Tracking the sources and fate of nitrate pollution by combining hydrochemical and isotopic data with a statistical approach     

Christiaens  Louis  Orban  Philippe  Brouyère  Serge  Goderniaux  Pascal 《Hydrogeology Journal》2023,31(5):1271-1289

This study contributes to identifying and spatializing the different types of nitrate sources by combining hydrogeochemical and isotopic data with principal component analysis (PCA) and t-distributed stochastic neighbor embedding (t-SNE) multicriteria statistical methods. The methodology is applied to the strategic Mons Basin chalk aquifer (Belgium). The results are based on a whole dataset containing 72 water samples with analyses of the hydrogeochemical parameters (temperature, pH, electrical conductivity (EC), redox potential, dissolved O₂), alkalinity, total organic carbon (TOC), silica (SiO₂), major and minor ions (NO₃^–, NH⁴⁺, Ca²⁺, dissolved Fe and Mn, K⁺, Mg²⁺, Na⁺, Sr²⁺, Cl^–, F^–, SO₄^–_, B) and multiple stable isotope ratios (δ¹¹B, δ¹⁵N–NO₃^–, δ¹⁸O–NO₃^–). Compared to classical PCA, the recently developed t-SNE method, which considers nonlinear relationships between variables and preserves local-scale similarities in a low-dimensional space, showed much better performance in discriminating different groups of samples and related zones in the aquifer. t-SNE results combined with isotope ratios highlighted four zones in the aquifer (grouped as A–D) and the presence of denitrification fronts. Group A presents a manure signature (δ¹⁵N–NO₃^– – mean (μ) +12.78‰, standard deviation (σ) 6.48‰; δ¹¹B – μ 29.96‰, σ 6.91‰). Group B exhibits both manure and inorganic fertilizer signatures (δ¹⁵N–NO₃^– – μ 6.27‰, σ 2.55‰; δ¹¹B – μ 15.86‰, σ 9.69‰). Group C shows a contamination by sewage (δ¹⁵N–NO₃^– – μ 12.67‰, σ 5.60‰; δ¹¹B – μ 9.97‰, σ 7.08‰). Group D presents a mixed signature (δ¹⁵N–NO₃^– – μ 9.25‰, σ 2.94‰; δ¹¹B – μ 20.00‰, σ 6.70‰).

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Optimization of Subsurface Flow Operations Using a Dynamic Proxy Strategy     

Ma  Zhiwei  Kim  Yong Do  Volkov  Oleg  Durlofsky  Louis J. 《Mathematical Geosciences》2022,54(8):1261-1287

Mathematical Geosciences - Machine-learning-based proxy models are often used to replace many of the flow simulations required in optimizations of subsurface flow processes. Because the optimizer...  相似文献   

Sedimentary Processes and Depositional Characteristics of Coarse-grained Subaqueous Fans along Steep Slopes in a Lacustrine Rift Basin: A Case Study from the Dongying Depression, Bohai Bay Basin, China     

YANG Baoliang  QIU Longwei  YANG Yongqiang  Kouassi Louis KRA  DONG Daotao  Danish KHAN 《《地质学报》英文版》2023,97(2):526-547

Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin, China. The insufficient understanding of their sedimentary processes, depositional patterns, and controlling factors restricts efficient exploration and development. Coarse-grained subaqueous fans in the Yong′an area, Dongying Depression, are investigated in this study. These fans include nearshore subaqueous fans, and sublacustrine fans, and their sedimentary processes, depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology. Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence. Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction. While the topography was gentle, sublacustrine fans did not develop. During the late weak tectonic activity stage, late sublacustrine fans developed with multiple stages superimposed. Frequent fault activity and related earthquakes steepened the basin margin, and the boundary fault slopes were 25.9°–34°. During the early–middle deposition stage, hyperpycnal flows triggered by outburst floods developed. During the late deposition stage, with weak tectonic activity, seasonal floods triggered hyperpycnal flows, and hybrid event beds developed distally.  相似文献   

Comprehensive framework for gradient-based optimization in closed-loop reservoir management     

Vladislav Bukshtynov  Oleg Volkov  Louis J. Durlofsky  Khalid Aziz 《Computational Geosciences》2015,19(4):877-897

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A case history of field pumping tests in a deep gravel formation in the Taipei Basin,Taiwan     

