rutile, Sm–Nd–Lu–Hf leaching technique on garnet, SHRIMP analysis on zircon and Ar–Ar dating on amphibole. Each of these techniques pertains to different processes that occurred before, during, or after the metamorphic peak. Our age data can be integrated with petrological constraints to provide a more complete understanding of the metamorphic cycle. Our pre-peak metamorphic zircon ages, peak metamorphic garnet ages and peak to late peak metamorphic amphibole ³⁹Ar–⁴⁰Ar ages bracket the upper amphibolite facies metamorphic event including hydration or dehydration processes into a time span of only ca. 20 Ma. The age data obtained by peak metamorphic mineral analyses cluster around 1340–1320 Ma. Based on age data and field observation, we interpret the upper amphibolite facies metamorphism as a large-scale regional mid-crustal event. Spot analyses of inherited zircon cores obtained by SHRIMP reflect the sedimentary origin of the respective rocks of the Orue Unit and derivation from Palaeoproterozoic protoliths. The metamorphic rocks south of the anorthositic Kunene Intrusive Complex (KIC) have previously been ascribed to the Palaeoproterozoic Epupa Complex at the SW margin of the Congo craton and were thus thought to be older than the Mesoproterozoic KIC. Our data show that the high-grade metamorphic overprint took place 30–50 Ma after emplacement of the KIC. Rutile growth ages of 1248 Ma in one sample reflect fluid activity which seems to be a local phenomenon since there is no other evidence of geological activity throughout the Orue Unit at that time. The rutile ages predate the emplacement of satellite intrusions in that area by 30 Ma and there is no causal relation between these two events.  相似文献   

Fire and vegetation history during the last 3800 years in northwestern Montana   总被引：1，自引：0，他引：1  

Mitchell J. Power  Cathy Whitlock  Patrick Bartlein  Lora R. Stevens 《Geomorphology》2006,75(3-4):420

Foy Lake in northwestern Montana provides a record of annual-to-decadal-scale landscape change. Sedimentary charcoal and pollen analyses were used to document fire and vegetation changes over the last 3800 years, which were then compared to similar records from AD 1880 to 2000. The long-term record at Foy Lake suggests shifts between forest and steppe as well as changes in fire regime that are likely the result of climate change. Fire activity (inferred from the frequency of charcoal peaks) averaged 18 fire episodes/1000 years from 3800 to 2125 cal year BP, and increased from 16 fire episodes/1000 years at 2125 cal year BP to 22 episodes/1000 years at 750 cal year BP, a period when the pollen data suggest that steppe vegetation yielded to increasing patches of forest cover. Between 2125 and 750 cal year BP, increased forest cover produced more background charcoal than before and after this period, when vegetation was dominated by steppe. Between 750 and 75 cal year BP steppe has expanded and fire episode frequency averaged 33 episodes/1000 years, increasing to a maximum of 40 episodes/1000 years at ca. 300 cal year BP and then decreasing to present levels. Since AD 1880, the pollen record indicates an increase in shrubs and grasses from AD 1895 to 1960 as a result of vegetation changes associated with timber harvesting and livestock grazing. No fires have been documented in the Foy Lake watershed since AD 1880. Charcoal from the extralocal fires of AD 1910, burning over 4,111,249 ha in Idaho, Montana, and Wyoming, however, is present in Foy Lake. Between AD 1970 and 2000, increased arboreal pollen in the record is consistent with observations that the forest has become more closed. The activities of Euro–Americans have led to a decline in forest cover between AD 1880 and 1970, followed by a recent increase as trees are now growing in areas previously occupied by steppe. Euro–Americans are likely the cause of a reduction in fire activity in watershed since AD 1880.  相似文献   

IGU Reports: International Geographical Union/Union Géographique Internationale     

Patrick Armstrong  Ute Wardenga 《GeoJournal》1998,44(2):175-175

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Comparing the robustness of ordinary kriging and lognormal kriging: Outlier resistance   总被引：1，自引：0，他引：1  

M. Armstrong  A. Boufassa 《Mathematical Geology》1988,20(4):447-457

Ordinary kriging is well-known to be optimal when the data have a multivariate normal distribution (and if the variogram is known), whereas lognormal kriging presupposes the multivariate lognormality of the data. But in practice, real data never entirely satisfy these assumptions. In this article, the sensitivity of these two kriging estimators to departures from these assumptions and in particular, their resistance to outliers is considered. An outlier effect index designed to assess the effect of a single outlier on both estimators is proposed, which can be extended to other types of estimators. Although lognormal kriging is sensitive to slight variations in the sill of the variogram of the logs (i.e., their variance), it is not influenced by the estimate of the mean of the logs.This paper was presented at MGUS 87 Conference, Redwood City, California, 14 April 1987.  相似文献   

