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91.
This paper discusses the effects of water quality on the hydrological and erosion response of non‐saline, non‐sodic soils during simulated rain experiments. It is well known that rain water quality affects the behaviour of saline soils. In particular, rain simulation experiments cannot be run using tap water if realistic values of infiltration rates and soil erosion are to be found. This paper reports on similar effects for non‐saline, non‐sodic soils. Two soils – a well‐aggregated clay‐rich soil developed on marine silty clay deposits and a soil developed on silt loam – were selected and subjected to a series of simulated rainstorms using demineralized water and tap water. The experiments were conducted in two different laboratories in order to obtain results independent of the tap water quality or the rainfall simulator characteristics. The results indicate that time‐to‐ponding is largely delayed by solute‐rich water (tap water). When tap water is used, infiltration rates are significantly overestimated, i.e. by more than 100 per cent. Interrill erosion rates increase by a factor of 2·5–3 when demineralized water is used. The silty clay soil was more affected by the water quality than the silt loam soil, with respect to infiltration and runoff production. Regarding interrill erosion rates, the two tested soils were similarly affected by the water quality. Therefore, it can be concluded that rainfall simulation experiments with non‐dispersive soils (e.g. non‐saline, non‐sodic) must also be conducted using water with very low electrical conductivity (i.e. less than 30–50 µS cm−1), close to that of distilled water. The use of tap water certainly hampers comparisons and the relative ranking of the hydrological and erosion response of different soils, while parameter values, such as final infiltration rate or time‐to‐ponding, cannot be extrapolated and extended to natural situations. Therefore, the majority of hydrological and erosion models and parameter values measured during rainfall simulations in the past should be used with caution for all types of soils. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
92.
A numerical approach is presented for the ‘identification’ (or back calculation) of the earth pressure acting on embedded or retaining structures. The procedure is applicable to structures of any shape and requires a set of in situ measurements that may include displacements of points on the structure, values of concentrated forces, values of distributed loads at some locations, etc. Possible limiting values of the unknown loads, non-linear structural behaviour, varying accuracies of the input data are accounted for in the problem formulation. Depending upon the type of problem, the solution is reached by means of the unconstrained or constrained minimization of a suitably defined error function. As an example, the proposed approach is applied to the identification of the earth pressure acting on some typical geotechnical engineering structures.  相似文献   
93.
A 2D depth‐averaged model has been developed for simulating water flow, sediment transport and morphological changes in gravel‐bed rivers. The model was validated with a series of laboratory experiments and then applied to the Nove reach of the Brenta River (Northern Italy) to assess its bed material transport, interpret channel response to a series of intensive flood events (R.I. ≈ 10 years) and provide a possible evolutionary scenario for the medium term. The study reach is 1400 m long with a mean slope of 0.0039 m m?1. High‐resolution digital terrain models were produced combining LiDAR data with colour bathymetry techniques. Extensive field sedimentological surveys were also conducted for surface and subsurface material. Data were uploaded in the model and the passage of two consecutive high intensity floods was simulated. The model was run under several hypotheses of sediment supply: one considering substantial equilibrium between sediment input and transport capacity, and the others reducing the sediment supply. The sediment supply was then calibrated comparing channel morphological changes as observed in the field and calculated by the model. Annual bed material transport was assessed and compared with other techniques. Low‐frequency floods (R.I. ≈ 1.5 years) are expected to produce negligible changes in the channel while high floods may erode banks rather than further incising the channel bed. Location and distribution of erosion and deposition areas within the Nove reach were predicted with acceptable biases stemming from imperfections of the model and the specified initial, boundary and forcing conditions. A medium‐term evolutionary scenario simulation underlined the different response to and impact of a consecutive sequence of floods. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
94.
