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381.
Metal contamination of estuarine sediments is an increasing problem in Florida and elsewhere as urbanization extends into previously undeveloped areas. Effective estuarine management practices require scientifically valid tools to assess the extent of estuarine contamination. Interpretation of anthropogenic metal contributions has been hampered by the fact that natural metal concentrations in sediments vary by orders of magnitude in different sediments. Normalization of metal concentrations to a reference element, aluminum, appears to be a promising method for comparing estuarine sediment metal concentrations on a regional basis. In this paper we describe an interpretive method based on the relationship between sediment metals and aluminum derived from statewide data on natural estuarine sediments in Florida. We show how the method can be used to interpret metal concentrations with an example using data from the Miami River and Biscayne Bay.  相似文献   
382.
The problem of identifying areas of accelerated erosion in a dynamic landscape is complicated. The limited history of sediment yield measurements makes this task difficult even if geomorphic evidence is available. Beryllium-10, a cosmogenic isotope produced by cosmic rays interacting with the earth's atmosphere and surface, has chemical and physical properties that make it useful as a tracer for erosion and sediment transport processes. The rarity of the stable isotope, 9Be, allows 10Be to be detected with accelerator mass spectrometry in natural materials at extremely low levels. Backgrounds for rocks and sediments below 105 atom per g are now attainable, a value to be compared with an average deposition rate of 1.3 × 106 atom cm?2 yr?1. The affinity of Be for the components of soil and sediment is sufficiently high that it is effectively immobilized on contact, thereby allowing 10Be to function as a tracer of sediment transport. To a good approximation all the 10Be transport out of a drainage basin is on the sediment leaving it. The number of 10Be atoms passing the gauging station can be determined by measuring the concentration of the isotope in the sediment, if the annual sediment load is known. The ratio of the 10Be carried from the basin by the sediment to that incident upon it, called the erosion index, has been determined for 48 drainage basins within the same physiographic province, which allows them to be reasonably compared, all of which have sediment yield data. Basins located in the Atlantic coastal plain have an average index of 0.3 with the maximum observed being 0.9. Basins located between the fall line and the mountains, a region called the Piedmont, have an average value of 2.2 with individual values ranging from 0.6 to 6.7; this marked difference is thought to result from two centuries of farming on land of moderate gradient. Basins in the highland regions reflect local conditions with low indices for those in grass and timber and high indices associated with destructive land use. The data allow an estimate of the erosion index for the pre-colonial Piedmont, which then allows the pre-colonial sediment yield to be calculated. A number of basins have also been examined world wide with similar conclusions derived. An important deviation from the rule is noted for rivers that erode large regions of loess, such as the Mississippi, Hwang Ho, and Yangtze. Large aeolian deposits were laid down during the ice age in these basins, deposits that brought inherited 10Be with them and that are easily eroded.  相似文献   
383.
In this work, we report a global mapping of vector lunar magnetic field based on new method of separation of internal and external fields. The magnetic measurements collected during the lifetime of lunar prospector (LP) extended mission during 1999 were strongly disturbed by the solar wind, a period which coincided with a maximum of the 23 cycle activity. The multiscale wavelength external fields were analyzed using spherical harmonic transform. The external field determined by inversion was then removed from each magnetic field component for each half orbit. To map the vector magnetic crustal anomalies, all LP magnetometer data collected at low altitudes in the three different lunar environments: (1) geomagnetic tail, (2) solar wind, and (3) geomagnetic sheath were processed using this new approach. The results obtained using these selection criteria allow us to get a global coverage of the lunar surface by the vector magnetic field at variable spacecraft low altitudes. To validate our mapping, we have developed and applied a method based on properties of potential fields functions. This method can be used to determine both horizontal north and east components using only vertical component. The validated lunar internal magnetic measurements obtained at variable spacecraft altitudes were then continued to a common altitude of 30 km using an inverse method. This mapping confirms firstly the nature of the crustal sources of lunar magnetic field and clearly shows that the strongest concentrations of anomalies are associated with high albedo and/or located antipodal to large young basins (Orientale, Serenitatis, Imbrium, and Crisium) of age about 3.9 Ga.  相似文献   
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385.