James C. Ni  Wen-Chieh Cheng  Louis Ge 《Engineering Geology》2011,117(1-2):17-28

33 large-diameter wells embedded in 2-m thick, 63-m deep diaphragm walls were constructed to reduce both the uplift pressures and the groundwater inflow during the excavations. As the actual thickness of the pumped aquifer is unknown, the installed wells are regarded as partial penetration wells. Single-well and multi-well pumping tests were conducted in the deep gravel formation of Taipei Basin to derive the hydraulic parameters and to investigate the drawdown characteristics at both the construction and remote sites. However, the tidal effect on the drawdown of both the pumping well and nearby observation wells was found significant. Additionally, wellbore storage, skin, and leakage need to be taken into account for deriving the hydraulic parameters. Hence, a method to remove these five factors influencing the drawdown curve is developed, which takes advantage from the late-time characteristics of drawdown data and the early-time behavior of drawdown. Some currently available semi-log graphic techniques are therefore proven applicable for parameter determination. Validity of the proposed method is verified by the good agreement between the calculated and the measured drawdown of both the pumping well and observation well.  相似文献   

Statistical assignment of upscaled flow functions for an ensemble of geological models   总被引：1，自引：0，他引：1  

Yuguang Chen  Kwangwon Park  Louis J. Durlofsky 《Computational Geosciences》2011,15(1):35-51

Upscaled flow functions are often needed to account for the effects of fine-scale permeability heterogeneity in coarse-scale simulation models. We present procedures in which the required coarse-scale flow functions are statistically assigned to an ensemble of upscaled geological models. This can be viewed as an extension and further development of a recently developed ensemble level upscaling (EnLU) approach. The method aims to efficiently generate coarse-scale flow models capable of reproducing the ensemble statistics (e.g., cumulative distribution function) of fine-scale flow predictions for multiple reservoir models. The most expensive part of standard coarsening procedures is typically the generation of upscaled two-phase flow functions (e.g., relative permeabilities). EnLU provides a means for efficiently generating these upscaled functions using stochastic simulation. This involves the use of coarse-block attributes that are both fast to compute and correlate closely with the upscaled two-phase functions. In this paper, improved attributes for use in EnLU, namely the coefficient of variation of the fine-scale single-phase velocity field (computed during computation of upscaled absolute permeability) and the integral range of the fine-scale permeability variogram, are identified. Geostatistical simulation methods, which account for spatial correlations of the statistically generated upscaled functions, are also applied. The overall methodology thus enables the efficient generation of coarse-scale flow models. The procedure is tested on 3D well-driven flow problems with different permeability distributions and variable fluid mobility ratios. EnLU is shown to capture the ensemble statistics of fine-scale flow results (water and oil flow rates as a function of time) with similar accuracy to full flow-based upscaling methods but with computational speedups of more than an order of magnitude.  相似文献   

The GREGOR Fabry‐Pérot Interferometer     

K.G. Puschmann  C. Denker  F. Kneer  N. Al Erdogan  H. Balthasar  S.M. Bauer  C. Beck  N. Bello Gonzlez  M. Collados  T. Hahn  J. Hirzberger  A. Hofmann  R.E. Louis  H. Nicklas  O. Okunev  V. Martínez Pillet  E. Popow  T. Seelemann  R. Volkmer  A.D. Wittmann  M. Woche 《Astronomische Nachrichten》2012,333(9):880-893

The GREGOR Fabry‐Pérot Interferometer (GFPI) is one of three first‐light instruments of the German 1.5‐meter GREGOR solar telescope at the Observatorio del Teide, Tenerife, Spain. The GFPI uses two tunable etalons in collimated mounting. Thanks to its large‐format, high‐cadence CCD detectors with sophisticated computer hard‐ and software it is capable of scanning spectral lines with a cadence that is sufficient to capture the dynamic evolution of the solar atmosphere. The field‐of‐view (FOV) of 50″×38″is well suited for quiet Sun and sunspot observations. However, in the vector spectropolarimetric mode the FOV reduces to 25″×38″. The spectral coverage in the spectroscopic mode extends from 530–860 nm with a theoretical spectral resolution of R ≈250 000, whereas in the vector spectropolarimetric mode the wavelength range is at present limited to 580–660 nm. The combination of fast narrow‐band imaging and post‐factum image restoration has the potential for discovery science concerning the dynamic Sun and its magnetic field at spatial scales down to ∼50 km on the solar surface (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