Heterogeneity in genetic composition among recruits, mostly due to a large variance in reproductive success mediated by oceanographic processes, has been reported for marine species but is less understood in coastal lagoons' organisms. Temporal genetic variation in natural populations of the Mediterranean shore crab Carcinus aestuarii was quantified over a multi-year sample. A total of 486 adult crabs were collected at eight different sites of the Venice Lagoon during the period 2005–2007 and screened for genetic variation using 11 microsatellite loci. Two additional samples (N = 115) from neighbouring sites, located approximately 100 km North and South to the Venice Lagoon, were included for the sake of comparison. Our results show significant differences in allelic frequencies at the micro-geographic scale of the Venice Lagoon, observed between sites of collection, typologies of habitat, and areas with different class of ecological risk or pattern of hemocyanin expression. However, this pattern was not constant between years, with significant differences observed mainly in 2005 and 2006, but not in 2007. Our results indicate significant temporal differences suggesting the existence of dynamic processes that act on the genetic pool of this species. Although natural selection and gene flow might play a role, we suggest that genetic drift linked to large variation in the reproductive success of individuals is the most probable scenario to explain the local genetic patterns of differentiation in the Mediterranean shore crab. Our study, by providing the first evidence for the existence of genetic differences in this species at the micro-geographic scale, suggests that a better comprehension of the link between reproduction, recruitment and oceanography is critical to understand how colonization and maintenance of genetic variation is achieved in ephemeral and vulnerable environments such as coastal lagoons.  相似文献   
95.
WASP-33 is a fast rotating, main sequence star which hosts a hot Jupiter moving along a retrograde and almost polar orbit with semi-major axis a=0.02 au and eccentricity provisionally set to e=0. The quadrupole mass moment J2*J_{2}^{\star} and the proper angular momentum S of the star are 1900 and 400 times, respectively, larger than those of the Sun. Thus, huge classical and general relativistic non-Keplerian orbital effects should take place in such a system. In particular, the large inclination Ψ of the orbit of WASP-33b to the star’s equator allows to consider the node precession [(W)\dot]\dot{\Omega} and the related time variation dt d /dt of the transit duration t d . The WASP-33b node rate due to J2*J_{2}^{\star} is 9×109 times larger than the same effect for Mercury induced by the Sun’s oblateness, while the general relativistic gravitomagnetic node precession is 3×105 times larger than the Lense-Thirring effect for Mercury due to the Sun’s rotation. We also consider the effect of the centrifugal oblateness of the planet itself and of a putative distant third body X. The magnitudes of the induced time change in the transit duration are of the order of 3×10−6,2×10−7,8×10−9 for J2*J_{2}^{\star}, the planet’s rotational oblateness and general relativity, respectively. A yet undiscovered planet X with the mass of Jupiter orbiting at more than 1 au would induce a transit duration variation of less than 4×10−9. A conservative evaluation of the accuracy in measuring dt d /dt over 10 yr points towards ≈10−8. The analysis presented here will be applicable also to other exoplanets with similar features if and when they will ne discovered.  相似文献   
96.
The Canan area (Honduras) is characterized by a gold-bearing ore deposit that is associated with quartz-veined shear zones. Gold mineralization occurs in low-to medium-grade metamorphic host-rocks (graphitic and sericitic schists). Hydrothermal fluids, which are associated with the emplacement of Cretaceous-Tertiary granodioritic intrusions, are responsible for the formation of quartz veins and the hydrothermal alteration of wall-rocks. Three main altered zones have been detected in the wall-rocks as far as 150 cm from the quartz veins. The distal zone (up to 50-cm thick) contains quartz, chlorite and illite. The intermediate zone is the thickest (up to 80 cm) and is marked by quartz, muscovite, sulphides, kaolinite and native elements such as Au and Ag. The proximal zone, which is close to the quartz veins, is rather thin (up to 25 cm) and contains clay minerals, Al-oxides-hydroxides and sulphides. The transition from the distal to the proximal zone is accompanied by the enrichment of SiO2 and the depletion of all other major elements, except for Fe2O3(tot). Precious metals occur in the highest concentrations in the intermediate zone (Au up to 7.6 ppm and Ag up to 11 ppm). We suggest that gold was transported as a reduced sulphur complex and was precipitated from the hydrothermal solution by the reaction of the sulphur complexes with Fe2+ from the alteration of the mafic minerals of the host-rock. Fluid–wall-rock interactions seem to be the main cause of gold mineralization. Genetic relationships with a strike-slip fault system, hydrothermal alteration zones within the metamorphic wall-rocks, and an entire set of geochemical anomalies are consistent with orogenic-type gold deposits of the epizonal class.  相似文献   
97.