“The Deterministic Side of Geostatistics” by A. G. Journel     

Margaret Armstrong 《Mathematical Geosciences》1985,17(8):855-859

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Origin, age and stratigraphic significance of distal fallout ash tuffs from the Carboniferous–Permian continental Saar–Nahe Basin (SW Germany)     

Stephan Königer  Volker Lorenz  Harald Stollhofen  Richard A. Armstrong 《International Journal of Earth Sciences》2002,91(2):341-356

Thin, widespread, fallout tuff layers interbedded within fluvio-lacustrine successions of the Carboniferous-Permian Saar-Nahe Basin provide important tephrostratigraphic markers. In addition, radiogeochronometric data derived from the tuffs serve as calibration points for the adjustment to regional chronostratigraphy and to numerical time scales. The Pappelberg-Tuff in the Meisenheim Formation (Glan Group) has been dated by U/Pb zircon SHRIMP technique at 297.0Dž.2 Ma. Taking the Carboniferous/Permian boundary at 296 Ma, the Meisenheim Formation coincides approximately with this boundary. Consequently, underlying strata, lithostratigraphically regarded as the basal part of the 'Rotliegend', chronostratigraphically belong to the Upper Carboniferous. Bed thicknesses, grain size and sorting characteristics of the tuffs and the absence of contemporaneously emplaced volcanics within the Saar-Nahe Basin point to an extrabasinal derivation of the wind-drifted volcanic ash. Decreasing grain sizes of juvenile pyroclastic particles towards the north suggest source areas south of the basin within 300 km distance. The majority of the tuffs are rhyolitic to rhyodacitic and indicate petrographic and geochemical affinities to Moldanubian S-type granitoids, in particular to highly differentiated two-mica granites, and related volcanic effusives. Within the time frame considered here, such potential source rocks were emplaced in the northern and central Black Forest (SW Germany) and the northern Vosges (E France) at 100-150 km distance south of the Saar-Nahe Basin.  相似文献   

Solubility behavior of alkali aluminosilicate components in aqueous fluids and silicate melts at high pressure and temperature     

Bjorn O. Mysen  Lora Armstrong 《Geochimica et cosmochimica acta》2002,66(12):2287-2297

The solubility behavior of K₂O, Na₂O, Al₂O₃, and SiO₂ in silicate-saturated aqueous fluid and coexisting H₂O-saturated silicate melts in the systems K₂O-Al₂O₃-SiO₂-H₂O and Na₂O-Al₂O₃-SiO₂-H₂O has been examined in the 1- to 2-GPa pressure range at 1100°C. Glasses of Na- and K-tetrasilicate compositions with 0, 3, and 6 mol% Al₂O₃ were used as starting materials. In both systems, the oxides dissolve incongruently in aqueous fluid and silicate melt. When recalculated to an anhydrous basis, the aqueous fluids are enriched in alkalis and depleted in silica and alumina relative to their proportions in the starting materials. The extent of incongruency is more pronounced in the Na₂O-Al₂O₃-SiO₂-H₂O system than in the K₂O-Al₂O₃-SiO₂-H₂O system.The partition coefficients of the oxides, D_oxide^fluid/melt, are linear and positive functions of the oxide concentration in the fluid for each composition. There is a slight dependence of the partition coefficients on bulk composition. No effect of pressure could be discerned. For alkali metals, the fluid/melt partition coefficients range from 0.06 to 0.8. For Al₂O₃ this range is 0.01 to 0.2, and for SiO₂, it is 0.01 to 0.32. For all compositions, D_K2O^fluid/melt∼D_Na2O^fluid/melt>D_SiO2^fluid/melt>D_Al2O3^fluid/melt for the same oxide concentration in the fluid. D_K2O^fluid/melt, D_Na2O^fluid/melt, and D_SiO2^fluid/melt correlate negatively with the Al₂O₃ content of the systems. This correlation is consistent with a solubility model of alkalis that involve associated KOH°, NaOH°, silicate, and aluminate complexes.  相似文献