A C25 highly branched isoprenoid (HBI) monoene hydrocarbon, designated IP25, has been proposed previously to originate from diatoms living in Arctic sea ice, while the presence of IP25 in sediments has been suggested to be a proxy for the occurrence of former Arctic sea ice. Here, we show that the 13C isotopic composition of IP25 in sea ice, in sediment trap material collected under sea ice, and in high latitude northern sediments, is distinctive (isotopically ‘heavy’) and distinguishable from that of organic matter of planktonic or terrigenous origin. Mean δ13C values for IP25 were − 22.3 ± 0.4‰ (sea ice), − 19.6 ± 1.1‰ (sediment traps) and − 19.3 ± 2.3‰ (sediments). These measurements, therefore, support further the proposed use of IP25 as an Arctic sea ice proxy.  相似文献   
386.
Abstract— Synthetic MgSiO3 glasses were irradiated at room temperature by 300 keV electrons in a transmission electron microscope (TEM). One of the samples had been previously irradiated by 50 keV He+ ions. Electron irradiation induces the nucleation and growth of randomly oriented nanometer‐sized crystallites. The crystallites first consist of MgO and subsequently of forsterite (Mg2SiO4). Both are seen to form within an amorphous SiO2 matrix. The rate of crystallization of the samples has been monitored by conventional TEM imaging and electron diffraction. The sample that had been pre‐irradiated with He+ ions is found to transform faster than the as‐quenched glass. The crystallization of metastable MgSiO3 glasses is explained by ionizing radiation‐induced elemental diffusion that allows the reorganization of matter into a more favourable thermodynamic state. These results show that ionizing radiation interactions could account for crystal formation as observed in infrared spectroscopy in some young stellar environments.  相似文献   
387.
Reduction in strength and stiffness in rocks attributed to an increase in water content has been extensively researched on a large variety of rock types over the past decades. Due to the considerable variations of texture and lithology, the extent of water-weakening effect is highly varied among different rock types, spanning from nearly negligible in quartzite to 90 % of uniaxial compressive strength reduction in shale. Readers, however, often face difficulties in comparing the data published in different sources due to the discrepancy of experimental procedures of obtaining the water saturation state and how the raw laboratory data is interpreted. In view of this, the present paper first reviews the terminologies commonly used to quantify the amount of water stored in rocks. The second part of the paper reviews the water-weakening effects on rock strengths, particularly focusing on uniaxial compressive strength and modulus, as well as tensile strength, under quasi-static loading and dynamic loading. The correlation relationships established among various parameters, including porosity, density and fabric of rocks, and external factors such as strain rate, surface tension and dielectric constant of the saturating liquid, absorption percentage and suction pressure, are reviewed and presented toward the end of the paper.  相似文献   
388.
Narrowing research and policy, while challenging, is especially important in climate change adaptation work (CCA) due to the high uncertainties involved in planning for climate change. This article aims to seek stakeholders’ opinions regarding how research and policy development can be bridged within the Cambodian water resources and agriculture sectors. The study used institutional ethnography methods with informants from government organizations, local academia, and development partners (DPs). This article identifies a number of challenges, and barriers for narrowing research–policy development gaps, including: limited effectiveness of governmental policies and planning; lack of relevant information required to promote evidence-based planning and policy development; and communication barriers. Evidence-based planning is valued by government officials most when there is actual and effective implementation of policies and plans. In practice, this often implies that governmental policies and plans need be scoped and scaled down to meet the available budget, and thus be achievable. In the long term, it also means building the capacity for policy-relevant research on climate change adaptation within Cambodia. Engaging policy stakeholders in research process for co-producing adaptation knowledge, and introducing knowledge intermediaries are suggested by informants as means to narrowing gaps between research and policy development. The presence of the Cambodia's Prime Minister in research–policy dialogues is recommended as important for attracting the attention of high-level policy makers.

Policy relevance

As a least developed and highly climate-vulnerable country, Cambodia has received climate change funding to implement a number of climate adaptation initiatives. Cambodia is likely to receive more climate change finance in the future. This article aims to assist evidence-based planning, in particular, through policy-relevant research on CCA, so that resources for adaptation in Cambodia are used effectively and efficiently. This research also directly benefits the sustainable development of the country.  相似文献   

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