New structural and stratigraphic data for a selected area of the Ligurian Alps are combined in order to assess and discuss the role played by extensional structures in the southernmost segment of the Western Alps during thrusting. Restored cross-sections and field data suggest that the structural style in the external sector of the chain may depend upon the presence of pre-orogenic normal faults ascribed to three extensional events linked to different geodynamic contexts: (i) Permian post-Variscan plate reorganisation, (ii) Mesozoic rifting–drifting phases leading to the opening of the Alpine Tethys, and (iii) Eocenic development of the European foreland basins. During positive inversion in Eocene times, a thin-skinned thrust system developed in this area, followed by a thick-skinned phase. In both situations the inherited extensional structures played fundamental roles: during the thin-skinned phase they conditioned the thrusting sequence, also producing large-scale buckle folds and partial reactivations; during the thick-skinned phase the strain was compartmentalized and partitioned by pre-existing faults.The kinematic model of the external sectors of the Ligurian chain also allows the re-assessment of the Alpine evolution of the front-foreland transition, including: (i) indirect confirmation that in the Eocene the Ligurian Briançonnais and Dauphinois domains were not separated by the Valais-Pyrenean oceanic basin; (ii) that the thin-skinned phase progressively changed into thick-skinned; (iii) the assertion that there were no significant deformations from the Oligocene to the present-day, and the Corsica–Sardinia block rotation only produced a change in orientation of previously formed structures and normal fault system development.  相似文献   
98.
Average proton binding constants (KH,i) for structure models of humic (HA) and fulvic (FA) acids were estimated semi-empirically by breaking down the macromolecules into reactive structural units (RSUs), and calculating KH,i values of the RSUs using linear free energy relationships (LFER) of Hammett. Predicted log KH,COOH and log KH,Ph-OH are 3.73 ± 0.13 and 9.83 ± 0.23 for HA, and 3.80 ± 0.20 and 9.87 ± 0.31 for FA. The predicted constants for phenolic-type sites (Ph-OH) are generally higher than those derived from potentiometric titrations, but the difference may not be significant in view of the considerable uncertainty of the acidity constants determined from acid-base measurements at high pH. The predicted constants for carboxylic-type sites agree well with titration data analyzed with Model VI (4.10 ± 0.16 for HA, 3.20 ± 0.13 for FA; Tipping, 1998), the Impermeable Sphere model (3.50-4.50 for HA; Avena et al., 1999), and the Stockholm Humic Model (4.10 ± 0.20 for HA, 3.50 ± 0.40 for FA; Gustafsson, 2001), but differ by about one log unit from those obtained by Milne et al. (2001) with the NICA-Donnan model (3.09 ± 0.51 for HA, 2.65 ± 0.43 for FA), and used to derive recommended generic values. To clarify this ambiguity, 10 high-quality titration data from Milne et al. (2001) were re-analyzed with the new predicted equilibrium constants. The data are described equally well with the previous and new sets of values (R2 ? 0.98), not necessarily because the NICA-Donnan model is overparametrized, but because titration lacks the sensitivity needed to quantify the full binding properties of humic substances. Correlations between NICA-Donnan parameters are discussed, but general progress is impeded by the unknown number of independent parameters that can be varied during regression of a model fit to titration data. The high consistency between predicted and experimental KH,COOH values, excluding those of Milne et al. (2001), gives faith in the proposed semi-empirical structural approach, and its usefulness to assess the plausibility of proton stability constants derived from simulations of titration data.  相似文献   
99.
The “genetic erosion” hypothesis posits that heavy metal stress is related to a loss of genetic diversity at the population level. The genetic diversity of natural populations can, however, be affected by natural processes as well as by human impact. We studied the relationship between heavy metal bioaccumulation and genetic variability in the intertidal crab Pachygrapsus marmoratus. Tissue samples were collected from 40 individuals inhabiting four polluted and four unpolluted sites along the Tuscan coast (Mediterranean basin), and were examined for four heavy metals (arsenic, As, cadmium, Cd, lead, Pb, and copper, Cu). We also assessed the genetic variability of 235 crabs from the same localities using six microsatellite loci.Our results show that the bioaccumulation levels of these individuals accurately reflect the levels of pollution in their immediate environment, and that heavy metals accumulate more in the hepatopancreas than in the gills. Moreover, populations from polluted sites have significantly less genetic variability, measured as mean standardized d2, and a significantly lower percentage of unrelated individuals, than populations from unpolluted sites. This evidence supports the “genetic erosion” hypothesis for metal heavy exposure in natural environments.  相似文献   
100.
We consider inhomogeneous viscous fluids in flat Friedmann-Robertson-Walker universe. We analyze different kinds of such fluids and investigate the possibility to reproduce the current cosmic acceleration providing a different future evolution with respect to the Cosmological Constant case. In particular, we study the presence of finite-future time singularities. We also discuss a general class of “integrable” viscous fluid models whose bulk viscosities obey to a common differential equation.  相似文献   
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