The development of the Space Environment Viability of Organics (SEVO) experiment aboard the Organism/Organic Exposure to Orbital Stresses (O/OREOS) satellite     

Nathan E. Bramall  Richard Quinn  Andrew Mattioda  Kathryn Bryson  Julie D. Chittenden  Amanda Cook  Cindy Taylor  Giovanni Minelli  Pascale Ehrenfreund  Antonio J. Ricco  David Squires  Orlando Santos  Charles Friedericks  David Landis  Nykola C. Jones  Farid Salama  Louis J. Allamandola  Søren V. Hoffmann 《Planetary and Space Science》2012,60(1):121-130

The Space Environment Viability of Organics (SEVO) experiment is one of two scientific payloads aboard the triple-cube satellite Organism/ORganic Exposure to Orbital Stresses (O/OREOS). O/OREOS is the first technology demonstration mission of the NASA Astrobiology Small Payloads Program. The 1-kg, 1000-cm³ SEVO cube is investigating the chemical evolution of organic materials in interstellar space and planetary environments by exposing organic molecules under controlled conditions directly to the low-Earth orbit (LEO) particle and electromagnetic radiation environment. O/OREOS was launched on November 19, 2010 into a 650-km, 72°-inclination orbit and has a nominal operational lifetime of six months. Four classes of organic compounds, namely an amino acid, a quinone, a polycyclic aromatic hydrocarbon (PAH), and a metallo-porphyrin are being studied. Initial reaction conditions were established by hermetically sealing the thin-film organic samples in self-contained micro-environments. Chemical changes in the samples caused by direct exposure to LEO radiation and by interactions with the irradiated microenvironments are monitored in situ by ultraviolet/visible/near-infrared (UV/VIS/NIR) absorption spectroscopy using a novel compact fixed-grating CCD spectrometer with the Sun as its light source. The goals of the O/OREOS mission include: (1) demonstrating key small satellite technologies that can enable future low-cost astrobiology experiments, (2) deploying a miniature UV/VIS/NIR spectrometer suitable for in-situ astrobiology and other scientific investigations, (3) testing the capability to establish a variety of experimental reaction conditions to enable the study of astrobiological processes on small satellites, and (4) measuring the chemical evolution of organic molecules in LEO under conditions that can be extrapolated to interstellar and planetary environments. In this paper, the science and technology development of the SEVO instrument payload and its measurements are described.  相似文献   

Validate global mapping of internal lunar magnetic field     

Mohamed Sharif Berguig  Mohamed Hamoudi  Jean Louis Lemouël  Yves Cohen 《Arabian Journal of Geosciences》2013,6(4):1063-1072

In this work, we report a global mapping of vector lunar magnetic field based on new method of separation of internal and external fields. The magnetic measurements collected during the lifetime of lunar prospector (LP) extended mission during 1999 were strongly disturbed by the solar wind, a period which coincided with a maximum of the 23 cycle activity. The multiscale wavelength external fields were analyzed using spherical harmonic transform. The external field determined by inversion was then removed from each magnetic field component for each half orbit. To map the vector magnetic crustal anomalies, all LP magnetometer data collected at low altitudes in the three different lunar environments: (1) geomagnetic tail, (2) solar wind, and (3) geomagnetic sheath were processed using this new approach. The results obtained using these selection criteria allow us to get a global coverage of the lunar surface by the vector magnetic field at variable spacecraft low altitudes. To validate our mapping, we have developed and applied a method based on properties of potential fields functions. This method can be used to determine both horizontal north and east components using only vertical component. The validated lunar internal magnetic measurements obtained at variable spacecraft altitudes were then continued to a common altitude of 30 km using an inverse method. This mapping confirms firstly the nature of the crustal sources of lunar magnetic field and clearly shows that the strongest concentrations of anomalies are associated with high albedo and/or located antipodal to large young basins (Orientale, Serenitatis, Imbrium, and Crisium) of age about 3.9 Ga.  相似文献   

Comment on “Changes in sulfides and platinum-group minerals with the degree of alteration in the Roby, Twilight, and High Grade Zones of the Lac des Iles Complex, Ontario, Canada” by MLN Djon and SJ Barnes     

Louis J. Cabri 《Mineralium Deposita》2012,47(8):949-952

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